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22 条记录 (耗时 0.014 秒)

    Process for producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation
    2.
    发明授权
    Process for producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation 有权

    公开(公告)号：US5973186A

    公开(公告)日：1999-10-26

    申请号：US187764

    申请日：1998-11-06

    申请人： Hideo Midorikawa ,  Naoki Sugiyama ,  Hidenori Hinago

    发明人： Hideo Midorikawa ,  Naoki Sugiyama ,  Hidenori Hinago

    IPC分类号： B01J23/18 ,  B01J8/24 ,  B01J23/20 ,  B01J23/22 ,  B01J23/28 ,  B01J27/057 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08 ,  C07C253/00

    CPC分类号： C07C253/24 ,  B01J8/1827

    摘要： Process for producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation at a temperature in the range of from 380 to 500.degree. C. in a fluidized-bed reactor containing a catalyst composition preheated to a temperature of not lower than 300.degree. C. and lower than the ammoxidation reaction temperature, the catalyst composition comprising a carrier having supported thereon an oxide catalyst comprising a compound oxide of molybdenum, vanadium, niobium and at least one element selected from tellurium and antimony, wherein the ammoxidation of propane or isobutane is preceded by a specific temperature elevation operation in which the catalyst temperature in the reactor is elevated, while supplying into the fluidized-bed reactor a molecular oxygen-containing gas together with a combustible gas capable of combustion by reaction with the molecular oxygen in the presence of said catalyst composition, until the temperature of the catalyst composition reaches said ammoxidation reaction temperature. The process of the present invention is advantageous in that the temperature elevation of the catalyst can be performed without suffering a deterioration of the catalytic activity during the temperature elevation, thereby allowing the catalyst to fully exhibit its performance.

    METHOD FOR PRODUCING GLYCOLIC ACID
    3.
    发明申请
    METHOD FOR PRODUCING GLYCOLIC ACID 有权
    生产甘油酸的方法

    公开(公告)号：US20120094344A1

    公开(公告)日：2012-04-19

    申请号：US13330383

    申请日：2011-12-19

    申请人： Hidenori HINAGO ,  Hajime Nagahara ,  Toshiya Aoki

    发明人： Hidenori HINAGO ,  Hajime Nagahara ,  Toshiya Aoki

    IPC分类号： C12P7/42

    CPC分类号： C12P7/42 ,  C07C51/08 ,  C07C51/412 ,  C07C59/06

    摘要： Provided is a production method of glycolic acid having a first step of preparing glycolonitrile from formaldehyde and hydrocyanic acid and a second step of hydrolyzing the glycolonitrile into glycolic acid directly or via a glycolate salt, which method can produce glycolic acid in easy production and purification steps while consuming less energy. In the production method, by carrying out the first and second steps continuously or by storing the glycolonitrile obtained in the first step at pH 4 or less and carrying out a hydrolysis reaction of the second step at from pH 5 to 9, a production yield of glycolic acid, activity for the production of glycolic acid and accumulated concentration of glycolic acid are improved, resulting in the production of glycolic acid having an improved purity and quality.

    摘要翻译： 本发明提供了一种乙醇酸的制备方法，其具有由甲醛和氢氰酸制备乙醇腈的第一步骤，第二步是直接或通过乙醇酸盐将乙醇腈水解成乙醇酸，该方法可以在容易的生产和纯化步骤中生产乙醇酸 同时消耗更少的能量。 在制造方法中，通过连续进行第一和第二工序，或者将第一工序中得到的乙醇腈的pH保持在4以下，进行pH5〜9的第二工序的水解反应， 乙醇酸，乙醇酸的生成活性和乙醇酸的累积浓度得到改善，导致纯度和质量提高的乙醇酸的生产。

    Method for producing glycolic acid
    4.
    发明申请
    Method for producing glycolic acid 有权
    乙醇酸生产方法

    公开(公告)号：US20090118541A1

    公开(公告)日：2009-05-07

    申请号：US11921072

    申请日：2006-05-25

    申请人： Hidenori Hinago ,  Hajime Nagahara ,  Toshiya Aoki

    发明人： Hidenori Hinago ,  Hajime Nagahara ,  Toshiya Aoki

    IPC分类号： C07C59/06 ,  C12P7/42

    CPC分类号： C12P7/42 ,  C07C51/08 ,  C07C51/412 ,  C07C59/06

    摘要： Provided is a production method of glycolic acid having a first step of preparing glycolonitrile from formaldehyde and hydrocyanic acid and a second step of hydrolyzing the glycolonitrile into glycolic acid directly or via a glycolate salt, which method can produce glycolic acid in easy production and purification steps while consuming less energy. In the production method, by carrying out the first and second steps continuously or by storing the glycolonitrile obtained in the first step at pH 4 or less and carrying out a hydrolysis reaction of the second step at from pH 5 to 9, a production yield of glycolic acid, activity for the production of glycolic acid and accumulated concentration of glycolic acid are improved, resulting in the production of glycolic acid having an improved purity and quality.

    摘要翻译： 本发明提供了一种乙醇酸的制备方法，其具有由甲醛和氢氰酸制备乙醇腈的第一步骤，第二步是直接或通过乙醇酸盐将乙醇腈水解成乙醇酸，该方法可以在容易的生产和纯化步骤中生产乙醇酸 同时消耗更少的能量。 在制造方法中，通过连续进行第一和第二工序，或者将第一工序中得到的乙醇腈的pH保持在4以下，进行pH5〜9的第二工序的水解反应， 乙醇酸，乙醇酸的生成活性和乙醇酸的累积浓度得到改善，导致纯度和质量提高的乙醇酸的生产。

    Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation
    6.
    发明授权
    Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation 有权
    用于通过氨氧化从丙烷或异丁烷生产丙烯腈或甲基丙烯腈的氨氧化催化剂

    公开(公告)号：US6143916A

    公开(公告)日：2000-11-07

    申请号：US453698

    申请日：1999-12-03

    申请人： Hidenori Hinago ,  Satoru Komada

    发明人： Hidenori Hinago ,  Satoru Komada

    IPC分类号： B01J23/16 ,  B01J23/20 ,  B01J27/057 ,  C07C253/24 ,  C07C255/08 ,  C07C253/00

    CPC分类号： B01J27/0576 ,  B01J23/16 ,  B01J23/20 ,  C07C253/24 ,  B01J2523/00 ,  Y02P20/52

    摘要： An ammoxidation catalyst comprising a compound oxide of Mo, V, Nb, and at least one element selected from the group consisting of Te and Sb, wherein the compound catalyst exhibits an X-ray diffraction pattern satisfying the following relationship:0.40.ltoreq.R.ltoreq.0.75wherein R represents the intensity ratio defined by the following formula:R=P.sub.1 /(P.sub.1 +P.sub.2)wherein P.sub.1 and P.sub.2 represent the intensities of peak 1 and peak 2 appearing at diffraction angles (2.theta.) of 27.3.+-.0.3.degree. and 28.2.+-.0.3.degree., respectively.By the use of the ammoxidation catalyst of the present invention, not only can acrylonitrile or methacrylonitrile be produced in high yield, but also oxidative decomposition of ammonia feedstock into nitrogen can be effectively suppressed, thereby enabling an improved utilization of ammonia as a feedstock.

    摘要翻译： 包含Mo，V，Nb的复合氧化物和选自Te和Sb中的至少一种元素的氨氧化催化剂，其中所述化合物催化剂表现出满足以下关系的X射线衍射图：0.40

    Method for producing glycolic acid
    7.
    发明授权
    Method for producing glycolic acid 有权

    公开(公告)号：US08956837B2

    公开(公告)日：2015-02-17

    申请号：US13330383

    申请日：2011-12-19

    申请人： Hidenori Hinago ,  Hajime Nagahara ,  Toshiya Aoki

    发明人： Hidenori Hinago ,  Hajime Nagahara ,  Toshiya Aoki

    IPC分类号： C12P7/42 ,  C07C59/06 ,  C07C51/08 ,  C07C51/41

    CPC分类号： C12P7/42 ,  C07C51/08 ,  C07C51/412 ,  C07C59/06

    摘要： Provided is a production method of glycolic acid having a first step of preparing glycolonitrile from formaldehyde and hydrocyanic acid and a second step of hydrolyzing the glycolonitrile into glycolic acid directly or via a glycolate salt, which method can produce glycolic acid in easy production and purification steps while consuming less energy. In the production method, by carrying out the first and second steps continuously or by storing the glycolonitrile obtained in the first step at pH 4 or less and carrying out a hydrolysis reaction of the second step at from pH 5 to 9, a production yield of glycolic acid, activity for the production of glycolic acid and accumulated concentration of glycolic acid are improved, resulting in the production of glycolic acid having an improved purity and quality.

    Method for producing glycolic acid
    9.
    发明授权
    Method for producing glycolic acid 有权
    乙醇酸生产方法

    公开(公告)号：US08106238B2

    公开(公告)日：2012-01-31

    申请号：US11921072

    申请日：2006-05-25

    申请人： Hidenori Hinago ,  Hajime Nagahara ,  Toshiya Aoki

    发明人： Hidenori Hinago ,  Hajime Nagahara ,  Toshiya Aoki

    IPC分类号： C07C59/00

    CPC分类号： C12P7/42 ,  C07C51/08 ,  C07C51/412 ,  C07C59/06

    摘要： Provided is a production method of glycolic acid having a first step of preparing glycolonitrile from formaldehyde and hydrocyanic acid and a second step of hydrolyzing the glycolonitrile into glycolic acid directly or via a glycolate salt, which method can produce glycolic acid in easy production and purification steps while consuming less energy. In the production method, by carrying out the first and second steps continuously or by storing the glycolonitrile obtained in the first step at pH 4 or less and carrying out a hydrolysis reaction of the second step at from pH 5 to 9, a production yield of glycolic acid, activity for the production of glycolic acid and accumulated concentration of glycolic acid are improved, resulting in the production of glycolic acid having an improved purity and quality.

    摘要翻译： 本发明提供了一种乙醇酸的制备方法，其具有由甲醛和氢氰酸制备乙醇腈的第一步骤，第二步是直接或通过乙醇酸盐将乙醇腈水解成乙醇酸，该方法可以在容易的生产和纯化步骤中生产乙醇酸 同时消耗更少的能量。 在制造方法中，通过连续进行第一和第二工序，或者将第一工序中得到的乙醇腈的pH保持在4以下，进行pH5〜9的第二工序的水解反应， 乙醇酸，乙醇酸的生成活性和乙醇酸的累积浓度得到改善，导致纯度和质量提高的乙醇酸的生产。

    NITROGEN-CONTAINING CARBON MATERIAL AND PROCESS FOR PRODUCING THE SAME
    10.
    发明申请
    NITROGEN-CONTAINING CARBON MATERIAL AND PROCESS FOR PRODUCING THE SAME 有权
    含氮的碳材料及其生产方法

    公开(公告)号：US20100111806A1

    公开(公告)日：2010-05-06

    申请号：US12593594

    申请日：2008-03-27

    申请人： Hidenori Hinago

    发明人： Hidenori Hinago

    IPC分类号： C01C3/02

    CPC分类号： C01B21/0605 ,  C01B3/0015 ,  C01B21/087 ,  H01G11/32 ,  H01G11/34 ,  H01M4/587 ,  Y02E60/13 ,  Y02E60/328 ,  Y10T29/49108

    摘要： The present invention provides a process for producing a nitrogen-containing carbon material, comprising a first step of subjecting azulmic acid to a first heat treatment in an oxygen-containing gas atmosphere, thereby preparing a heat-treated product, and a second step of subjecting the heat-treated product to a second heat treatment in an inert gas atmosphere.

    摘要翻译： 本发明提供一种含氮碳材料的制造方法，其特征在于，包括：在含氧气体气氛中进行第一次热处理，由此制备热处理物的第一工序， 将热处理产物在惰性气体气氛中进行第二次热处理。