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公开(公告)号：US5254434A
公开(公告)日：1993-10-19
申请号：US783243
申请日：1991-10-28
摘要： Method of forming thermal transfer dye images comprising exposing a recording element comprising at least one layer of an organic photochemical imaging composition comprising a heat-diffusible dye (precursor) monomer, said layer being permeable to said dye (precursor) monomer, to an image-wise distribution of actinic radiation to create a change in its permeability corresponding to said image-wise distribution of actinic radiation, wherein said change in permeability is brought about by the radiation-induced polymerization or crosslinking reaction of said organic photochemical imaging composition combined with a concurrent copolymerization or crosslinking reaction of said heat-diffusible dye (precursor) monomer, bringing said recording element in contact with an image-receiving element, overall heating at least one of said contacting elements to cause diffusion of the heat-diffusible dye (precursor) monomer from the areas having unchanged permeability and transfer to said image-receiving element, causing in the case of said dye precursor monomer reaction of said transferred dye precursor monomer with a reagent present in said recording element, in said image-receiving element, or in a fluid medium applied to said image-receiving element, to convert said transferred dye precursor monomer into a dye. The invention also provides a recording element for use according to this method.
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2.发明授权Method for the preparation of stable aqueous dispersions of polymer beads and the use of these dispersions in photographic elements 失效用于制备聚合物珠的稳定水分散体的方法以及这些分散体在照相元件中的应用
公开(公告)号：US4614708A
公开(公告)日：1986-09-30
申请号：US580272
申请日：1984-02-16
IPC分类号： G03C1/32 , C08F2/00 , C08F2/16 , C08F2/18 , C08F257/02 , C08F267/02 , C08F291/00 , G03C1/825 , G03C1/89 , G03C1/95 , G03C1/84 , G03C1/02
CPC分类号： C08F257/02 , C08F267/02 , G03C1/825 , G03C1/89 , G03C1/95 , Y10S430/132 , Y10S430/151 , Y10S430/162
摘要： Method for the preparation of stable aqueous dispersions of finely divided solid spherical polymer beads having an average particle size between about 0.5 and about 5 .mu.m and having a glass transition temperature of at least 40.degree. C. by dissolving in an aqueous solvent mixture at least one .alpha.,.beta.-ethylenically unsaturated monomer capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in said aqueous solvent mixture, a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution to a temperature from 50.degree. C. to the reflux temperature thereof with stirring so as to form said polymer beads. The polymer beads can be used in an antifriction surface layer, an antihalation surface layer, an antistatic surface layer, or in a protective surface layer of a photographic element or in a top layer of a drafting film containing a photosensitive layer.
摘要翻译： 制备平均粒径为约0.5至约5μm的玻璃化转变温度为至少40℃的细分固体球形聚合物珠粒的稳定水分散体的方法，通过将至少 能够形成可溶于所述水性溶剂混合物中存在但不溶于所述水性溶剂混合物中的单体的聚合物的一种α，β-烯属不饱和单体，自由基形成聚合引发剂和接枝 - 含有亲水基团的可聚合聚合物，在搅拌下将溶液加热至50℃至其回流温度，以形成所述聚合物珠粒。 聚合物珠可以用于减摩表面层，防光晕表面层，抗静电表面层，或照相元件的保护表面层或含有感光层的牵伸膜的顶层中。
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3.发明授权
公开(公告)号：US4186010A
公开(公告)日：1980-01-29
申请号：US567109
申请日：1975-04-11
IPC分类号： G03C1/34 , C08F246/00 , G03C1/053 , G03C5/30 , G03C1/72
CPC分类号： G03C1/053 , Y10S430/164
摘要： A photographic element is described comprising an emulsion layer of low gelatin to silver halide ratio, the emulsion comprising a polymeric compound containing recurring units with ketoiminoguanidinium groups in the side chain to reduce formation of pressure marks.
摘要翻译： 描述了一种照相元件，其包含低明胶与卤化银比例的乳剂层，该乳液包含在侧链中含有酮亚胺基团的重复单元的聚合物，以减少形成压痕。
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公开(公告)号：US4139768A
公开(公告)日：1979-02-13
申请号：US819154
申请日：1977-07-26
IPC分类号： G03G15/22 , G03G15/054 , B41M5/00 , G03B41/16
CPC分类号： G03G15/0545
摘要： An ionographic imaging chamber, which comprises: first and second substantially planar electrodes; means supporting said electrodes in the chamber in spaced relation defining a gap therebetween; means for connecting a voltage source to said electrodes, and means enabling a dielectric charge receptor member to be introduced into said chamber and into contact with one of said electrodes, wherein said one electrode has in a non-porous surface layer for contacting said member a relief structure or configuration providing a recess or recesses capable of holding gas while a said charge receptor member is in position against said one electrode.
摘要翻译： 一种离子成像室，包括：第一和第二基本平面的电极; 意味着以间隔开的方式支撑所述室中的所述电极，其间形成间隙; 用于将电压源连接到所述电极的装置，以及使介电电荷受体构件能够被引入所述室并与所述电极之一接触的装置，其中所述一个电极具有用于使所述构件a接触的无孔表面层 浮雕结构或构造提供能够保持气体的凹部或凹部，同时所述电荷接收构件抵靠所述一个电极就位。
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公开(公告)号：US4130670A
公开(公告)日：1978-12-19
申请号：US723189
申请日：1976-09-14
CPC分类号： G03G5/02 , G03G11/00 , G03G13/20 , G03G5/0202 , Y10T428/2843 , Y10T428/2852 , Y10T428/2883 , Y10T428/2891
摘要： A sheet or web material for use in developing and fixing toner images which comprises a support and a thermo-adhesive fixing layer defining the surface of the material on which the toner image is deposited. The thermo-adhesive fixing layer comprises an organic polymeric material and has the following properties: a surface resistance above 10.sup.10 Ohm/square, freedom from blocking at least up to 35.degree. C, a melt viscosity at 190.degree. C of not more than 120 P, and an abrasion resistance at 20.degree. C above 175 g.The process for fixing a toner image on this sheet or web material comprises the steps of image-wise depositing on said thermo-adhesive fixing layer toner particles forming with the molten thermo-adhesive fixing layer a contact angle smaller than 90.degree., heating above 90.degree. C at least those parts of such layer corresponding with the toner images, said heating being of a sufficient intensity and duration that said particles sink within the softened fixing layer, and allowing said imaged layer to cool to fix said image particles in said layer.
摘要翻译： 用于显影和定影调色剂图像的片材或网状材料，其包括支撑体和限定其上沉积有调色剂图像的材料表面的热固性粘合层。 热固性粘合层包含有机聚合材料，具有以下特性：表面电阻高于1010欧姆/平方，不受阻塞至少高达35℃，190℃下的熔体粘度不大于120P ，并且在20℃下的耐磨性高于175g。
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公开(公告)号：US4820608A
公开(公告)日：1989-04-11
申请号：US110797
申请日：1987-10-21
申请人： Daniel A. Claeys , Daniel M. Timmerman , Antonius A. Rutges , Eddy A. Michiels , Luc J. Vanmaele , Piet Kok
发明人： Daniel A. Claeys , Daniel M. Timmerman , Antonius A. Rutges , Eddy A. Michiels , Luc J. Vanmaele , Piet Kok
CPC分类号： G03C8/26 , G03C8/00 , Y10S430/142
摘要： The present invention provides a dye diffusion transfer imaging process comprising transferring image-wise by diffusion an acid dye to an image-receiving layer incorporating a non-polymeric phosphonium mordanting agent and a copolymer latex comprising free weak acid groups as a stabilizer for the mordanting agent, wherein the image-wise transfer of said acid dye is performed in the presence of a heterocyclic compound corresponding to one of the following general formulae I, II, and III: ##STR1## wherein: Y represents the non-metallic atoms needed to complete a saturated or unsaturated 5- or 6-membered heterocyclic nucleus, which may carry a fused-on aromatic ring system, and M represents hydrogen, an alkali metal atom, a quaternary ammonium group, or a negative charge forming an inner salt with a quaternized nitrogen atom of the heterocyclic compound. The invention also provides an image receptor element for dye diffusion transfer imaging processes comprising a support and such image-receiving layer.
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公开(公告)号：US4266044A
公开(公告)日：1981-05-05
申请号：US968175
申请日：1978-12-11
IPC分类号： G03C1/835 , G03C7/25 , C08C19/22 , C08F26/00 , C08F220/60 , C08F226/00
CPC分类号： G03C1/835 , G03C7/25 , Y10S430/142 , Y10S526/923
摘要： Mordanting agents for anionic organic compounds are described which comprise recurring units of the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; A is methylene or methylene substituted by C.sub.1 -C.sub.5 alkyl;n is 0 or 1;R.sub.2 is alkyl, andX is an acid radical.They are particularly suitable for hindering diffusion of dyes in hydrophilic colloid media e.g. hydrophilic colloid layers of a photographic silver halide element, for hindering diffusion of color couplers in such layers e.g. layers of a radiographic silver halide color element and for the formation of color images by the relief imbibition process.
摘要翻译： 描述了阴离子有机化合物的媒染剂，其包含下式的重复单元：其中R 1是氢或甲基; A是被C1-C5烷基取代的亚甲基或亚甲基; n为0或1; R2是烷基，X是酸基。 它们特别适用于阻止染料在亲水胶体介质中的扩散，例如 照相卤化银元素的亲水胶体层，用于阻止彩色成色剂在这种层中的扩散。 一层放射摄影卤化银色素，并通过浮雕吸收过程形成彩色图像。
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8.发明授权
公开(公告)号：US4145220A
公开(公告)日：1979-03-20
申请号：US213990
申请日：1971-12-30
CPC分类号： G03C1/835 , G03C7/25 , Y10S430/142 , Y10S526/923
摘要： Mordanting agents for anionic organic compounds are described which comprise recurring units of the formula: ##STR1## wherein R.sub.1 is hydrogen or methyl; A is methylene or methylene sustituted by C.sub.1 -C.sub.5 alkyl; N is 0 or 1; R.sub.2 is alkyl, and X is an acid radical. They are particularly suitable for hindering diffusion of dyes in hydrophilic colloid media e.g. hydrophilic colloid layers of a photographic silver halide element, for hindering diffusion of color couplers in such layers e.g. layers of a radiographic silver halide color element and for the formation of color images by the relief imbibition process.
摘要翻译： 描述了阴离子有机化合物的媒染剂，其包含下式的重复单元：其中R 1是氢或甲基; A是由C 1 -C 5烷基取代的亚甲基或亚甲基; N IS 0或1; R2是烷基，X是酸基。
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9.发明授权
公开(公告)号：US5380619A
公开(公告)日：1995-01-10
申请号：US226395
申请日：1994-04-12
IPC分类号： C08F230/02 , G03C1/835 , G03C8/56 , G03C5/54
CPC分类号： C08F230/02 , G03C1/835 , G03C8/56 , Y10S430/142
摘要： Phosphonium mordanting polymer comprising randomly distributed recurring units corresponding to the general formula (I) ##STR1## wherein: A represents a unit that is derived from a copolymerizable monomer having a hydrophobic character e.g. acrylonitrile,n represents an integer of from 1 to about 12;each of R.sub.1, R.sub.2 and R.sub.3 (same or different) represents a C.sub.1 -C.sub.8 alkyl group, a cycloalkyl group or an aryl group;X.sup.-- represents an acid anion e.g. a halogen anion, or an anion derived from an inorganic acid;x+y+z represents from about 2 mole % to about 70 mole % with y+z maximum 15 mole % andw represents from about 30 mole % to about 98 mole %.
摘要翻译： 包含对应于通式（I）的随机分布的重复单元的鏻媒染聚合物其中：A表示衍生自具有疏水性的共聚单体的单元， 丙烯腈，n表示1〜12的整数， R1，R2和R3（相同或不同）表示C1-C8烷基，环烷基或芳基; X-表示酸性阴离子例如 卤素阴离子或衍生自无机酸的阴离子; x + y + z表示约2摩尔％至约70摩尔％，y + z最大为15摩尔％，w表示约30摩尔％至约98摩尔％。
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10.发明授权
公开(公告)号：US5273951A
公开(公告)日：1993-12-28
申请号：US899855
申请日：1992-06-17
CPC分类号： B41M5/44 , B41M2205/02 , B41M2205/30 , B41M5/443 , Y10S428/913 , Y10S428/914 , Y10T428/31663
摘要： Dye-donor element for use according to thermal dye sublimation transfer comprising a support having on one side a dye layer and on the other side a slipping layer, characterized in that said slipping layer comprises the cured product of a moisture-curable binder composition prepared by mixing the following components (A) and (B):(A) 30 to 99 parts by weight of at least one copolymer of olefinically unsaturated compounds having a weight-average molecular weight [Mw] of at least 1500 and containing chemically incorporated moieties capable of undergoing an addition reaction with amino groups, and(B) 1 to 70 parts by weight of organic substances containing blocked amino groups from which substances under the influence of moisture compounds having free primary and/or secondary amino groups are formed,wherein i) the copolymers of component (A) contain intramolecularly bound carboxylic anhydride moieties, with the anhydride equivalent weight of the copolymers being from 196 to 9800 and ii) the binder composition contains from 0.25 to 10 anhydride moieties for each blocked amino group.
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