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公开(公告)号：US09663866B2
公开(公告)日：2017-05-30
申请号：US13486089
申请日：2012-06-01
申请人： Giovanni Meneghini , Corrado Mojana , Felix Prado
发明人： Giovanni Meneghini , Corrado Mojana , Felix Prado
摘要： The invention relates to a cathode for electrolytic processes provided with a catalytic coating based on ruthenium crystallites with highly controlled size falling in a range of 1-10 nm. The coating can be produced by physical vapor deposition of a ruthenium or ruthenium oxide layer.
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公开(公告)号：US20120234676A1
公开(公告)日：2012-09-20
申请号：US13486089
申请日：2012-06-01
申请人： Giovanni Meneghini , Corrado Mojana , Felix Prado
发明人： Giovanni Meneghini , Corrado Mojana , Felix Prado
摘要： The invention relates to a cathode for electrolytic processes provided with a catalytic coating based on ruthenium crystallites with highly controlled size falling in a range of 1-10 nm. The coating can be produced by physical vapour deposition of a ruthenium or ruthenium oxide layer.
摘要翻译： 本发明涉及一种电解方法的阴极，其具有基于铱微晶的催化涂层，其具有高度可控的尺寸，其范围为1-10nm。 涂层可以通过钌或氧化钌层的物理气相沉积来制备。
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公开(公告)号：US20080264779A1
公开(公告)日：2008-10-30
申请号：US11829674
申请日：2007-07-27
申请人： Giovanni Meneghini
发明人： Giovanni Meneghini
摘要： The invention describes an improved anode suitable for being installed in chlor-alkali electrolysis cells intercalated to cathode elements provided with a diaphragm.In operation, the anode of the invention is in direct contact with the diaphragm so as to form mutually equivalent vertical channels defined by the surfaces of the plates, of the supporting sheets and of the diaphragm, allowing a predefined and controlled upward motion of the chlorine-brine biphasic mixture.
摘要翻译： 本发明描述了一种改进的阳极，适用于安装在设置有隔膜的阴极元件上的氯碱电解槽中。 在操作中，本发明的阳极与膜片直接接触，以便形成相互等效的垂直通道，其由板的表面，支撑片和隔膜限定，允许预先确定和控制氯的向上运动 - 双相混合物。
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公开(公告)号：US5066378A
公开(公告)日：1991-11-19
申请号：US416719
申请日：1989-10-03
申请人： Giovanni Meneghini
发明人： Giovanni Meneghini
摘要： Operation of diaphragm monopolar electrolyzers for chlor-alkali electrolysis is improved by providing at least part of the anodes in their upper portion with hydrodynamic baffles capable of generating a plurality of lifting and downcoming recirculation motions of the mixed anolyte-gas phase and of the anolyte separated from gas, respectively, which baffles are characterized by their superior edge or overflow holes located under the free surface of the anolyte, resulting in a reduction of the cell voltage and an increase in the faradic efficiency and the quality of the products.
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5.发明授权Monopolar electrolytic diaphragm cells with removable and replaceable dimensionally stable anodes and method of inserting and removing said anodes 失效具有可拆卸和可更换的尺寸稳定的阳极的单极电解隔膜电池和插入和去除所述阳极的方法
公开(公告)号：US4162953A
公开(公告)日：1979-07-31
申请号：US862674
申请日：1977-12-21
摘要： Describes a monopolar diaphragm electrolytic cell with dimensionally stable anodes in which the anodes rest freely in the cell and are spring-pressed toward the diaphragms by spring-loaded transverse arms on the positive current carriers, which in use contact, but are not mechanically connected to, the anodes, the spring-pressed electrical contacts between the transverse arms and the anodes are sufficient to carry current to the anodes without substantial ohmic drop through these contacts and permit the anodes to be removed from the cells for recoating and other purposes without destroying any welds or other permanent mechanical connections between the anodes and other portions of the cell.
摘要翻译： 描述具有尺寸稳定的阳极的单极隔膜电解池，其中阳极在电池中自由地放置并且通过弹簧加载的横向臂在正电流载体上弹簧压向隔膜，该正电流载体在使用中接触但不机械地连接到 阳极，横向臂和阳极之间的弹簧压力电接触足以将电流携带到阳极，而不会通过这些触点发生实质的欧姆下降，并允许阳极从电池中移除以用于重新涂覆和其他目的，而不会破坏任何 阳极和电池的其他部分之间的焊接或其他永久机械连接。
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6.发明授权公开(公告)号：US08268140B2
公开(公告)日：2012-09-18
申请号：US12793177
申请日：2010-06-03
申请人： Giovanni Meneghini
发明人： Giovanni Meneghini
CPC分类号： C25B1/46 , C25B13/04 , C25B13/08 , H01M8/0289 , H01M2300/0014 , Y02P70/56
摘要： The invention relates to a synthetic diaphragm for chlor-alkali cells with improved energy consumption and gas separation characteristics. The diaphragm comprises a network of polymer fibers bound to a hydrophilic ceramic material containing zirconium chemically bound to hydroxyl groups. The ceramic material is obtained starting from ZrO2 by a process of hydration under vacuum which can be carried out directly in the cell by means of suitable equipment.
摘要翻译： 本发明涉及一种具有改善能耗和气体分离特性的氯碱电池合成隔膜。 隔膜包括与包含与羟基化学键合的锆的亲水性陶瓷材料结合的聚合物纤维网。 通过真空下水合的方法从ZrO 2开始获得陶瓷材料，其可以通过合适的设备直接在电池中进行。
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7.发明授权Amalgam decomposer for mercury cathode cells for alkali chloride electrolysis 失效用于碱金属氯化物电解的汞阴极电池的汞齐分解器公开(公告)号：US08062712B2
公开(公告)日：2011-11-22
申请号：US12249396
申请日：2008-10-10
CPC分类号： C25B1/44 , B01J8/025 , B01J19/30 , B01J27/22 , B01J27/224 , B01J37/0225 , B01J37/349 , B01J2208/00884 , B01J2208/025 , B01J2219/30215 , B01J2219/30223 , B01J2219/30408 , B01J2219/30475 , B01J2219/318 , C22B3/22 , C22B11/10 , C22B43/00 , C25B9/005 , Y02P10/234
摘要： The invention relates to an amalgam decomposer for mercury cathode chlor-alkali cells. The amalgam decomposer of the invention contains a filling of carbon steel rings whose external surface is provided with a catalytic coating for amalgam decomposition consisting of one or more electrically conductive metals carbides. The internal surface of the rings is free of catalytic coating and wettable by the amalgam, while the external carbide catalytic coating is not wettable by the amalgam thereby favoring hydrogen evolution.
摘要翻译： 本发明涉及汞阴极氯碱电池的汞齐分解器。 本发明的汞合金分解器包含碳钢环的填充物，其外表面设置有由一种或多种导电金属碳化物组成的汞齐分解催化涂层。 环的内表面没有催化涂层，可以通过汞齐润湿，而外部碳化物催化涂层不能被汞齐润湿，从而有利于析氢。
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公开(公告)号：US07560010B2
公开(公告)日：2009-07-14
申请号：US10503278
申请日：2003-02-26
申请人： Giovanni Meneghini
发明人： Giovanni Meneghini
摘要： A diaphragm electrolytic cell is composed of two or more overlaid modules; at least the upper modules having U-shaped anodes with diaphragm-coated cathodes housed within, allowing for a reduced electrode pitch.
摘要翻译： 隔膜电解池由两个或更多个重叠的模块组成; 至少上模块具有U形阳极，其上装有隔膜涂覆的阴极，允许减小的电极间距。
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公开(公告)号：US20080308414A1
公开(公告)日：2008-12-18
申请号：US12194938
申请日：2008-08-20
摘要： There is disclosed an inlet and outlet end-box design for mercury cathode chlor-alkali electrolysis cells of extended lifetime, comprising a composite mechanical structure consisting of a carbon steel bottom entirely supporting the mechanical solicitations, a plastic cover, and a hydraulic head device for washing the mercury and the amalgam. The device is partially extractable thereby allowing the withdrawal of foreign materials accumulated during operation with no need for opening the end-boxes.
摘要翻译： 公开了一种延长使用寿命的汞阴极氯碱电解槽的入口和出口端盒设计，包括由完全支撑机械吸收的碳钢底部组成的复合机械结构，塑料盖和用于 洗涤汞和汞齐。 该装置是部分可抽出的，从而允许在操作期间累积的异物的抽出而不需要打开终端盒。
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10.发明授权Cell having a porous diaphragm for chlor-alkali electrolysis and process using the same 失效具有用于氯碱电解的多孔膜的电池和使用其的方法
公开(公告)号：US5534122A
公开(公告)日：1996-07-09
申请号：US412754
申请日：1995-03-29
申请人： Carlo Traini , Giovanni Meneghini
发明人： Carlo Traini , Giovanni Meneghini
摘要： A chlor-alkali diaphragm electrolysis cell comprising pairs of interleaved cathodes (C) and anodes (B), said cathodes having surfaces with openings and are provided with porous corrosion resistant diaphragms, said cell further comprising feed brine inlets and outlets (H, I, L) for the removal of produced chlorine, hydrogen and caustic, said anodes (B) are expanded by internal extenders (F) and have electrode surfaces with openings for releasing produced gaseous chlorine, characterized in that each of said expanded anodes (B) comprises a plurality of pressing means (O,Q) made of corrosion resistant material having elastic properties to maintain the electrode surfaces of the anodes against the diaphragm and said pressing means are longitudinally positioned inside the anodes having very low operating voltages.
摘要翻译： 一种含有交错阴极（C）和阳极（B）的氯碱隔膜电解槽，所述阴极具有开口的表面并且设置有多孔耐腐蚀隔膜，所述电池还包括进料盐水入口和出口（H，I， 所述阳极（B）通过内部补充剂（F）膨胀并且具有用于释放产生的气态氯的开口的电极表面，其特征在于，每个所述膨胀的阳极（B）包括 由具有弹性的耐腐蚀材料制成的多个按压装置（O，Q），以将阳极的电极表面保持在隔膜和所述按压装置上，纵向位于具有非常低的工作电压的阳极的内部。
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