REINFORCED MATRIX IMPREGNATED WITH ELECTROLYTES FOR MOLTEN CARBONATE FUEL CELL AND FABRICATION METHOD THEREOF
    3.
    发明申请
    REINFORCED MATRIX IMPREGNATED WITH ELECTROLYTES FOR MOLTEN CARBONATE FUEL CELL AND FABRICATION METHOD THEREOF 有权
    用于碳酸钙燃料电池的电解质的增强基质及其制造方法

    公开(公告)号:US20110287333A1

    公开(公告)日:2011-11-24

    申请号:US13127027

    申请日:2009-10-29

    IPC分类号: H01M8/14 H01M8/00

    摘要: The present invention relates to an electrolyte-impregnated, reinforced matrix for molten carbonate fuel cells and a manufacturing method thereof. According to the invention, the electrolyte-impregnated matrix, which comprises both the electrolyte and the reinforcing particles including a metal and an oxide, is manufactured by adding the electrolyte, as required per unit cell of a fuel cell, and the reinforcing particles including the metal and the oxide, to a slurry during the matrix preparation step, and subjecting the resulting slurry to a tape casting process. By doing so, the matrix stacking operation is facilitated, and the matrix manufacturing process is simplified. In addition, cracking caused by the difference in thermal expansion coefficient between an electrolyte sheet and the matrix can be suppressed, and thermal shock occurring during operation of the fuel cell stack can be reduced, thus improving the performance and lifetime of the fuel cell.

    摘要翻译: 本发明涉及一种用于熔融碳酸盐燃料电池的电解质浸渍的增强基体及其制造方法。 根据本发明,包括电解质和包括金属和氧化物的增强颗粒的电解质浸渍基质是通过根据燃料电池单位电池的需要加入电解质,并且包括 金属和氧化物,在基质制备步骤中与浆料接触,并将所得浆料进行带铸造过程。 通过这样做,矩阵堆叠操作便利,矩阵制造过程简化。 此外,可以抑制由电解质片和基体之间的热膨胀系数的差异引起的破裂,并且可以降低在燃料电池堆的操作期间发生的热冲击,从而提高燃料电池的性能和寿命。

    METHOD AND APPARATUS FOR PREPARING VINYL CHLORIDE USING ETHANE AND 1,2-DICHLOROETHANE

    公开(公告)号:US20070112234A1

    公开(公告)日:2007-05-17

    申请号:US11560069

    申请日:2006-11-15

    IPC分类号: C07C17/10

    摘要: The present invention provides a method and apparatus for preparing vinyl chloride in which reaction yield is improved and problems caused by coke generated during reactions can be solved. According to an aspect of the present invention, there is provided a method of preparing vinyl chloride comprising: supplying chlorine gas and ethane to an ethane chlorination reaction region disposed in a lower portion of a pyrolysis reactor in which solid particles exist; performing an ethane chlorination reaction by contacting the chlorine gas and ethane with solid particles such that a product of the ethane chlorination reaction and the solid particles rise toward an upper portion of the pyrolysis reactor at the same time, and depositing coke produced during the ethane chlorination reaction on the solid particles; performing a pyrolysis reaction in a pyrolysis reaction region disposed in an upper portion of the pyrolysis reactor by contacting a product of the ethane chlorination reaction with the solid particles such that the product of the ethane chlorination reaction and the solid particles rise up at the same time, and depositing coke produced during the pyrolysis reaction on the solid particles; separating solid particles obtained from the pyrolysis reaction and a product of the pyrolysis reaction in a separator; moving the separated solid particles to a regeneration reactor, and then burning coke deposited on the solid particles to regenerate the solid particles; and resupplying the regenerated solid particles to the pyrolysis reactor. According to another aspect of the present invention, there is provided an apparatus of preparing vinyl chloride comprising: a pyrolysis reactor comprising an ethane chlorination reaction region in a lower portion thereof and a pyrolysis reaction region in an upper portion thereof; a separator that separates a product of a pyrolysis reaction and solid particles; and a regeneration reactor that regenerates the separated solid particles by burning. When vinyl chloride is prepared using the method and apparatus according to the present invention, reaction yield is improved, and coke production and following coke accumulation in reactor can be inhibited.

    Reinforced matrix impregnated with electrolytes for molten carbonate fuel cell and fabrication method thereof
    7.
    发明授权
    Reinforced matrix impregnated with electrolytes for molten carbonate fuel cell and fabrication method thereof 有权
    用熔融碳酸盐燃料电池电解质浸渍的强化基体及其制造方法

    公开(公告)号:US09160023B2

    公开(公告)日:2015-10-13

    申请号:US13127027

    申请日:2009-10-29

    IPC分类号: H01M8/14 H01M8/02

    摘要: The present invention relates to an electrolyte-impregnated, reinforced matrix for molten carbonate fuel cells and a manufacturing method thereof. According to the invention, the electrolyte-impregnated matrix, which comprises both the electrolyte and the reinforcing particles including a metal and an oxide, is manufactured by adding the electrolyte, as required per unit cell of a fuel cell, and the reinforcing particles including the metal and the oxide, to a slurry during the matrix preparation step, and subjecting the resulting slurry to a tape casting process. By doing so, the matrix stacking operation is facilitated, and the matrix manufacturing process is simplified. In addition, cracking caused by the difference in thermal expansion coefficient between an electrolyte sheet and the matrix can be suppressed, and thermal shock occurring during operation of the fuel cell stack can be reduced, thus improving the performance and lifetime of the fuel cell.

    摘要翻译: 本发明涉及一种用于熔融碳酸盐燃料电池的电解质浸渍的增强基体及其制造方法。 根据本发明,包括电解质和包括金属和氧化物的增强颗粒的电解质浸渍基质是通过根据燃料电池单位电池的需要加入电解质,并且包括 金属和氧化物,在基质制备步骤中与浆料接触,并将所得浆料进行带铸造过程。 通过这样做,矩阵堆叠操作便利,矩阵制造过程简化。 此外,可以抑制由电解质片和基体之间的热膨胀系数的差异引起的破裂,并且可以降低在燃料电池堆的操作期间发生的热冲击,从而提高燃料电池的性能和寿命。