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    Acrylate composite barrier coating
    1.
    发明授权
    Acrylate composite barrier coating 失效
    丙烯酸酯复合阻挡涂层

    公开(公告)号：US06420003B2

    公开(公告)日：2002-07-16

    申请号：US09745083

    申请日：2000-12-20

    申请人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    发明人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    IPC分类号： B29D2200

    CPC分类号： B05D1/60 ,  B05D3/144 ,  B65D1/0215 ,  H01G2/12 ,  H01G4/20 ,  H01G4/206 ,  H01G4/32 ,  Y10T428/1334 ,  Y10T428/1338 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/265 ,  Y10T428/31667 ,  Y10T428/31699 ,  Y10T428/31743 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31928 ,  Y10T428/31935

    摘要： A thermoplastic container or packaging material is given low oxygen permeability by coating with a crosslinked acrylate layer and a layer of oxygen barrier material deposited over the acrylate layer. Another acrylate layer may be deposited over the oxygen barrier. The oxygen barrier is selected from the group consisting of silicon oxide, aluminum oxide and metal. The acrylate layer may be formed from a photopolymerizable polyfunctional acrylate that is sufficiently low viscosity to be sprayed on the substrate or applied by dipping. Alternatively, the acrylate layer is a polymerization product of an acrylate monomer which is evaporated in a vacuum, condensed on the substrate and polymerized by irradiation by ultraviolet or an electron beam. The surface of the thermoplastic substrate is prepared for deposition of the acrylate by either flame treating the surface of the substrate to heat it above its melting point without deforming the substrate to thereby smooth the surface, or by plasma treating the surface for enhancing adhesion of the acrylate. Chilling the substrate enhances deposition efficiency.

    摘要翻译： 热塑性容器或包装材料通过用交联的丙烯酸酯层和沉积在丙烯酸酯层上的氧阻隔材料层进行涂覆而被赋予低氧渗透性。 另外的丙烯酸酯层可以沉积在氧阻隔层上。 氧阻挡层选自氧化硅，氧化铝和金属。 丙烯酸酯层可以由可光聚合的多官能丙烯酸酯形成，其具有足够低的粘度以喷涂在基材上或通过浸渍施加。 或者，丙烯酸酯层是在真空中蒸发的丙烯酸酯单体的聚合产物，在基材上冷凝并通过紫外线或电子束的照射进行聚合。 制备热塑性基材的表面，通过对基材表面进行火焰处理以将其加热到熔点以上而不使基材变形，从而使表面光滑，或通过等离子体处理表面以提高粘合性 丙烯酸酯。 冷却衬底增强了沉积效率。

    Acrylate composite barrier coating
    5.
    发明授权
    Acrylate composite barrier coating 失效
    丙烯酸酯复合阻挡涂层

    公开(公告)号：US06231939B1

    公开(公告)日：2001-05-15

    申请号：US08706180

    申请日：1996-08-30

    申请人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    发明人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    IPC分类号： B29D2200

    CPC分类号： B05D1/60 ,  B05D3/144 ,  B65D1/0215 ,  H01G2/12 ,  H01G4/20 ,  H01G4/206 ,  H01G4/32 ,  Y10T428/1334 ,  Y10T428/1338 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/24975 ,  Y10T428/265 ,  Y10T428/31667 ,  Y10T428/31699 ,  Y10T428/31743 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31928 ,  Y10T428/31935

    摘要： A thermoplastic container or packaging material is given low oxygen permeability by coating with a cross-linked acrylate layer and a layer of oxygen barrier material deposited over the acrylate layer. Another acrylate layer may be deposited over the oxygen barrier. The oxygen barrier is selected from the group consisting of silicon oxide, aluminum oxide and metal. The acrylate layer may be formed from a photopolymerizable polyfunctional acrylate that is sufficiently low viscosity to be sprayed on the substrate or applied by dipping. Alternatively, the acrylate layer is a polymerization product of an acrylate monomer which is evaporated in a vacuum, condensed on the substrate and polymerized by irradiation by ultraviolet or an electron beam. The surface of the thermoplastic substrate is prepared for deposition of the acrylate by either flame treating the surface of the substrate to heat it above its melting point without deforming the substrate to thereby smooth the surface, or by plasma treating the surface for enhancing adhesion of the acrylate. Chilling the substrate enhances deposition efficiency.

    摘要翻译： 热塑性容器或包装材料通过用交联的丙烯酸酯层和沉积在丙烯酸酯层上的氧阻挡材料层进行涂覆而被赋予低氧渗透性。 另外的丙烯酸酯层可以沉积在氧阻隔层上。 氧阻挡层选自氧化硅，氧化铝和金属。 丙烯酸酯层可以由可光聚合的多官能丙烯酸酯形成，其具有足够低的粘度以喷涂在基材上或通过浸渍施加。 或者，丙烯酸酯层是在真空中蒸发的丙烯酸酯单体的聚合产物，在基材上冷凝并通过紫外线或电子束的照射进行聚合。 制备热塑性基材的表面，通过对基材表面进行火焰处理以将其加热到熔点以上而不使基材变形，从而使表面光滑，或通过等离子体处理表面以提高粘合性 丙烯酸酯。 冷却衬底增强了沉积效率。

    Acrylate polymer coated sheet materials and method of production thereof
    6.
    发明授权
    Acrylate polymer coated sheet materials and method of production thereof 失效
    丙烯酸酯聚合物涂层片材及其制备方法

    公开(公告)号：US06218004B1

    公开(公告)日：2001-04-17

    申请号：US08514411

    申请日：1995-08-11

    申请人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    发明人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    IPC分类号： B32B1508

    CPC分类号： B05D7/52 ,  B05D1/60 ,  D21H19/08 ,  D21H19/16 ,  D21H19/82 ,  Y10T428/24802 ,  Y10T428/265 ,  Y10T428/31699 ,  Y10T428/31703 ,  Y10T428/31891 ,  Y10T428/31928

    摘要： Sheet materials according to the present invention comprise a sheet material substrate, such as for example a film or paper sheet, with a polymer base coating overlying and adhered to a surface of the sheet material substrate. The base coating comprises a radiation cured crosslinked polymer derived from at least one vapor deposited acrylate prepolymer composition having a molecular weight in the range of from about 150 to 600. A metal layer is deposited on and overlies a surface of the base coating, and a polymer top coating overlies and is adhered to a surface of the metal layer. The top coating comprises a radiation cured crosslinked polymer derived from a vapor deposited acrylate prepolymer composition having a molecular weight in the range of from about 150 to 600 and a ratio of its molecular weight to its number of acrylate groups (MW/Ac) in the range of from about 150 to 600. According to one embodiment of the invention, metallized paper sheet materials are produced with superior appearance and performance characteristics which can be tailored to specific end use applications. For example, the metallized paper can be produced with a very shiny, high gloss surface appearance, and/or a high quality metallized layer free of defects or pinholes, and/or an outer surface which is highly receptive to printing.

    摘要翻译： 根据本发明的片材包括片材基材，例如薄膜或纸片，聚合物基底涂层覆盖并粘附到片材基材的表面。 基底涂层包含衍生自分子量在约150至600范围内的至少一种气相沉积的丙烯酸酯预聚物组合物的辐射固化的交联聚合物。金属层沉积在基底涂层的表面上并覆盖在基底涂层的表面上， 聚合物顶涂层覆盖并附着在金属层的表面上。 顶部涂层包含辐射固化的交联聚合物，其衍生自分子量范围为约150-600的气相沉积丙烯酸酯预聚物组合物，其分子量与其丙烯酸酯基团数（MW / Ac）的比例 范围为约150至600.根据本发明的一个实施例，生产具有优异的外观和性能特征的金属化纸片材料，其可以针对具体的最终用途应用而定制。 例如，可以以非常光泽，高光泽的表面外观和/或没有缺陷或针孔的高质量金属化层和/或高度接受印刷的外表面来制造金属化纸。

    Acrylate coating material
    8.
    发明授权
    Acrylate coating material 失效
    丙烯酸酯涂料

    公开(公告)号：US5440446A

    公开(公告)日：1995-08-08

    申请号：US131328

    申请日：1993-10-04

    申请人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    发明人： David G. Shaw ,  Eric Dawson ,  Daniel Cline ,  Marc Langlois

    IPC分类号： B05D3/14 ,  B05D7/24 ,  B65D1/02 ,  H01G4/20 ,  H01G2/12 ,  B32B15/08 ,  H01G4/14

    CPC分类号： B05D1/60 ,  B05D3/144 ,  B65D1/0215 ,  H01G4/20 ,  H01G4/206 ,  Y10T428/31681 ,  Y10T428/31797

    摘要： Material for winding high voltage capacitors is prepared by evaporating polyfunctional acrylate monomer having a molecular rate in the range of from 150 to 600 and condensing the acrylate as a monomer film on a dielectric substrate. The acrylate is polymerized by irradiation by ultraviolet or electrons. Sometimes both faces of the dielectric are coated to protect the thermoplastic dielectric from swelling when exposed to dielectric liquid. The metallized layer provides an electrode of the capacitor. A polymerized acrylate layer may be applied over the metal layer. Electrical contact can be made to the metal layer by Schooping even though the metallized layer is covered by a layer of acrylate. Low oxygen permeability polypropylene, polyester or nylon sheet has a layer of crosslinked acrylate and an oxygen barrier layer formed of silicon oxide, aluminum oxide or metal. Adhesion is enhanced by plasma or corona treatment of a surface immediately before deposition. Condensation efficiency is also enhanced by chilling the substrate on which the acrylate is condensed.

    摘要翻译： 用于卷绕高压电容器的材料通过蒸发分子速率在150至600范围内的多官能丙烯酸酯单体并将作为单体膜的丙烯酸酯凝结在电介质基底上来制备。 丙烯酸酯通过紫外线或电子的照射聚合。 有时电介质的两面被涂覆以保护热塑性介电体在暴露于电介质液体时不溶胀。 金属化层提供电容器的电极。 聚合的丙烯酸酯层可以施加在金属层上。 即使金属化层被丙烯酸酯层覆盖，也可以通过Schooping对金属层进行电接触。 低透氧性聚丙烯，聚酯或尼龙片具有交联的丙烯酸酯层和由氧化硅，氧化铝或金属形成的氧阻隔层。 通过在沉积之前的表面进行等离子体或电晕处理来增强粘附性。 通过冷却丙烯酸酯缩合的基板也可以提高冷凝效率。