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公开(公告)号：US07888280B2
公开(公告)日：2011-02-15
申请号：US12178248
申请日：2008-07-23
申请人： Katrin Ebert , Detlev Fritsch , Herbert Plenio , Gisela Bengston
发明人： Katrin Ebert , Detlev Fritsch , Herbert Plenio , Gisela Bengston
IPC分类号： B01J31/00
CPC分类号： B01J31/1625 , B01J31/1658 , B01J35/04 , B01J35/06
摘要： A catalyst is produced by bonding a homogeneous catalyst to the surface of a catalyst support. A catalyst may include a catalyst support, a spacer molecule bonded to the catalyst support, and a homogeneous catalyst bonded to the spacer molecule. A catalyzed reaction can be carried out by providing reactants in a first phase and providing a catalyst as described herein in the first phase.
摘要翻译： 通过将均相催化剂结合到催化剂载体的表面来制备催化剂。 催化剂可以包括催化剂载体，键合到催化剂载体上的间隔分子和与间隔分子结合的均相催化剂。 催化反应可以通过在第一相中提供反应物并在第一相中提供如本文所述的催化剂来进行。
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2.发明申请New Cyclopentadienyl, Indenyl or Fluorenyl Substituted Phosphine Compounds and their Use in Catalytic Reactions 有权新的环戊二烯基，茚基或芴基取代的膦化合物及其在催化反应中的应用公开(公告)号：US20120245348A1
公开(公告)日：2012-09-27
申请号：US13437415
申请日：2012-04-02
申请人： Herbert PLENIO , Christoph FLECKENSTEIN , Renat KADYROV , Juan ALMENA , Axel MONSEES , Thomas RIERMEIER
发明人： Herbert PLENIO , Christoph FLECKENSTEIN , Renat KADYROV , Juan ALMENA , Axel MONSEES , Thomas RIERMEIER
IPC分类号： C07F9/50 , C07F19/00 , C07C45/68 , C07C41/30 , C07C209/68 , C07C201/12 , C07C253/30 , C07C231/12 , C07C303/40 , C07D213/16 , C07D213/73 , C07D401/04 , C07D295/033 , C07D295/155 , C07C1/32 , C07F9/54
CPC分类号： C07C2/88 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2231/4227 , B01J2231/4266 , B01J2231/4283 , B01J2531/824 , C07C17/26 , C07C41/30 , C07C45/62 , C07C201/12 , C07C209/68 , C07C253/30 , C07D213/16 , C07D213/22 , C07D213/73 , C07D265/30 , C07F9/5022 , C07F9/5442
摘要： Disclosed herein are phosphine compounds represented by the general formula (4): and corresponding phosphonium salts represented by the general formula (4a): Also disclosed are processes for the preparation of these phosphines and phosphonium salts as well as their use as ligands in catalytic reactions.
摘要翻译： 本文公开了由通式（4）表示的膦化合物：和由通式（4a）表示的相应的鏻盐：还公开了制备这些膦和鏻盐以及它们在催化反应中作为配体的用途的方法 。
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3.发明申请CYCLOPENTADIENYL, INDENYL OR FLUORENYL SUBSTITUTED PHOSPHINE COMPOUNDS AND THEIR USE IN CATALYTIC REACTIONS 审中-公开环戊二烯基，茚基或氟代替膦酸酯化合物及其在催化反应中的应用公开(公告)号：US20090253907A1
公开(公告)日：2009-10-08
申请号：US12375869
申请日：2007-08-14
申请人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
发明人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
IPC分类号： C07D295/155 , C07D401/04 , C07C209/68 , C07F9/54 , C07F9/50 , C07C45/61
CPC分类号： C07C2/88 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2231/4227 , B01J2231/4266 , B01J2231/4283 , B01J2531/824 , C07C17/26 , C07C41/30 , C07C45/62 , C07C201/12 , C07C209/68 , C07C253/30 , C07D213/16 , C07D213/22 , C07D213/73 , C07D265/30 , C07F9/5022 , C07F9/5442
摘要： A phosphine compound represented by general formula (1) wherein R′ and R″ independently are selected from alkyl, cycloalkyl and 2-furyl radicals, or R′ and R″ are joined together to form with the phosphorous atom a carbon-phosphorous monocycle including at least 3 carbon atoms or a carbon-phosphorous bicycle; the alkyl radicals, cycloalkyl radicals, and carbon-phosphorous monocycle being unsubstituted or substituted by at least one radical selected from the group of alkyl, cycloalkyl, aryl, alkoxy, and aryloxy radicals; Cps is a partially substituted or completely substituted cyclopentadien-1-yl group, including substitutions resulting in a fused ring system, and wherein a substitution at the 1-position of the cyclopentadien-1-yl group is mandatory when the cyclopentadien-1-yl group is not part of a fused ring system or is part of an indenyl group. These phosphines can be used as ligands in catalytic reactions.
摘要翻译： 由通式（1）表示的膦化合物，其中R'和R“独立地选自烷基，环烷基和2-呋喃基，或者R'和R”连接在一起，与磷原子一起形成碳 - 磷 包含至少3个碳原子的单环或碳磷自行车; 烷基，环烷基和碳 - 磷单环未被取代或被至少一个选自烷基，环烷基，芳基，烷氧基和芳氧基的基团取代; Cps是部分取代的或完全取代的环戊二烯-1-基，包括导致稠环系统的取代，并且其中当环戊二烯-1-基的1-位上的取代是必需的，当环戊二烯-1-基 基团不是稠环体系的一部分或是茚基基团的一部分。 这些膦可以用作催化反应中的配体。
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公开(公告)号：US5171736A
公开(公告)日：1992-12-15
申请号：US421586
申请日：1989-10-16
申请人： Dietmar Seyferth , Herbert Plenio
发明人： Dietmar Seyferth , Herbert Plenio
IPC分类号： C04B35/571 , C04B35/589 , C08G77/48 , C08G77/60 , C08G77/62 , C08G79/00 , C08G79/08 , C08L83/16
CPC分类号： C08G77/60 , C04B35/589 , C08G79/00 , C08L83/16
摘要： Preceramic polymers are prepared by mixing an organosilicon oligomer or polymer containing a multiplicity of Si--H and/or Si--N functional groups with a borane in an organic solvent for a sufficient time for the reactants to react, wherein the molar ratio of the organosilicon polymer repeat unit to borane is 15 or less.
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5.发明授权Cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions 有权环戊二烯基，茚基或芴基取代的膦化合物及其在催化反应中的应用公开(公告)号：US08618328B2
公开(公告)日：2013-12-31
申请号：US13437415
申请日：2012-04-02
申请人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
发明人： Herbert Plenio , Christoph Fleckenstein , Renat Kadyrov , Juan Almena , Axel Monsees , Thomas Riermeier
IPC分类号： C07F9/02
CPC分类号： C07C2/88 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2231/4227 , B01J2231/4266 , B01J2231/4283 , B01J2531/824 , C07C17/26 , C07C41/30 , C07C45/62 , C07C201/12 , C07C209/68 , C07C253/30 , C07D213/16 , C07D213/22 , C07D213/73 , C07D265/30 , C07F9/5022 , C07F9/5442
摘要： Disclosed herein are phosphine compounds represented by the general formula (4): and corresponding phosphonium salts represented by the general formula (4a): Also disclosed are processes for the preparation of these phosphines and phosphonium salts as well as their use as ligands in catalytic reactions.
摘要翻译： 本文公开了由通式（4）表示的膦化合物：和由通式（4a）表示的相应的鏻盐：还公开了制备这些膦和鏻盐以及它们在催化反应中作为配体的用途的方法 。
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公开(公告)号：US20090029849A1
公开(公告)日：2009-01-29
申请号：US12178248
申请日：2008-07-23
申请人： Katrin Ebert , Detlev Fritsch , Herbert Plenio , Gisela Bengtson
发明人： Katrin Ebert , Detlev Fritsch , Herbert Plenio , Gisela Bengtson
CPC分类号： B01J31/1625 , B01J31/1658 , B01J35/04 , B01J35/06
摘要： A catalyst is produced by bonding a homogeneous catalyst to the surface of a catalyst support. A catalyst may include a catalyst support, a spacer molecule bonded to the catalyst support, and a homogeneous catalyst bonded to the spacer molecule. A catalyzed reaction can be carried out by providing reactants in a first phase and providing a catalyst as described herein in the first phase.
摘要翻译： 通过将均相催化剂结合到催化剂载体的表面来制备催化剂。 催化剂可以包括催化剂载体，键合到催化剂载体上的间隔分子和与间隔分子结合的均相催化剂。 催化反应可以通过在第一相中提供反应物并在第一相中提供如本文所述的催化剂来进行。
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