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    Methods for Producing Isomers of Muconic Acid and Muconate Salts
    4.
    发明申请
    Methods for Producing Isomers of Muconic Acid and Muconate Salts 有权
    生产莫索酸和木瓜酸盐的异构体的方法

    公开(公告)号：US20130030215A1

    公开(公告)日：2013-01-31

    申请号：US13518534

    申请日：2011-01-10

    申请人： Vu Bui ,  Man Kit Lau ,  Doug MacRae ,  Dirk Schweitzer

    发明人： Vu Bui ,  Man Kit Lau ,  Doug MacRae ,  Dirk Schweitzer

    IPC分类号： C12P7/44 ,  C07C51/353

    CPC分类号： C12N9/88 ,  C12N9/0069 ,  C12P7/44

    摘要： A method for producing cis,trans- and trans,trans-isomers of muconate by providing cis,cis-muconate produced from a renewable carbon source through biocatalytic conversion; isomerizing cis,cis-muconate to cis,trans-muconate under reaction conditions in which substantially all of the cis,cis-muconate is isomerized to cis,trans-muconate; separating the cis,trans-muconate; and crystallizing the cis,trans-muconate. The cis,trans-isomer can be further isomerized to the trans,trans-isomer. In one example, the method includes culturing recombinant cells that express 3-dehydroshikimate dehydratase, protocatechuate decarboxylase and catechol 1,2-dioxygenase in a medium comprising the renewable carbon source and under conditions in which the renewable carbon source is converted to 3-dehydroshikimate by enzymes in the common pathway of aromatic amino acid biosynthesis of the cell, and the 3-dehydroshikimate is biocatalytically converted to cis,cis-muconate.

    摘要翻译： 通过生物催化转化提供由可再生碳源生产的顺式，顺式 - 粘多糖的方法，制备顺式，反式和反式异构体， 在其中基本上所有的顺式顺式 - 顺式 - 卡络酸酯被异构化为顺式，反式 - 粘蛋白的反应条件下将顺式，顺式 - 分离顺式，反式粘蛋白; 并结晶顺式，反式 - 粘蛋白。 顺式反式异构体可进一步异构化为反式异构体。 在一个实例中，该方法包括在包含可再生碳源的培养基中培养表达3-脱水莽草酸脱水酶，原儿茶酸脱羧酶和儿茶酚1,2-双加氧酶的重组细胞，并且在可再生碳源通过以下方式转化为3-脱水莽草酸的条件下 酶在细胞的芳香族氨基酸生物合成的共同途径中，3-脱水莽草酸被生物催化转化成顺式，顺式 - 粘蛋白。

    Terephthalic and trimellitic based acids and carboxylate derivatives thereof
    5.
    发明授权
    Terephthalic and trimellitic based acids and carboxylate derivatives thereof 失效
    对苯二酸和偏苯三酸类的酸及其羧酸衍生物

    公开(公告)号：US08367858B2

    公开(公告)日：2013-02-05

    申请号：US12816763

    申请日：2010-06-16

    申请人： John W. Frost ,  Adeline Miermont ,  Dirk Schweitzer ,  Vu Bui ,  Douglas A. Wicks

    发明人： John W. Frost ,  Adeline Miermont ,  Dirk Schweitzer ,  Vu Bui ,  Douglas A. Wicks

    IPC分类号： C07C67/04 ,  C07C63/26

    CPC分类号： C07D307/89 ,  C07B2200/09 ,  C07C51/353 ,  C07C67/08 ,  C07C67/303 ,  C07C67/317 ,  C07C67/333 ,  C07C67/347 ,  C07C69/75 ,  C07C2601/14 ,  C07C2601/16 ,  C08G63/183 ,  C07C57/16 ,  C07C69/602 ,  C07C69/76 ,  C07C69/82 ,  C07C61/22

    摘要： The present invention relates to novel substituted and unsubstituted terephthalic acid and carboxylate derivatives and products prepared therefrom having a significant renewable content. The invention also relates to processes for preparing substituted and unsubstituted terephthalic and carboxylate derivatives thereof wherein a portion of the starting materials utilized is derived from renewable resources. The invention also relates to novel cyclohexene based intermediates prepared in these processes and to conversion of these intermediates to substituted and unsubstituted cyclohexane-1,4-dicarboxylates and carboxylate derivatives thereof and novel forms of the resulting products having renewable content. The invention also relates to products prepared from substituted and unsubstituted terephthalic acid and carboxylate derivatives thereof derived from starting materials derived from renewable resources.

    摘要翻译： 本发明涉及新的取代和未取代的对苯二甲酸和羧酸酯衍生物以及由其制备的具有显着可再生含量的产物。 本发明还涉及制备取代和未取代的对苯二甲酸和羧酸酯衍生物的方法，其中所用起始物质的一部分来自可再生资源。 本发明还涉及在这些方法中制备的新型环己烯基中间体以及将这些中间体转化为取代和未取代的环己烷-1,4-二羧酸酯及其羧酸酯衍生物以及具有可再生含量的所得产物的新型形式。 本发明还涉及由衍生自可再生资源的起始原料的取代和未取代的对苯二甲酸及其羧酸衍生物制备的产品。

    Methods for producing isomers of muconic acid and muconate salts
    9.
    发明授权
    Methods for producing isomers of muconic acid and muconate salts 有权
    用于生产粘康酸和粘康酸盐的异构体的方法

    公开(公告)号：US08809583B2

    公开(公告)日：2014-08-19

    申请号：US13518534

    申请日：2011-01-10

    申请人： Vu Bui ,  Man Kit Lau ,  Doug MacRae ,  Dirk Schweitzer

    发明人： Vu Bui ,  Man Kit Lau ,  Doug MacRae ,  Dirk Schweitzer

    IPC分类号： C07C51/353 ,  C12P7/44 ,  C12N9/88 ,  C12N9/02

    CPC分类号： C12N9/88 ,  C12N9/0069 ,  C12P7/44

    摘要： A method for producing cis,trans- and trans,trans-isomers of muconate by providing cis,cis -muconate produced from a renewable carbon source through biocatalytic conversion; isomerizing cis,cis-muconate to cis,trans-muconate under reaction conditions in which substantially all of the cis,cis-muconate is isomerized to cis,trans -muconate; separating the cis,trans-muconate; and crystallizing the cis,trans-muconate. The cis,trans-isomer can be further isomerized to the trans,trans-isomer. In one example, the method includes culturing recombinant cells that express 3-dehydroshikimate dehydratase, protocatechuate decarboxylase and catechol 1,2-dioxygenase in a medium comprising the renewable carbon source and under conditions in which the renewable carbon source is converted to 3-dehydroshikimate by enzymes in the common pathway of aromatic amino acid biosynthesis of the cell, and the 3-dehydroshikimate is biocatalytically converted to cis,cis-muconate.

    摘要翻译： 提供通过生物催化转化由可再生碳源生产的顺式，顺式 - 琥珀酸的顺式，反式和反式反式异构体的制备方法; 在其中基本上所有的顺式顺式 - 顺式 - 卡络酸酯被异构化为顺式，反式 - 马来酸酐的反应条件下将顺式，顺式 - 分离顺式，反式粘蛋白; 并结晶顺式，反式 - 粘蛋白。 顺式反式异构体可进一步异构化为反式异构体。 在一个实例中，该方法包括在包含可再生碳源的培养基中培养表达3-脱水莽草酸脱水酶，原儿茶酸脱羧酶和儿茶酚1,2-双加氧酶的重组细胞，并且在可再生碳源通过以下方式转化为3-脱水莽草酸的条件下 酶在细胞的芳香族氨基酸生物合成的共同途径中，3-脱水莽草酸被生物催化转化成顺式，顺式 - 粘蛋白。

    Process for Preparing Caprolactam and Polyamides Therefrom
    10.
    发明申请
    Process for Preparing Caprolactam and Polyamides Therefrom 有权
    己内酰胺和聚酰胺的制备方法

    公开(公告)号：US20130085255A1

    公开(公告)日：2013-04-04

    申请号：US13442306

    申请日：2012-04-09

    申请人： Laetitia Coudray ,  Vu Bui ,  John W. Frost ,  Dirk Schweitzer

    发明人： Laetitia Coudray ,  Vu Bui ,  John W. Frost ,  Dirk Schweitzer

    IPC分类号： C07D223/10

    CPC分类号： C07D223/10 ,  C07C209/48 ,  C07C231/02 ,  C07C235/74 ,  C07C235/76 ,  C07C255/04 ,  C07C255/09 ,  C08G69/26 ,  C08G69/28 ,  C07C211/12

    摘要： Provided herein are processes for preparing caprolactam from a starting material such as one or more of the cis,cis-, cis,trans- and trans,trans-double-bond isomers of muconamide, muconic acid ester, or muconic acid. The starting material, intermediates, and caprolactam prepared therefrom can contain carbon atoms derived from biomass containing detectable 14C content determined according to ASTM D6866 and optionally containing a 14C content up to 0.0000000001% (one part per trillion). Caprolactam so prepared can be used to make various polyamides.

    摘要翻译： 本文提供了从起始材料如粘蛋白酰胺，粘康酸酯或粘康酸的顺式，顺式，顺式，反式和反式，反式 - 双键异构体中的一种或多种制备己内酰胺的方法。 由其制备的起始原料，中间体和己内酰胺可以包含衍生自含有根据ASTM D6866测定的可检测14C含量的生物质的碳原子，并且任选含有高达0.0000000001％（一兆份）的14C含量。 如此制备的己内酰胺可用于制备各种聚酰胺。