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公开(公告)号:US06719922B1
公开(公告)日:2004-04-13
申请号:US10070631
申请日:2002-07-08
IPC分类号: D06L312
摘要: The present invention relates to a mixture of fluorescent whitening agents comprising 20 to 70% by weight of a compound of formula (1), 30 to 80% of a compound of formula (2) and 0.5 to 5% of a compound of formula (3), compositions containing the mixture and the use of the compositions for whitening synthetic fibers, in particular polyester.
摘要翻译: 本发明涉及包含20-70%(重量)式(1)化合物,30-80%式(2)化合物和0.5-5%式(III)化合物 3),含有该混合物的组合物和用于增白合成纤维,特别是聚酯的组合物的用途。
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公开(公告)号:US5939379A
公开(公告)日:1999-08-17
申请号:US867110
申请日:1997-06-02
IPC分类号: C07D251/52 , C07D251/54 , C07D251/68 , C09B62/04 , C09K3/00 , C11D3/395 , C11D3/42 , D06L3/12 , D06M13/02 , D06M13/248 , D06M13/256 , D06M13/322 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/402 , D06M13/415 , D06M13/463 , D06P1/642 , D21H21/28 , D21H27/00 , C11D3/34 , C11D7/54
CPC分类号: C09B23/148 , C07D251/52 , C07D251/68 , C11D3/42 , D06L3/1214 , D06L3/1257 , D06M13/358 , D06P1/6426
摘要: The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fibre material, especially cotton, polyamide and wool, treated with the new compounds.
摘要翻译: 本发明涉及可用作紫外线吸收剂(UVA)和荧光增白剂(FWA)的新化合物,以及改善纺织纤维材料,特别是棉花,聚酰胺和羊毛的防晒因子(SPF)的方法 ,用新化合物处理。
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公开(公告)号:US5945396A
公开(公告)日:1999-08-31
申请号:US996895
申请日:1997-12-23
IPC分类号: C07D251/68 , C07D251/50 , C07D251/54 , C09K3/00 , C11D1/62 , C11D3/42 , D06L3/12 , D06M13/07 , D06M13/355 , D06M13/358 , D06M11/00 , C07D251/38
CPC分类号: C07D251/50 , C07D251/54 , C11D1/62 , C11D3/42 , D06L3/1214 , D06L3/1257 , D06M13/07 , D06M13/355 , D06M13/358 , D06M2200/25 , D06M2200/50
摘要: The present invention provides a compound having the formula: ##STR1## in which each R.sub.d is the same or different and each is --NH--Z--N(R.sub.a)(R.sub.b) or --N--�Z--N(R.sub.a)(R.sub.b)!.sub.2 in which Z is C.sub.2 -C.sub.14 alkylene or optionally substituted arylene, R.sub.a and R.sub.b are the same or different and each is C.sub.1 -C.sub.12 alkyl, or R.sub.a and R.sub.b, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; each R.sub.c is the same or different and is NH.sub.2, NH(C.sub.1 -C.sub.4 alkyl), N(C.sub.1 -C.sub.4 alkyl).sub.2, N(CH.sub.2 CH.sub.2 OH).sub.2, O--C.sub.1 -C.sub.4 alkyl, ##STR2## alkali metal atom, ammonium or a cation formed from an amine; or a quaternized form thereof. The present invention also relates to a composition for the treatment of textiles, in particular to a composition containing the new ultra-violet absorbing agents; and to a method for the improvement of both the sun protection factor (UPF) and the whiteness of textile fiber material, comprising treating the material with the composition according to the present invention.
摘要翻译: 本发明提供具有下式的化合物:其中每个R d相同或不同,各自为-NH-ZN(Ra)(Rb)或-N- [ZN(Ra)(Rb)] 2,其中Z为 C 2 -C 14亚烷基或任选取代的亚芳基,R a和R b相同或不同,各自为C 1 -C 12烷基,或者R a和R b与它们各自连接的氮原子一起形成吗啉代,哌啶子基或哌嗪基环; 每个Rc相同或不同,是NH 2,NH(C 1 -C 4烷基),N(C 1 -C 4烷基)2,N(CH 2 CH 2 OH)2,O-C 1 -C 4烷基,碱金属原子,铵或由胺形成的阳离子 ; 或其季铵化形式。 本发明还涉及用于处理纺织品的组合物,特别涉及含有新的紫外线吸收剂的组合物; 以及用于改善防晒因子(UPF)和纺织纤维材料的白度的方法,包括用根据本发明的组合物处理该材料。
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公开(公告)号:US06835329B2
公开(公告)日:2004-12-28
申请号:US10398040
申请日:2003-03-31
申请人: Dieter Reinehr , Hanspeter Sauter , Rudolf Zink
发明人: Dieter Reinehr , Hanspeter Sauter , Rudolf Zink
IPC分类号: C07D25124
CPC分类号: C07D403/10 , A61K8/4966 , A61Q17/04 , C07D413/10 , C08K5/3492
摘要: The present invention provides compounds having the formula (1) in which each of the radicals R1, R2, R3 and R4, independently, represent hydrogen, hydroxy, halogen, C1-C20-alkyl, C1-C20-alkoxy, CN or COOR5, in which R5 is C1-C20-alkyl and Z represents a heterocyclic residue selected from the 2H-benzo[1,2-d]triazol-2-yl, 2H-naphtho[1,2-d]triazol-2-yl, benzimidazol-2-yl, benzoxazol-2-yl and benzofuran-2-yl moieties, optionally substituted by C1-C4-alkyl, C1-C4-alkoxy, halogen or NHCOC1-C4-alkyl, a process for their preparation, new intermediate benzoxazinones useful for their preparation and use of the compounds of formula (1) as UV-absorbers which have improved absorption spectrum characteristics, superior resistance to exposure to UV light and excellent thermal stability, relative to known triphenyltriazine compounds.
摘要翻译: 本发明提供具有式(1)的化合物,其中每个基团R 1,R 2,R 3和R 4独立地代表氢,羟基,卤素,C 1 -C 20 - 烷基,C 1 -C 20 - 烷氧基,CN或COOR 5, 其中R 5是C 1 -C 20 - 烷基,Z代表选自2H-苯并[1,2-d]三唑-2-基,2H-萘并[1,2-d]三唑-2-基的杂环残基, 苯并恶唑-2-基和苯并呋喃-2-基部分,任选被C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,卤素或NHCOC 1 -C 4 - 烷基取代,其制备方法,新中间体 苯并恶嗪酮可用于制备和使用式(1)化合物作为UV吸收剂,其相对于已知的三苯基三嗪化合物具有改进的吸收光谱特征,优异的耐紫外线性和耐热稳定性。
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公开(公告)号:US6080208A
公开(公告)日:2000-06-27
申请号:US218246
申请日:1998-12-22
IPC分类号: A61K8/49 , A61Q17/04 , C07D251/68 , C09B57/00 , C11D1/83 , C11D3/39 , C11D3/42 , C11D11/00 , D06L3/12 , D06M13/358 , D06P1/642 , D21H21/30 , C07D251/00 , C11D3/28 , D06P5/02
CPC分类号: C11D3/3947 , A61K8/4966 , A61Q17/04 , C07D251/68 , C11D1/83 , C11D11/0017 , C11D3/42 , D06L3/1214 , D06M13/358 , D06P1/6426 , D21H21/30 , A61K2800/434 , C11D3/3905
摘要: The present invention provides new stilbene compounds which are useful as fluorescent whitening agents (FWAs), imparting high whiteness levels to textile fibre material treated with them, and which also impart a high sun protection factor (SPF) to textile fibre material treated with them. The present invention also concerns a method of imparting a high whiteness level and a high sun protection factor to textile fibre material, especially cotton, polyamide and wool, comprising treating the textile material with the new compounds.
摘要翻译: 本发明提供了可用作荧光增白剂(FWA)的新颖的二苯乙烯化合物,赋予了用它们处理的纺织纤维材料高的白度,并且还对用它们处理的纺织纤维材料赋予高的防晒因子(SPF)。 本发明还涉及一种赋予纺织纤维材料,特别是棉,聚酰胺和羊毛的高白度和高防晒系数的方法,其包括用新化合物处理纺织材料。
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公开(公告)号:US06783698B1
公开(公告)日:2004-08-31
申请号:US10111530
申请日:2002-04-23
IPC分类号: D06L312
摘要: The present invention relates to a mixture of fluorescent whitening agents comprising 20 to 70% by weight of a compound of formula (1), 30 to 80% of a compound of formula (2) and 0.1 to 10% of a compound of formula (3), compositions containing the mixture and the user of the compositions for whitening synthetic fibers, in particular, polyester.
摘要翻译: 本发明涉及一种荧光增白剂的混合物,其包含20至70重量%的式(1)化合物,30至80%的式(2)化合物和0.1至10%的式(1)化合物 3),含有混合物的组合物和用于使合成纤维增白的组合物,特别是聚酯的用户。
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公开(公告)号:US06730655B2
公开(公告)日:2004-05-04
申请号:US09956318
申请日:2001-09-19
IPC分类号: C11D162
CPC分类号: A61Q17/005 , A01N33/12 , A61K8/416 , A61Q5/02 , A61Q11/00 , A61Q15/00 , A61Q19/10 , C07C211/63
摘要: There are described diquaternary ammonium compounds of the general formula: wherein R1 and R4 are each independently of the other C4-C16alkyl, phenyl or phenyl-C1-C10 alkyl, R2, R3, R5 and R6 are each independently of the others C1-C4alkyl, and A is a monovalent anion. The compounds exhibit a pronounced action against gram-positive and gram-negative bacteria, and also against yeast, molds and algae. They are accordingly suitable for the antimicrobial treatment of surfaces and for the preservation and disinfection of materials and cosmetic products, and especially also for the preparation of solid or liquid formulations and for the preservation of foodstuffs and drinks. The compounds are furthermore suitable for imparting antimicrobial properties to technical plant and for antimicrobial water treatment.
摘要翻译: 描述了具有以下通式的二季铵化合物:其中R 1和R 4各自独立于其它C 4 -C 16烷基,苯基或苯基-C 1 -C 10烷基,R 2,R 3,R 5和R 6各自独立地为C 1 -C 4烷基, A是一价阴离子。 该化合物对革兰氏阳性和革兰氏阴性细菌以及酵母,霉菌和藻类都表现出明显的作用。 因此,它们适用于表面的抗微生物处理和用于材料和化妆品的保存和消毒,特别是适用于制备固体或液体制剂以及用于食品和饮料的保存。 该化合物还适用于赋予技术性植物抗微生物性能和抗微生物水处理。
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公开(公告)号:US5892031A
公开(公告)日:1999-04-06
申请号:US862036
申请日:1997-05-22
IPC分类号: A61K8/49 , A61Q17/04 , C07D251/68 , C09B57/00 , C11D1/83 , C11D3/39 , C11D3/42 , C11D11/00 , D06L3/12 , D06M13/358 , D06P1/642 , D21H21/30
CPC分类号: C11D3/3947 , A61K8/4966 , A61Q17/04 , C07D251/68 , C11D1/83 , C11D11/0017 , C11D3/42 , D06L3/1214 , D06M13/358 , D06P1/6426 , D21H21/30 , A61K2800/434 , C11D3/3905
摘要: The present invention provides new stilbene compounds which are useful as fluorescent whitening agents (FWAs), imparting high whiteness levels to textile fibre material treated with them, and which also impart a high sun protection factor (SPF) to textile fibre material treated with them. The present invention also concerns a method of imparting a high whiteness level and a high sun protection factor to textile fibre material, especially cotton, polyamide and wool, comprising treating the textile material with the new compounds.
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9.
公开(公告)号:US06215029B1
公开(公告)日:2001-04-10
申请号:US09328744
申请日:1999-06-09
申请人: Urs Burckhardt , Armando Di Teodoro , Werner Hölzl , Dieter Reinehr , Rudolf Zink , Hanspeter Sauter , Uwe Gronde
发明人: Urs Burckhardt , Armando Di Teodoro , Werner Hölzl , Dieter Reinehr , Rudolf Zink , Hanspeter Sauter , Uwe Gronde
IPC分类号: C07C4101
CPC分类号: C07C43/295 , C07C49/84 , C07C67/42 , C07C69/017 , C07C69/65 , C07C69/63
摘要: A process for the preparation of halohydroxydiphenyl compounds useful for protecting organic materials and articles from microorganisms, of the formula by acylation of a halogenated benzene compound (first stage), etherification of the acylated compound with a halogenated phenol compound (second stage), oxidation of the etherified compound (third stage) and hydrolysis of the oxidized compound in a fourth stage, according to the following reaction scheme: in which R1 and R2 independently of one another are F, Cl or Br; R3 and R4 independently of one another are hydrogen; or C1-C4alkyl; m is 1 to 3; and n is 1 or 2.
摘要翻译: 用于制备用于保护有机材料和制品免受微生物的卤代羟基联苯化合物的制备方法,卤化苯化合物的制备酰化(第一阶段),酰化化合物与卤化酚化合物的醚化(第二阶段) 根据以下反应方案,第四阶段的醚化化合物(第三阶段)和氧化化合物的水解:其中R1和R2彼此独立地为F,Cl或Br; R 3和R 4彼此独立地是氢; 或C 1 -C 4烷基; m为1〜3; n为1或2。
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