公开(公告)号：US08524840B2

公开(公告)日：2013-09-03

申请号：US11442839

申请日：2006-05-30

申请人： Huide D. Zhu ,  Daniel P. Heberer

发明人： Huide D. Zhu ,  Daniel P. Heberer

IPC分类号： C08G18/48

CPC分类号： C08G18/4812 ,  B32B2605/08 ,  C08G18/12 ,  C08G2190/00 ,  C09J175/04 ,  C08G18/289 ,  C08G18/307 ,  C08G18/48 ,  C08G18/792

摘要： In one aspect, this invention is a composition comprising a urethane prepolymer having isocyanate moieties; a catalytic amount of a compound which catalyzes the reaction of isocyanate moieties with water or an active hydrogen containing compound; alpha hydrocarbyl silane compound; and a catalytic amount of a compound which catalyzes silanol condensation. The composition of the invention can be used to bond a window into a structure without the need to prime the window or the window flange of the structure.

摘要翻译： 一方面，本发明是包含具有异氰酸酯部分的氨基甲酸酯预聚物的组合物; 催化量的催化异氰酸酯部分与水或含活性氢化合物的反应的化合物; α烃基硅烷化合物; 和催化量的催化硅烷醇缩合的化合物。 本发明的组合物可用于将窗户结合到结构中，而不需要施加结构的窗口或窗口凸缘。

公开(公告)号：US07708853B2

公开(公告)日：2010-05-04

申请号：US12195648

申请日：2008-08-21

申请人： Ziyan Wu ,  Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam

发明人： Ziyan Wu ,  Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam

IPC分类号： C09J5/02 ,  B60J10/02

CPC分类号： C03C27/048 ,  C03C27/10 ,  C09D5/002 ,  C09J5/02

摘要： The invention is a bonding process using a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.

摘要翻译： 本发明是使用组合物的粘合方法，该组合物包含a）一种或多种具有四种配体的有机钛酸酯或锆酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷的杂原子的官能团， 硫，其中两个或更多个配体可以形成环状结构，条件是配体之一具有酸性部分; 一种或多种强有机酸或其混合物; b）一种或多种烷氧基硅烷; c）任选的一种或多种高分子量树脂; 和d）溶解组合物组分的溶剂。 该组合物在下文中称为透明底漆。 优选地，组合物包含有机钛酸盐或锆酸盐和强酸。

公开(公告)号：US20090205769A1

公开(公告)日：2009-08-20

申请号：US12195648

申请日：2008-08-21

申请人： Ziyan Wu ,  Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam

发明人： Ziyan Wu ,  Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam

IPC分类号： B32B37/12

CPC分类号： C03C27/048 ,  C03C27/10 ,  C09D5/002 ,  C09J5/02

摘要： The invention is a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.

摘要翻译： 本发明是一种组合物，其包含a）一种或多种具有四种配体的有机钛酸酯或锆酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷和硫的杂原子的官能团，其中两个或 更多的配体可以形成环状结构，条件是配体之一具有酸性部分; 一种或多种强有机酸或其混合物; b）一种或多种烷氧基硅烷; c）任选的一种或多种高分子量树脂; 和d）溶解组合物组分的溶剂。 该组合物在下文中称为透明底漆。 优选地，组合物包含有机钛酸盐或锆酸盐和强酸。

公开(公告)号：US06875303B2

公开(公告)日：2005-04-05

申请号：US10304425

申请日：2002-11-26

申请人： Andon Samurkas ,  Ziyan Wu ,  Sean C. Tobin ,  Daniel P. Heberer

发明人： Andon Samurkas ,  Ziyan Wu ,  Sean C. Tobin ,  Daniel P. Heberer

IPC分类号： B60J1/02 ,  B08B7/00 ,  B32B17/10 ,  C03C27/04 ,  C08L75/04 ,  C09J5/02 ,  C09J175/04 ,  C09J201/00 ,  H05H1/24

CPC分类号： C09J5/02 ,  B08B7/00 ,  C03C27/048 ,  C08L75/04 ,  C09J2400/143 ,  C09J2475/00

摘要： The invention is a process for bonding glass to a substrate without the need to prime the surface of the substrate. The process comprises, first, treating the surface of the substrate with air plasma, applying to the surface of the substrate or to the surface of the glass an adhesive capable of bonding to the treated substrate and glass, and contacting the glass and the substrate with the adhesive disposed between the substrate and the glass, and allowing the adhesive to cure. Preferably the substrate is coated with a coating. Preferred adhesives are polyurethane or silane functional elastomeric adhesives.The process of the invention allows bonding of glass to a substrate without the need to use a primer on the substrate prior to application of the adhesive. The process is especially effective in facilitating the bonding of glass to coated substrates, especially substrates coated with acid resistant coatings such as PPG's carbamate coating or DuPont's Gen III, IV and VI coatings.

摘要翻译： 本发明是一种将玻璃粘合到基材上的方法，而不需要填充基材的表面。 该方法包括：首先用空气等离子体处理衬底的表面，向衬底的表面或玻璃表面施加能够与经处理的衬底和玻璃结合的粘合剂，并将玻璃和衬底与 粘合剂设置在基板和玻璃之间，并允许粘合剂固化。 优选地，用涂层涂覆基材。 优选的粘合剂是聚氨酯或硅烷官能的弹性体粘合剂。本发明的方法允许将玻璃粘合到基材上，而不需要在施加粘合剂之前在基材上使用底漆。 该方法在促进玻璃与涂覆的基材，特别是涂覆有耐酸涂层如PPG的氨基甲酸酯涂层或DuPont的Gen III，IV和VI涂层的基材之间特别有效。

公开(公告)号：US5681919A

公开(公告)日：1997-10-28

申请号：US453150

申请日：1995-05-30

申请人： Charles J. Amirsakis ,  David E. Vietti ,  Daniel P. Heberer ,  Louis C. Dolmon ,  Lawrence Picchiotti

发明人： Charles J. Amirsakis ,  David E. Vietti ,  Daniel P. Heberer ,  Louis C. Dolmon ,  Lawrence Picchiotti

IPC分类号： C08G63/685 ,  C07F9/38 ,  C08G18/08 ,  C08G18/30 ,  C08G63/692 ,  C09D5/23 ,  G11B5/702

CPC分类号： C08G18/0819 ,  C08G63/6926 ,  G11B5/7021 ,  Y10S428/90 ,  Y10T428/25 ,  Y10T428/31609 ,  Y10T428/31786

摘要： A magnetic recording medium is prepared by applying a magnetic coating composition onto a non-magnetic support and curing said composition, said coating composition containing ferromagnetic particles dispersed in a binder comprising a thermoplastic resin selected from the group consisting of polyurethanes and polyester wherein there is chemically bonded to said resin at least one aminoalkylphosphonate represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different oxyalkyl radicals having from 2 to 12 carbon atoms, R.sup.3 is an alkylene radical having from 1 to 12 carbon atoms, or an aralkylene radical having from 7 to 10 carbon atoms R.sup.4 is an alkyl radical having from 1 to 12 carbon atoms, a cycloalkyl radical having from 5 to 12 carbon atoms, or an aryl radical having from 6 to 12 carbon atoms wherein the aryl radical may contain a halogen atom, a hydroxyl group, or an amino group, and M.sup.+ is a metal ion or an ammonium ion.

摘要翻译： 通过将磁性涂料组合物施加到非磁性载体上并固化所述组合物来制备磁记录介质，所述涂料组合物含有分散在粘合剂中的铁磁颗粒，所述粘合剂包含选自聚氨酯和聚酯的热塑性树脂，其中存在化学 与所述树脂键合至少一种由下式表示的氨基烷基膦酸酯：其中R 1和R 2是相同或不同的具有2至12个碳原子的氧烷基，R 3是具有1至12个碳原子的亚烷基，或 具有7至10个碳原子的亚芳基R 4是具有1至12个碳原子的烷基，具有5至12个碳原子的环烷基或具有6至12个碳原子的芳基，其中芳基可以含有 卤素原子，羟基或氨基，M +是金属离子或铵离子。

公开(公告)号：US07834102B2

公开(公告)日：2010-11-16

申请号：US11510234

申请日：2006-08-25

申请人： Lirong Zhou ,  Daniel P. Heberer

发明人： Lirong Zhou ,  Daniel P. Heberer

IPC分类号： C08F20/00 ,  C08G73/00 ,  C08G18/00

CPC分类号： C09J175/04 ,  B60J10/34 ,  B60J10/45 ,  C08G18/10 ,  C08G18/12 ,  C08G18/163 ,  C08G18/4072 ,  C08G18/7664 ,  C08G18/792

摘要： The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.

摘要翻译： 本发明是一种组合物，其包含a）一种或多种异氰酸酯官能的聚醚基预聚物; b）一种或多种异氰酸酯官能聚酯预聚物，其中所述一种或多种聚酯用于制备熔点为约45至约59℃的预聚物; c）一种或多种具有约3或更大的标称官能度的多异氰酸酯; d）一种或多种非导电炭黑; e）用于使具有羟基的异氰酸酯部分反应的一种或多种催化剂。 在优选的实施方案中，本发明的组合物还包含一种或多种异氰酸酯官能的聚酯预聚物，其中所述一种或多种聚酯用于制备熔点为约60至约90℃的预聚物。

公开(公告)号：US5556698A

公开(公告)日：1996-09-17

申请号：US452804

申请日：1995-05-30

申请人： Charles J. Amirsakis ,  David E. Vietti ,  Daniel P. Heberer ,  Louis C. Dolmon ,  Lawrence Picchiotti

发明人： Charles J. Amirsakis ,  David E. Vietti ,  Daniel P. Heberer ,  Louis C. Dolmon ,  Lawrence Picchiotti

IPC分类号： C08G63/685 ,  C07F9/38 ,  C08G18/08 ,  C08G18/30 ,  C08G63/692 ,  C09D5/23 ,  G11B5/702

CPC分类号： C08G18/0819 ,  C08G63/6926 ,  G11B5/7021 ,  Y10S428/90 ,  Y10T428/25 ,  Y10T428/31609 ,  Y10T428/31786

摘要： A magnetic recording medium is prepared by applying a magnetic coating composition onto a non-magnetic support and curing said composition, said coating composition containing ferromagnetic particles dispersed in a binder comprising a thermoplastic resin selected from the group consisting of polyurethanes and polyester wherein there is chemically bonded to said resin at least one aminoalkylphosphonate represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different oxyalkyl radicals having from 2 to 12 carbon atoms, R.sup.3 is an alkylene radical having from 1 to 12 carbon atoms, or an aralkylene radical having from 7 to 10 carbon atoms R.sup.4 is an alkyl radical having from 1 to 12 carbon atoms, a cycloalkyl radical having from 5 to 12 carbon atoms, or an aryl radical having from 6 to 12 carbon atoms wherein the aryl radical may contain a halogen atom, a hydroxyl group, or an amino group, and M.sup.+ is a metal ion or an ammonium ion.

摘要翻译： 通过将磁性涂料组合物施加到非磁性载体上并固化所述组合物来制备磁记录介质，所述涂料组合物含有分散在粘合剂中的铁磁颗粒，所述粘合剂包含选自聚氨酯和聚酯的热塑性树脂，其中存在化学 与所述树脂键合至少一种由下式表示的氨基烷基膦酸酯：其中R 1和R 2是相同或不同的具有2至12个碳原子的氧烷基，R 3是具有1至12个碳原子的亚烷基，或 具有7至10个碳原子的亚芳基R 4是具有1至12个碳原子的烷基，具有5至12个碳原子的环烷基或具有6至12个碳原子的芳基，其中芳基可以含有 卤素原子，羟基或氨基，M +是金属离子或铵离子。

公开(公告)号：US07789990B2

公开(公告)日：2010-09-07

申请号：US11825085

申请日：2007-07-03

申请人： Huide D. Zhu ,  Daniel P. Heberer

发明人： Huide D. Zhu ,  Daniel P. Heberer

IPC分类号： B60J1/00 ,  E06B3/00 ,  E06B5/00 ,  E06B7/00 ,  C04B37/00 ,  B41J2/16 ,  B32B7/12 ,  C09J4/00 ,  C09J101/00 ,  C09J201/00 ,  C09J7/02 ,  C08L83/00 ,  C08L83/04

CPC分类号： C09J5/00 ,  C09J201/10 ,  C09J2400/143 ,  C09J2483/00

摘要： The invention is an adhesive composition comprising one or more polymers having a flexible backbone and silane moieties capable of silanol condensation; one or more hydrophobic silanes having one or more hydrocarbyloxy groups and one or more hydrocarbyl groups; one or more catalysts for the reaction of silane moieties with active hydrogen containing compounds. Preferably, the adhesive composition further comprises one or more heat stabilizers and/or light stabilizers. In another embodiment, the invention is a method of bonding a window to a coated substrate, such as a window in a vehicle, which comprises applying to the window or the coated substrate an adhesive as described; contacting the window with the coated substrate wherein the adhesive is located between the window and the substrate; and allowing the adhesive to cure.

摘要翻译： 本发明是一种粘合剂组合物，其包含一种或多种具有柔性主链和能够硅烷醇缩合的硅烷部分的聚合物; 一个或多个具有一个或多个烃氧基和一个或多个烃基的疏水性硅烷; 用于使硅烷部分与含活性氢化合物反应的一种或多种催化剂。 优选地，粘合剂组合物还包含一种或多种热稳定剂和/或光稳定剂。 在另一个实施方案中，本发明是将窗口结合到涂覆的基底，例如车辆中的窗口的方法，其包括向所述窗口或所述涂覆的基底施加如上所述的粘合剂; 使所述窗与所述涂覆的基底接触，其中所述粘合剂位于所述窗和所述基底之间; 并使粘合剂固化。

公开(公告)号：US07494540B2

公开(公告)日：2009-02-24

申请号：US11012606

申请日：2004-12-15

申请人： Ziyan Wu ,  Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam

发明人： Ziyan Wu ,  Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam

IPC分类号： C09J5/02 ,  C09J175/00

CPC分类号： C03C27/048 ,  C03C27/10 ,  C09D5/002 ,  C09J5/02

摘要： The invention is a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.

摘要翻译： 本发明是一种组合物，其包含a）一种或多种具有四种配体的有机钛酸酯或锆酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷和硫的杂原子的官能团，其中两个或 更多的配体可以形成环状结构，条件是配体之一具有酸性部分; 一种或多种强有机酸或其混合物; b）一种或多种烷氧基硅烷; c）任选的一种或多种高分子量树脂; 和d）溶解组合物组分的溶剂。 该组合物在下文中称为透明底漆。 优选地，组合物包含有机钛酸盐或锆酸盐和强酸。

公开(公告)号：US07416599B2

公开(公告)日：2008-08-26

申请号：US11008426

申请日：2004-12-10

申请人： Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam ,  Ziyan Wu

发明人： Harry W. Hsieh ,  Daniel P. Heberer ,  Dominic J. Allam ,  Ziyan Wu

IPC分类号： E06B3/56 ,  C09J5/02 ,  C09J175/00

CPC分类号： C09J175/04 ,  C03C27/048 ,  C08G18/10 ,  C08G18/307

摘要： The invention is a composition comprising a) one or more organotitanates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure; b) one or more mercaptosilanes; c) one or more polyaminosilanes; d) one or more secondary aminosilanes; and e) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. In another embodiment the invention is a system for bonding glass to a substrate which comprises a clear primer according to the invention; and an adhesive comprising an isocyanate functional prepolymer and a catalyst for the cure of the isocyanate functional prepolymer.

摘要翻译： 本发明是一种组合物，其包含a）一种或多种具有四种配体的有机钛酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷和硫的杂原子的官能团，其中两个或多个 配体可以形成环状结构; b）一种或多种巯基硅烷; c）一种或多种聚氨基硅烷; d）一种或多种仲氨基硅烷; 和e）溶解组合物组分的溶剂。 该组合物在下文中称为透明底漆。 在另一个实施方案中，本发明是用于将玻璃粘合到基底上的系统，其包含根据本发明的透明底漆; 以及包含异氰酸酯官能预聚物和用于固化异氰酸酯官能预聚物的催化剂的粘合剂。