摘要:
Disclosed are polyestercarbonate copolymers comprising a carbonate unit of Formula (I), an ITR ester unit of Formula (V), and optionally a different carbonate unit of Formula (VI): wherein Ra, Rb, p, q, A, h, j, k, Rc, r, and R1 are as described herein. The polyestercarbonate copolymers have a combination of scratch resistance, good flow, and good weatherability.
摘要:
Disclosed are polymer compositions including polycarbonates, polyphosphonates, copoly(phosphonate carbonate)s, and organic salts and/or silicone containing compounds that exhibit a superior combination of properties compared to prior art.
摘要:
A method of making a thermoplastic composition comprises melt blending a reaction mixture comprising a first polycarbonate comprising repeat units derived from monoaryl monomers (II) and (III) and a diaryl monomer (IV), wherein the sum of the mole percent of the repeat units derived from monomers (II) and (III) is greater than or equal to 30 mole percent, and the mole percent of the repeat units derived from monomer (IV) is 5 to 70 mole percent, each based on the total moles the repeat units derived from monomers (II), (III), and (IV), and the total weight of the repeat units derived from monomers (II), (III), and (IV) is greater than or equal to 90 wt. % of the first polycarbonate; and an additional polycarbonate, comprising 50 to 100 mole percent of repeat units derived from a bisphenol cyclohexane.
摘要:
Thermoplastic polyurethanes (TPUs) formulations including phosphonate oligomers, phosphonate co-oligomers, phosphonate polymers, or phosphonate containing copolymers which exhibit an excellent combination of properties including optical transparency and melt flow without significant reduction in other important physical or mechanical properties and exceptional fire resistance are described herein.
摘要:
A method of increasing the branching and polydispersity of a polycarbonate includes the steps of: (a) including in the polycarbonate at least one species of an alkyl substituted monomer, and (b) treating the polycarbonate at an elevated temperature and for a sufficient time to increase the branching and polydispersity relative to an otherwise equivalent polycarbonate without alkyl substituents.
摘要:
A melt polymerized polycarbonate comprising repeat units in the polycarbonate derived from the melt polymerization of monomers (II) and/or (III), monomer (IV), and optionally monomer (VIII), wherein monomers (II) and (III) are diaryl dihydroxy compounds, monomer (IV) is a sterically hindered dihydroxy compound, and monomer (VIII) is a non-sterically hindered dihydroxy diaryl compound; wherein the mole ratio of repeat units in the polycarbonate derived from monomers [(II)+(III)]:(IV):(VIII) is 15-70:1-85:0-50, the sum of the mole percent of repeat units in the polycarbonate derived from monomers [(II)+(III)]+(IV) is greater than or equal to 50 mole %, and the sum of the mole percent of units in the polycarbonate derived from monomers [(II)+(III)]+(IV) +(VIII) is 100 mole %; and wherein the polycarbonate has an L* value that is at least 1 L* unit value higher than the same polycarbonate in which monomer (IV) is replaced by bisphenol A.
摘要:
A silylated dihydroxy aromatic compound of the formula (1a); wherein Ga and Gb are each independently C1-12 alkyl, —OSi(C1-12 alkyl)3, C1-12 arylalkyl, or —OSi(C1-12 arylalkyl)3; Za and Zb are each independently a straight or branched C2-18 alkylene, a C8-18 arylalkylene, or a C8-18 alkylarylene, Xa is a direct bond, a heteroatom-containing group, or a C1-18 organic group, and r and s are each independently 1 or 2 is disclosed.
摘要:
Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound)+(total moles of dihydroxy compound)) of less than or equal to 0.5.
摘要:
A polycarbonate copolymer comprising90 to 100 mol % of units derived from a cyclohexylidene bisphenol of the formula wherein Ra′ and Rb′ are each independently C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4;2 to 35 wt % of units derived from a polysiloxane diol of the formulas or a combination thereof, wherein Ar is a substituted or unsubstituted C6-36 arylene group, each R is the same or different C1-13 monovalent organic group, each R6 is the same or different divalent C1-C30 organic group, and E is an integer from 2 to 100; and0 to 10 mol % of units derived from a dihydroxy aromatic compound of formula (3) wherein Ra and Rb are each independently halogen, p and q are each independently integers of 0 to 4, and the dihydroxy aromatic compound of formula (3) is not the same as the cyclohexylidene bisphenol or the polysiloxane diols.
摘要:
A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.