DENSE THIN FILIM, FUEL CELL USING THE SAME AND FABRICATION METHODS THEREOF
    2.
    发明申请
    DENSE THIN FILIM, FUEL CELL USING THE SAME AND FABRICATION METHODS THEREOF 审中-公开
    DENSE薄膜,使用它的燃料电池及其制造方法

    公开(公告)号:US20120015279A1

    公开(公告)日:2012-01-19

    申请号:US13176216

    申请日:2011-07-05

    Abstract: Disclosed is a dense thin film, a fuel cell using the same and fabrication methods thereof. A method for fabricating a dense thin film comprises (1) forming a first thin film on a porous surface, and (2) forming, on a surface of the first thin film, a second thin film made of a homogeneous material with respect to the first thin film, thereby removing pinholes of the first thin film. The method for fabricating a dense thin film may comprise (1′) forming a first thin film on a porous surface, (2′) forming, on a surface of the first thin film, a second thin film made of a to heterogeneous material with respect to the first thin film, thereby removing pinholes of the first thin film, and (3′) etching a surface of the second thin film. A dense thin film comprises a porous material, a first thin film formed on a surface of the porous material and having pinholes, a blocking material including a homogeneous or heterogeneous material with respect to the first thin film and configured to block the pinholes, and a second thin film including a homogeneous or heterogeneous material with respect to the first thin film and formed on a surface of the first thin film.

    Abstract translation: 公开了一种致密薄膜,使用该薄膜的燃料电池及其制造方法。 一种制造致密薄膜的方法包括:(1)在多孔表面上形成第一薄膜,以及(2)在第一薄膜的表面上形成第二薄膜,该薄膜由均匀材料制成,相对于 第一薄膜,从而去除第一薄膜的针孔。 用于制造致密薄膜的方法可以包括在多孔表面上形成第一薄膜(1')(2'),(2')在第一薄膜的表面上形成第二薄膜,其由异质材料制成, 相对于第一薄膜,从而去除第一薄膜的针孔,和(3')蚀刻第二薄膜的表面。 致密的薄膜包括多孔材料,形成在多孔材料的表面上并具有针孔的第一薄膜,相对于第一薄膜包括均质或异质材料的阻挡材料,并且被构造成阻挡针孔,以及 第二薄膜包括相对于第一薄膜均匀或不均匀的材料并形成在第一薄膜的表面上。

    SEALING COMPOSITE FOR FLAT SOLID OXIDE FUEL CELL STACK HAVING HIGH FRACTURE RESISTANCE AND THE FABRICATION METHOD THEREOF
    3.
    发明申请
    SEALING COMPOSITE FOR FLAT SOLID OXIDE FUEL CELL STACK HAVING HIGH FRACTURE RESISTANCE AND THE FABRICATION METHOD THEREOF 审中-公开
    用于具有高耐断裂性的平坦的固体氧化物燃料电池堆的密封复合材料及其制造方法

    公开(公告)号:US20100331165A1

    公开(公告)日:2010-12-30

    申请号:US12438608

    申请日:2006-12-08

    Abstract: A composite sealant of the present invention increases a fracture toughness of glass which has an excellent gas tightness but has a low fracture resistance, to enhance the thermal cycle stability while maintaining the gas tightness of a stack. For this, alpha-alumina fiber particles, alpha-alumina granular particles, and metallic particles are mixed and added to a glass matrix for remarkably increasing the fracture toughness from 0.5 MPa·m05 to 6 MPa·m°'5 through the multiple effects of crack deflection and crack bridging by the fiber and granular particles, and effects of crack arresting and plastic deformation by the metallic particles. When using the high fracture toughness composite sealant of the present invention, since the gas tightness and the stability of the stack can be maintained even when there is a thermal stress produced by a non-uniform temperature distribution or a thermal cycle condition in the stack, increasing the fracture toughness of the composite sealant works as the most important factor for enhancing the reliability of a large-area stack.

    Abstract translation: 本发明的复合密封剂提高了具有优异的气密性但具有低抗断裂性的玻璃的断裂韧性,以提高热循环的稳定性,同时保持了叠层的气密性。 为此,将α-氧化铝纤维颗粒,α-氧化铝颗粒和金属颗粒混合并加入到玻璃基质中,通过多种效应将断裂韧性从0.5MPa·m05显着提高到6MPa·m·5 由纤维和颗粒颗粒引起的裂纹弯曲和裂纹桥接,以及金属颗粒的裂纹阻滞和塑性变形的影响。 当使用本发明的高断裂韧性复合密封剂时,即使当堆叠中存在由不均匀的温度分布或热循环条件产生的热应力时,由于能够保持气密性和堆叠的稳定性, 提高复合密封胶的断裂韧性是提高大面积叠层可靠性的最重要因素。

    Process for the preparation of SiC whisker-reinforced ceramic composite
materials
    5.
    发明授权
    Process for the preparation of SiC whisker-reinforced ceramic composite materials 失效
    SiC晶须增强陶瓷复合材料的制备工艺

    公开(公告)号:US5656212A

    公开(公告)日:1997-08-12

    申请号:US496204

    申请日:1995-06-28

    CPC classification number: C04B35/645 C04B35/803

    Abstract: A SiC whisker-reinforced ceramic composite is prepared by adding about 0.4 to 1.0% by weight of a nonionic polymer, polyvinylalcohol (PVA) to a heat-treated SiC whisker to obtain a SiC whisker slurry, mixing the SiC whisker slurry with a matrix slurry formed at about pH 4 followed by freeze-drying the resulting slurry mixture to produce granules having a uniform packing structure and hot pressing the granules.

    Abstract translation: 通过向热处理的SiC晶须中加入约0.4-1.0重量%的非离子聚合物聚乙烯醇(PVA)制备SiC晶须增强陶瓷复合材料,以获得SiC晶须浆料,将SiC晶须浆料与基体浆料 在约pH 4下形成,然后将得到的浆料混合物冷冻干燥,得到具有均匀包装结构和热压颗粒的颗粒。

    High performance anode-supported solid oxide fuel cell
    8.
    发明申请
    High performance anode-supported solid oxide fuel cell 审中-公开
    高性能阳极支撑固体氧化物燃料电池

    公开(公告)号:US20070015045A1

    公开(公告)日:2007-01-18

    申请号:US11521478

    申请日:2006-09-15

    Abstract: Disclosed is an anode supporter for a solid oxide fuel cell (SOFC). The SOFC comprises an anode supporter having a high gas permeability, a high electrical conductivity, a high electrochemical activity, a high mechanical strength, and a large area; an anode functional layer for attenuating a surface defect of the anode supporter and maximizing an electrochemical activity of the anode; an electrolyte having a ultra-thin film; a cathode functional layer for removing an interface reaction between the electrolyte and the cathode and enhancing an electrochemical reaction at the cathode; a cathode having an excellent interface bonding characteristic with the cathode functional layer and a high electrical conductivity; and a current collect layer for maximizing an electrical connection between the cathode and a separator or interconnector. Accordingly, a performance of the single cell of a large area is enhanced.

    Abstract translation: 公开了一种固体氧化物燃料电池(SOFC)的阳极支撑体。 SOFC包括具有高透气性,高导电性,高电化学活性,高机械强度和大面积的阳极支撑体; 阳极功能层,用于衰减阳极支撑体的表面缺陷并使阳极的电化学活性最大化; 具有超薄膜的电解质; 阴极功能层,用于去除电解质和阴极之间的界面反应并增强阴极处的电化学反应; 与阴极功能层具有优异的界面结合特性和高导电性的阴极; 以及用于最大化阴极和分离器或互连器之间的电连接的电流收集层。 因此,提高了大面积的单电池的性能。

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