Self-etching dental materials based on (METH) acrylamide phosphates
    1.
    发明申请
    Self-etching dental materials based on (METH) acrylamide phosphates 有权
    基于(METH)丙烯酰胺磷酸盐的自蚀牙科材料

    公开(公告)号:US20060135719A1

    公开(公告)日:2006-06-22

    申请号:US11211938

    申请日:2005-08-25

    IPC分类号: C08F120/54

    摘要: Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicylic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    摘要翻译: 可聚合的牙科材料,其特征在于它含有至少一种下列通式(I)的(甲基)丙烯酰胺磷酸酯:其中R 1是H或CH 3; R 2是H或C 1 -C 4烷基,或与其键合的氮原子一起形成一个或多个 属于R 3或R 3'杂原子的杂原子; R 3,R 3,R 3'彼此独立地是直链或支链的脂族C 1 -C 50 - 基团 具有m + n或p + n的化合价,m + n或p + n的芳族C 6 -C 18 - 基团,或脂环族基团, 芳烷基或杂环C 3 -C 18 - 基团,其价态为m + n或p + n,其中基团或基团的碳链可以被O, S,CONR 4,OCONH,或与一个或多个属于R 2的原子和氮原子一起形成,R 2 O 2 >键合杂环,如果p = 0,则R 3'为H,R 4为H,C 1 -C 3 C 10 -C 12烷基,C 6 -C 12芳基,C 6 -C 10芳烷基或C 6 -C 12烷基 二元C 4 -C 12 - 基团; 如果p = 0,则n为1,2,3或4,如果p <0,则为1或2; m为1,2,3或4; p是0,1,2,3或4; x是0或S.

    Self-etching dental materials based on (METH) acrylamide phosphates
    2.
    发明授权
    Self-etching dental materials based on (METH) acrylamide phosphates 有权
    基于(METH)丙烯酰胺磷酸盐的自蚀牙科材料

    公开(公告)号:US07622538B2

    公开(公告)日:2009-11-24

    申请号:US11211938

    申请日:2005-08-25

    IPC分类号: C08F20/58 C08F20/60

    摘要: Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-10 aralkyl or a bicylic C4-C12 radial; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p ≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    摘要翻译: 可聚合牙科材料,其特征在于其含有至少一种下列通式(I)的(甲基)丙烯酰胺磷酸酯:其中R1是H或CH3; R2是H或C1-C4烷基或与其键合的氮原子一起形成一个或多个属于R3或R3'杂原子的原子; R 3,R 3'彼此独立地为具有m + n或p + n价的直链或支链脂族C 1 -C 50基团,价数为m + n或p + n的芳族C 6 -C 18基团或 脂环族,芳脂族或杂环C 3 -C 18基,其价态为m + n或p + n,其中基团或基团的碳链可被O,S,CONR 4,OCONH中断,或与一个或多个原子一起形成 属于R2和氮原子,R 2与杂环结合,如果p = 0,则R3'为H,R4为H,C1-C10烷基,C6-C12芳基,C6-10芳烷基或双 C4-C12径向; 如果p = 0,则n为1,2,3或4,如果p为0,则为1或2; m为1,2,3或4; p是0,1,2,3或4; x是0或S.

    Dental materials based on ring-opening polymerizable acid monomers
    6.
    发明申请
    Dental materials based on ring-opening polymerizable acid monomers 审中-公开
    基于开环聚合酸单体的牙科材料

    公开(公告)号:US20070287792A1

    公开(公告)日:2007-12-13

    申请号:US11585280

    申请日:2006-10-24

    IPC分类号: C08L31/00

    摘要: Dental material which contains at least one radically polymerizable monomer according to the general formula (I): in which PG is a cyclic, ring-opening polymerizable group; X1 is absent, O, S, is an ester, amide or urethane group; X2 is absent with, O, S, is an ester, amide or urethane group; Y is absent, O, S, is an ester, amide or urethane group; R is an organic radical with a valency of (n+m), with 1 to 35 carbon atoms and 0 to 8 heteroatoms, the H atoms of which can be wholly or partially substituted by F atoms; R1 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; R2 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; n is 1, 2, 3, 4, 5 or 6; m is 1, 2 or 3; HG is —P═O(OH)2; —P═O(OH)(OR14); —O—P═O(OH)2, —O—P═O(OH)(OR15) or —SO2OH, wherein R14 is a C1-C15 alkyl radical, phenyl or benzyl radical; and R15 is a C1-C15 alkyl radical, phenyl or benzyl radical.

    摘要翻译: 含有至少一种根据通式(I)的可自由基聚合的单体的牙科材料:其中PG是环状可开环聚合基团; X 1不存在,O,S是酯,酰胺或氨基甲酸酯基; O,S不是酯,酰胺或氨基甲酸酯基; Y不存在,O,S是酯,酰胺或氨基甲酸酯基; R为化合价为(n + m),有1至35个碳原子和0至8个杂原子的有机基团,其H原子可以被F原子全部或部分取代; R 1不存在或可被O原子间断的C 1 -C 16亚烷基; R 2不存在或可被O原子间隔的C 1 -C 16亚烷基; n为1,2,3,4,5或6; m为1,2或3; HG是-P-O(OH)2; -P-O(OH)(OR 14); -OPO(OH)2,-OPO(OH)(OR 15)或-SO 2 OH,其中R 14, CH 2是C 1 -C 15烷基,苯基或苄基; R 15是C 1 -C 15烷基,苯基或苄基。

    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    9.
    发明授权
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N,O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号:US07932303B2

    公开(公告)日:2011-04-26

    申请号:US11898338

    申请日:2007-09-11

    摘要: A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    摘要翻译: 材料至少包含式(I)的可聚合的N,O-官能化的丙烯酸羟基酰胺,其中A是n + m价的直链或支链脂族C1至C50基团,其中碳链可以被O ,S,-CO-O-,CO-NH,O-CO-NH或NH-CO-NH,n + m价芳族C6至C18基或n + m价环脂族或杂环C3至C18基 其中基团可以携带一个或多个取代基,Y不存在,或者是O,S,酯,酰胺或氨基甲酸酯基,R 1是氢,可以携带一个的脂族C1至C20烷基或C3至C8环烷基 或更多的取代基,R 2是H或C 1至C 10烷基,R 3不存在或是可被O,HG不存在的C 1至C 16亚烷基,是-COOH,-P = O(OH) 2; -POO(OH)(OR4); -O-P = O(OH)2,-SO 2 OH或-O-P = O(OH)(OR 4),R 4为C 1至C 15烷基,苯基或苄基,n为1至5的数, ma号从0到3。