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    Metal complex compositions and use thereof in dye sensitized solar cells
    2.
    发明申请
    Metal complex compositions and use thereof in dye sensitized solar cells 审中-公开
    金属络合物组合物及其在染料敏化太阳能电池中的应用

    公开(公告)号：US20070017569A1

    公开(公告)日：2007-01-25

    申请号：US11188575

    申请日：2005-07-25

    申请人： John Gui ,  Oltea Siclovan ,  Mukundan Thelakkat ,  James Spivack

    发明人： John Gui ,  Oltea Siclovan ,  Mukundan Thelakkat ,  James Spivack

    IPC分类号： C07F15/00 ,  H01L31/00

    CPC分类号： C07F15/0053 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0061 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

    摘要： The present invention provides in one aspect a composition having at least one metal complex, such that the metal complex comprises at least one metal atom, at least one first organic ligand comprising at least one triarylamine group, at least one second ligand comprising at least one acidic group, and at least one thiocyanate or isothiocyanate ligand. This composition may be disposed on a semiconductor layer which is further disposed on an electrically conductive surface to provide a dye-sensitized electrode. The dye-sensitized electrode can be assembled together with a counter electrode and a redox electrolyte to provide a dye-sensitized solar cell.

    摘要翻译： 本发明在一个方面提供了具有至少一种金属络合物的组合物，使得金属络合物包含至少一种金属原子，至少一种包含至少一种三芳基胺基团的第一有机配体，至少一种第二配体，其包含至少一种 酸性基团和至少一种硫氰酸酯或异硫氰酸酯配体。 该组合物可以设置在进一步设置在导电表面上以提供染料敏化电极的半导体层上。 染料敏化电极可以与对电极和氧化还原电解质一起组装以提供染料敏化太阳能电池。

    Opto-electronic devices exhibiting enhanced efficiency
    4.
    发明申请
    Opto-electronic devices exhibiting enhanced efficiency 审中-公开
    表现出提高效率的光电器件

    公开(公告)号：US20070215879A1

    公开(公告)日：2007-09-20

    申请号：US11384769

    申请日：2006-03-20

    申请人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

    发明人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

    IPC分类号： H01L33/00 ,  C09K9/00

    CPC分类号： C09K9/02 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1044 ,  H01G9/2059 ,  H01L51/4206 ,  H01L51/5032 ,  H01L51/5221 ,  Y02E10/542

    摘要： Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I) wherein R1-R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical is disclosed and wherein X+ is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

    摘要翻译： 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机铵盐接触。 在某些实施方案中，有机铵盐具有结构（I），其中R 1至R 4各自独立地为C 1 -C 3 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 20脂肪族基团， 20芳族基团，其中X +选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

    Compositions and use thereof in dye sensitized solar cells
    5.
    发明申请
    Compositions and use thereof in dye sensitized solar cells 审中-公开
    染料敏化太阳能电池的组成和用途

    公开(公告)号：US20070000539A1

    公开(公告)日：2007-01-04

    申请号：US11171713

    申请日：2005-06-30

    申请人： John Gui ,  Oltea Siclovan ,  James Spivack ,  Fuyou Li ,  Xianghong Li ,  Men Zhang

    发明人： John Gui ,  Oltea Siclovan ,  James Spivack ,  Fuyou Li ,  Xianghong Li ,  Men Zhang

    IPC分类号： H01L31/00

    CPC分类号： C07F15/025 ,  C07F15/0026 ,  C07F15/0053 ,  C07F15/008

    摘要： The present invention provides in one aspect a composition having at least one metal complex, such that the metal complex comprises at least one metal atom, a phenanthroline-based first ligand and a second ligand comprising at least one acidic group, and at least two coordinative nitrogen atoms capable of simultaneous binding to the metal atom. This composition may be disposed on a semiconductor layer which is further disposed on an electrically conductive surface to provide a dye-sensitized electrode. The dye-sensitized electrode can be assembled together with a counter electrode and a redox electrolyte to provide a dye-sensitized solar cell.

    摘要翻译： 本发明在一个方面提供具有至少一种金属络合物的组合物，使得金属络合物包含至少一种金属原子，基于菲咯啉的第一配体和包含至少一个酸性基团的第二配体和至少两个配位体 能同时结合金属原子的氮原子。 该组合物可以设置在进一步设置在导电表面上以提供染料敏化电极的半导体层上。 染料敏化电极可以与对电极和氧化还原电解质一起组装以提供染料敏化太阳能电池。

    Passivated, dye-sensitized oxide semiconductor electrode, solar cell using same, and method
    6.
    发明申请
    Passivated, dye-sensitized oxide semiconductor electrode, solar cell using same, and method 审中-公开
    钝化染料敏化氧化物半导体电极，使用其的太阳能电池和方法

    公开(公告)号：US20060005877A1

    公开(公告)日：2006-01-12

    申请号：US10884028

    申请日：2004-07-06

    申请人： James Spivack ,  Shellie Gasaway ,  Oltea Siclovan

    发明人： James Spivack ,  Shellie Gasaway ,  Oltea Siclovan

    IPC分类号： H01L31/00

    CPC分类号： H01G9/2031 ,  H01G9/2004 ,  H01G9/2059 ,  H01L51/0086 ,  Y02E10/542

    摘要： Disclosed is a dye-sensitized oxide semiconductor electrode comprising an electrically conductive substrate, an oxide semiconductor film provided on a surface of said electrically conductive substrate, and a sensitizing dye adsorbed on said film, wherein the oxide semiconductor film has been further treated with at least one silanizing agent comprising the partial structure R1—Si—OR2, wherein R1 and R2 are each independently alkyl groups, or R1 is an alkyl group and R2 is hydrogen or aryl. Also disclosed are solar cells comprising said electrode and a method for improving the efficiency of the solar cells. The solar cells exhibit improved efficiency and other beneficial properties compared to similar cells not having the passivated electrode.

    摘要翻译： 公开了一种染料敏化氧化物半导体电极，其包括导电基板，设置在所述导电基板的表面上的氧化物半导体膜和吸附在所述膜上的增感染料，其中所述氧化物半导体膜至少被进一步处理 一种含有部分结构R 1 -Si-OR 2的硅烷化剂，其中R 1和R 2均为 每个独立的烷基或R 1是烷基，R 2是氢或芳基。 还公开了包括所述电极的太阳能电池和用于提高太阳能电池的效率的方法。 与不具有钝化电极的类似细胞相比，太阳能电池显示出改善的效率和其它有益特性。

    Opto-electronic devices exhibiting enhanced efficiency
    8.
    发明申请
    Opto-electronic devices exhibiting enhanced efficiency 审中-公开
    表现出提高效率的光电器件

    公开(公告)号：US20070215865A1

    公开(公告)日：2007-09-20

    申请号：US11384770

    申请日：2006-03-20

    申请人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

    发明人： Jie Liu ,  James Cella ,  Larry Lewis ,  Anil Duggal ,  James Spivack ,  Qing Ye

    IPC分类号： H01L51/00 ,  H01L51/54

    CPC分类号： H05B33/14 ,  H01G9/2004 ,  H01L51/0037 ,  H01L51/5032 ,  H01L51/5231 ,  Y02E10/542

    摘要： Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic phosphonium salt. In certain embodiments, the organic phosphonium salt has structure (I) wherein R1-R4 are independently at each occurrence a C1-C20 aliphatic radical, a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical is disclosed and wherein X− is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.

    摘要翻译： 本文描述的是一种有机光电子器件，其包括：包含至少一种零价金属的阴极; 阳极; 光电活性有机材料; 其中所述阴极与至少一种有机鏻盐接触。 在某些实施方案中，有机鏻盐具有结构（I），其中R 1至R 4各自独立地为C 1 -C 3 20脂肪族基团，C 3 -C 20脂环族基团或C 3 -C 20脂肪族基团， 20芳族基团，其中X - 选自一价无机阴离子，一价有机阴离子，多价无机阴离子，多价有机阴离子及其混合物。

    Molecular photovoltaics, method of manufacture and articles derived therefrom
    9.
    发明申请
    Molecular photovoltaics, method of manufacture and articles derived therefrom 审中-公开
    分子光伏，制造方法和从其衍生的物品

    公开(公告)号：US20060021647A1

    公开(公告)日：2006-02-02

    申请号：US10900624

    申请日：2004-07-28

    申请人： John Gui ,  James Spivack ,  Anil Duggal ,  James Cella ,  Azar Alizadeh ,  Aharon Yakimov

    发明人： John Gui ,  James Spivack ,  Anil Duggal ,  James Cella ,  Azar Alizadeh ,  Aharon Yakimov

    IPC分类号： H01L21/00 ,  H01L31/00

    CPC分类号： H01L51/4253 ,  B82Y10/00 ,  B82Y30/00 ,  H01L51/0034 ,  H01L51/0045 ,  H01L51/005 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0595 ,  H01L51/4206 ,  H01L51/426 ,  Y02E10/549 ,  Y02P70/521

    摘要： Disclosed herein is a photovoltaic cell comprising an absorber that can absorb electromagnetic radiation; a first substrate comprising a first conductive surface; a second substrate comprising a second conductive surface that is opposed to the first conductive surface and faces the first conductive surface of the first substrate; an electron transporter that is in electrical communication with the second conductive surface of the second substrate, but is electrically insulated from the first substrate; a hole transporter that is in electrical communication with the first conductive surface of the first substrate, but is electrically insulated from the second substrate; wherein the hole transporter and/or the electron transporter are chemically bonded to an electrically insulating sheath; and wherein the hole transporter and/or the electron transporter are chemically bonded to the absorber.

    摘要翻译： 本文公开了一种光伏电池，其包括可吸收电磁辐射的吸收体; 第一基板，包括第一导电表面; 第二基板，包括与第一导电表面相对并面向第一基板的第一导电表面的第二导电表面; 电子输送器，其与第二基板的第二导电表面电连通，但与第一基板电绝缘; 孔传送器，其与第一基板的第一导电表面电连通，但与第二基板电绝缘; 其中所述空穴传输体和/或电子转运体化学键合到电绝缘鞘; 并且其中所述空穴传输体和/或电子转运体化学键合到所述吸收体。