公开(公告)号：US07597868B2

公开(公告)日：2009-10-06

申请号：US11649715

申请日：2007-01-04

申请人： Mamoru Senna ,  Hiroto Watanabe ,  Takahiro Kubo ,  Eitaro Matsui

发明人： Mamoru Senna ,  Hiroto Watanabe ,  Takahiro Kubo ,  Eitaro Matsui

IPC分类号： C01B31/00 ,  C01B13/02

CPC分类号： C01B13/02 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  Y10S977/847

摘要： Powdery fullerene is milled in an oxygen atmosphere, whereby mechanical impacts are applied to the fullerene and a carbon cage of the fullerene is dynamically distorted to the extent that an energy for conversion of atmospheric oxygen to a singlet excited state is accomplished from the distorted carbon cage to atmospheric oxygen. Singlet oxygen, i.e. an efficient oxidant in various industrial fields, is generated by solid-state reaction under stable conditions without necessity of photo-irradiation. The singlet oxygen also enables efficient oxidation of fullerene itself.

摘要翻译： 粉状富勒烯在氧气氛中研磨，由此对富勒烯施加机械冲击，并且富勒烯的碳笼动态变形到将大气氧转化为单重激发态的能量从变形碳笼 到大气氧气。 在不需要光照射的情况下，在稳定的条件下，通过固态反应产生单线态氧，即在各种工业领域的高效氧化剂。 单线态氧还可以有效地氧化富勒烯本身。

公开(公告)号：US09410245B2

公开(公告)日：2016-08-09

申请号：US13996229

申请日：2011-12-28

申请人： Mari Shimizu ,  Eitaro Matsui ,  Aiko Sato ,  Masaki Nakaya ,  Hiroyasu Tabuchi

发明人： Mari Shimizu ,  Eitaro Matsui ,  Aiko Sato ,  Masaki Nakaya ,  Hiroyasu Tabuchi

IPC分类号： C23C16/44 ,  C23C16/04 ,  C23C16/40 ,  C23C16/505 ,  B65D1/40

CPC分类号： C23C16/44 ,  B65D1/40 ,  C23C16/045 ,  C23C16/325 ,  C23C16/401 ,  C23C16/4404 ,  C23C16/505 ,  Y10T428/1352 ,  Y10T428/269

摘要： A gas barrier plastic molded product having high gas barrier properties is provided. The gas barrier plastic molded product is a gas barrier plastic molded product comprising a plastic molded product and a gas barrier thin film provided on the surface of the plastic molded product, in which the gas barrier thin film contains silicon (Si), carbon (C), oxygen (O) and hydrogen (H) as constituent elements, and comprises a Si-containing layer having a Si content percentage represented by (Mathematical Formula 1) of 40.1% or more: Si content percentage [%]={(Si content [atomic %])/ (total content of Si, O and C [atomic %])}×100  (Mathematical Formula 1) wherein in Mathematical Formula 1, the content of Si, O or C is a content thereof in the items of the three elements of Si, O and C.

摘要翻译： 提供了具有高阻气性的阻气性塑料成型体。 阻气性塑料成型体是阻气性塑料成型品，其包含设置在塑料成型体的表面上的塑料成型品和阻气性薄膜，其中阻气性薄膜含有硅（Si），碳（C ），作为构成元素的氧（O）和氢（H）作为构成元素，含有Si数量百分比[％] = {（Si 含量[原子％]）/（Si，O和C的总含量[原子％]）×100（数学式1）其中，在数学式1中，Si，O或C的含量为项目的含量 的Si，O和C的三个元素。

公开(公告)号：US08932676B2

公开(公告)日：2015-01-13

申请号：US13976798

申请日：2011-12-28

申请人： Masaki Nakaya ,  Midori Takiguchi ,  Mari Shimizu ,  Aiko Sato ,  Hiroyasu Tabuchi ,  Eitaro Matsui

发明人： Masaki Nakaya ,  Midori Takiguchi ,  Mari Shimizu ,  Aiko Sato ,  Hiroyasu Tabuchi ,  Eitaro Matsui

IPC分类号： C23C16/00 ,  C09D5/00 ,  C23C16/04 ,  C23C16/40

CPC分类号： C09D5/00 ,  B65D23/02 ,  B65D23/0807 ,  C23C16/045 ,  C23C16/401 ,  C23C16/46

摘要： Provided is a method for producing a gas barrier plastic molded body by forming a gas barrier thin film which is substantially colorless and has gas barrier properties, on the surface of a plastic molded body by a heating element CVD method using only raw material gases that are highly safe. The method for producing a gas barrier plastic molded body according to the present invention is a method for producing a gas barrier plastic molded body (90) by forming a gas barrier thin film (92) on the surface of a plastic molded body (91), the method comprising: a film-forming process in which the gas barrier thin film (92) is formed on the surface of the plastic molded body by a heating element CVD method, using an organosilane-based compound represented by formula (Chemical Formula 1) as a main raw material gas, using an oxidizing gas as an additive gas, and using a heating element containing tantalum (Ta) as a main constituent element: H3Si—Cn—X  (Chemical Formula 1) wherein in Chemical Formula 1, n represents 2 or 3; and X represents SiH3, H, or NH2.

摘要翻译： 本发明提供一种阻气性塑料成型体的制造方法，该方法是通过仅使用原料气体的加热元素CVD法在塑料成型体的表面形成基本上无色且具有阻气性的阻气性薄膜， 高度安全 本发明的阻气性塑料成型体的制造方法是在塑料成形体（91）的表面形成阻气性薄膜（92）来制造阻气性塑料成型体（90）的方法， 该方法包括：使用由式（化学式1）表示的有机硅烷系化合物，通过加热元素CVD法在塑料成型体的表面上形成阻气薄膜（92）的成膜方法 ）作为主要原料气体，使用氧化气体作为添加气体，使用含有钽（Ta）作为主要成分的加热元件：H3Si-Cn-X（化学式1）其中化学式1中n为 代表2或3; X表示SiH 3，H或NH 2。

公开(公告)号：US20130323423A1

公开(公告)日：2013-12-05

申请号：US13976798

申请日：2011-12-28

申请人： Masaki Nakaya ,  Midori Takiguchi ,  Mari Shimizu ,  Aiko Sato ,  Hiroyasu Tabuchi ,  Eitaro Matsui

发明人： Masaki Nakaya ,  Midori Takiguchi ,  Mari Shimizu ,  Aiko Sato ,  Hiroyasu Tabuchi ,  Eitaro Matsui

IPC分类号： C09D5/00

CPC分类号： C09D5/00 ,  B65D23/02 ,  B65D23/0807 ,  C23C16/045 ,  C23C16/401 ,  C23C16/46

摘要： Provided is a method for producing a gas barrier plastic molded body by forming a gas barrier thin film which is substantially colorless and has gas barrier properties, on the surface of a plastic molded body by a heating element CVD method using only raw material gases that are highly safe. The method for producing a gas barrier plastic molded body according to the present invention is a method for producing a gas barrier plastic molded body (90) by forming a gas barrier thin film (92) on the surface of a plastic molded body (91), the method comprising: a film-forming process in which the gas barrier thin film (92) is formed on the surface of the plastic molded body by a heating element CVD method, using an organosilane-based compound represented by formula (Chemical Formula 1) as a main raw material gas, using an oxidizing gas as an additive gas, and using a heating element containing tantalum (Ta) as a main constituent element: H3Si-Cn-X   (Chemical Formula 1) wherein in Chemical Formula 1, n represents 2 or 3; and X represents SiH3, H, or NH2.

摘要翻译： 本发明提供一种阻气性塑料成型体的制造方法，该方法是通过仅使用原料气体的加热元素CVD法在塑料成型体的表面形成基本上无色且具有阻气性的阻气性薄膜， 高度安全 本发明的阻气性塑料成型体的制造方法是在塑料成形体（91）的表面形成阻气性薄膜（92）来制造阻气性塑料成型体（90）的方法， 该方法包括：使用由式（化学式1）表示的有机硅烷系化合物，通过加热元素CVD法在塑料成型体的表面上形成阻气薄膜（92）的成膜方法 ）作为主要原料气体，使用氧化气体作为添加气体，使用含有钽（Ta）作为主要成分的加热元件：H3Si-Cn-X（化学式1）其中化学式1中n为 代表2或3; X表示SiH 3，H或NH 2。

公开(公告)号：US20130316108A1

公开(公告)日：2013-11-28

申请号：US13996229

申请日：2011-12-28

申请人： Mari Shimizu ,  Eitaro Matsui ,  Aiko Sato ,  Masaki Nakaya ,  Hiroyasu Tabuchi

发明人： Mari Shimizu ,  Eitaro Matsui ,  Aiko Sato ,  Masaki Nakaya ,  Hiroyasu Tabuchi

IPC分类号： C23C16/44 ,  B65D1/40

CPC分类号： C23C16/44 ,  B65D1/40 ,  C23C16/045 ,  C23C16/325 ,  C23C16/401 ,  C23C16/4404 ,  C23C16/505 ,  Y10T428/1352 ,  Y10T428/269

摘要： A gas barrier plastic molded product having high gas barrier properties is provided. The gas barrier plastic molded product is a gas barrier plastic molded product comprising a plastic molded product and a gas barrier thin film provided on the surface of the plastic molded product, in which the gas barrier thin film contains silicon (Si), carbon (C), oxygen (O) and hydrogen (H) as constituent elements, and comprises a Si-containing layer having a Si content percentage represented by (Mathematical Formula 1) of 40.1% or more: Si content percentage[%]={(Si content[atomic %])/(total content of Si, O and C [atomic %])}×100  (Mathematical Formula 1) wherein in Mathematical Formula 1, the content of Si, O or C is a content thereof in the items of the three elements of Si, O and C.

摘要翻译： 提供了具有高阻气性的阻气性塑料成型体。 阻气性塑料成型体是阻气性塑料成型品，其包含设置在塑料成型体的表面上的塑料成型品和阻气性薄膜，其中阻气性薄膜含有硅（Si），碳（C ），作为构成元素的氧（O）和氢（H）作为构成元素，含有Si数量百分比[％] = {（Si 含量[原子％]）/（Si，O和C的总含量[原子％]）×100（数学式1）其中，在数学式1中，Si，O或C的含量为项目的含量 的Si，O和C的三个元素。

公开(公告)号：US20070286791A1

公开(公告)日：2007-12-13

申请号：US11649715

申请日：2007-01-04

申请人： Mamoru Senna ,  Hiroto Watanabe ,  Takahiro Kubo ,  Eitaro Matsui

发明人： Mamoru Senna ,  Hiroto Watanabe ,  Takahiro Kubo ,  Eitaro Matsui

IPC分类号： C01B13/00 ,  B01J19/08

CPC分类号： C01B13/02 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/15 ,  C01B32/152 ,  Y10S977/847

摘要： Powdery fullerene is milled in an oxygen atmosphere, whereby mechanical impacts are applied to the fullerene and a carbon cage of the fullerene is dynamically distorted to the extent that an energy for conversion of atmospheric oxygen to a singlet excited state is accomplished from the distorted carbon cage to atmospheric oxygen. Singlet oxygen, i.e. an efficient oxidant in various industrial fields, is generated by solid-state reaction under stable conditions without necessity of photo-irradiation. The singlet oxygen also enables efficient oxidation of fullerene itself.

摘要翻译： 粉状富勒烯在氧气氛中研磨，由此对富勒烯施加机械冲击，并且富勒烯的碳笼动态变形到将大气氧转化为单重激发态的能量从变形碳笼 到大气氧气。 在不需要光照射的情况下，在稳定的条件下，通过固态反应产生单线态氧，即在各种工业领域的高效氧化剂。 单线态氧还可以有效地氧化富勒烯本身。