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公开(公告)号：US07304153B1
公开(公告)日：2007-12-04
申请号：US08360184
申请日：1994-12-20
申请人： Donald Benjamin Appleby , David Joseph Bruno, Jr. , Patrick Joseph Corrigan , John Keeney Howie , Ju-Nan Kao , Scott David Pearson , Richard Gerard Schafermeyer , Glen Reid Wyness
发明人： Donald Benjamin Appleby , David Joseph Bruno, Jr. , Patrick Joseph Corrigan , John Keeney Howie , Ju-Nan Kao , Scott David Pearson , Richard Gerard Schafermeyer , Glen Reid Wyness
摘要： Polyol polyesters useful as nondigestible fat substitutes are prepared by improved heterogeneous interesterification processes between fatty acid esters of easily removable alcohol and polyol characterized by having one or more improvements such as using low levels of soap emulsifying agent, catalyst, and/or excess fatty acid ester; reducing the size of the polyol by mechanical means; removing extraneous particulate material during the reaction; using low temperature and/or high pressure and compensating by increasing the mass transfer area; and/or using backmixing in the initial stage(s) and plug-flow conditions in the final stage(s).
摘要翻译： 用作不易消化的脂肪替代物的多元醇聚酯通过改进的容易除去的醇和多元醇的脂肪酸酯之间的异构酯交换方法来制备，其特征在于具有一个或多个改进，例如使用低含量的皂乳化剂，催化剂和/或过量的脂肪酸酯 ; 通过机械方式减少多元醇的大小; 在反应过程中除去外来颗粒物质; 使用低温和/或高压，并通过增加传质面积进行补偿; 和/或在最终阶段中的初始阶段和插件流条件下使用回混。
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公开(公告)号：US5338487A
公开(公告)日：1994-08-16
申请号：US9369
申请日：1993-01-26
IPC分类号： B01F17/56 , B01F17/22 , B01J23/02 , B01J23/04 , B01J27/18 , B01J27/232 , C07B61/00 , C07C231/02 , C07C233/18 , C07C233/20 , C11D1/52 , C07C233/01 , C11D7/32
CPC分类号： C11D1/525 , C07C231/02
摘要： An improved process for manufacturing a linear glucamide surfactant comprises reacting an N-alkylglucamine, e.g., N-methylglucamine, a fatty ester, e.g., coconut methyl ester and a catalyst selected from trilithium phosphate, trisodium phosphate, tripotassium phosphate, tetrasodium pyrophosphate, tetrapotassium pyrophosphate, pentasodium tripolyphosphate, pentapotassium tripolyphosphate, lithium hydroxide, sodium hydroxide, potassium hydroxide, calcium hydroxide, lithium carbonate, sodium carbonate, potassium carbonate, disodium tartrate, dipotassium tartrate, sodium potassium tartrate, trisodium citrate, tripotassium citrate, sodium basic silicates, potassium basic silicates, sodium basic aluminosilicates, potassium basic aluminosilicates and mixtures thereof.
摘要翻译： 用于制备线性葡糖酰胺表面活性剂的改进方法包括使N-烷基葡糖胺例如N-甲基葡糖胺，脂肪酯，例如椰子甲酯和选自磷酸三氢锂，磷酸三钠，磷酸三钾，焦磷酸四钠，焦磷酸四钾 ，三聚磷酸五钠，三聚磷酸五钾，氢氧化锂，氢氧化钠，氢氧化钾，氢氧化钙，碳酸锂，碳酸钠，碳酸钾，酒石酸二钠，酒石酸二钾，酒石酸钠钾，柠檬酸三钠，柠檬酸三钾，碱式硅酸钠， 硅酸盐，碱式硅铝酸钠，碱式硅铝酸钾及其混合物。
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公开(公告)号：US5338486A
公开(公告)日：1994-08-16
申请号：US7039
申请日：1993-01-21
IPC分类号： B01F17/56 , B01F17/22 , B01J21/08 , B01J21/12 , B01J23/02 , B01J27/18 , B01J27/232 , B01J31/04 , C07B61/00 , C07C231/02 , C07C233/18 , C07C233/20 , C11D1/52 , C11D11/04 , C07C233/01 , C11D7/32
CPC分类号： C07C231/02 , C07C233/18 , C11D1/525 , C11D11/04
摘要： Improved process for manufacturing a linear glucamide surfactant comprising reacting an N-alkylglucamine, e.g., N-methylglucamine, a fatty ester, e.g., coconut methyl ester and a catalyst at high concentration selected from trilithium phosphate, trisodium phosphate, tripotassium phosphate, tetrasodium pyrophosphate, tetrapotassium pyrophosphate, pentasodium tripolyphosphate, pentapotassium tripolyphosphate, lithium carbonate, sodium carbonate, potassium carbonate, disodium tartrate, dipotassium tartrate, sodium potassium tartrate, trisodium citrate, tripotassium citrate, sodium basic silicates, potassium basic silicates, sodium basic aluminosilicates, potassium basic aluminosilicates and mixtures thereof.
摘要翻译： 包括使N-烷基葡糖胺例如N-甲基葡糖胺，脂肪酯，例如椰子甲酯和高浓度的催化剂与选自磷酸三氢钠，磷酸三钠，磷酸三钾，焦磷酸四钠， 焦磷酸四钾，三聚磷酸五钠，三聚磷酸五钾，碳酸锂，碳酸钠，碳酸钾，酒石酸二钠，酒石酸二钾，酒石酸钠钾，柠檬酸三钠，柠檬酸三钾，碱式硅酸钠，碱式硅酸钠，碱式硅铝酸钠，碱性铝硅酸钾和 其混合物。
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4.发明授权Process for obtaining highly esterified polyol fatty acid polyesters having reduced levels of difatty ketones and &bgr;-ketoesters 失效获得具有降低水平的不饱和酮和β-酮酯的高度酯化的多元醇脂肪酸聚酯的方法公开(公告)号：US06303777B1
公开(公告)日：2001-10-16
申请号：US08271273
申请日：1994-07-06
申请人： Ju-Nan Kao , John Keeney Howie , Patrick Joseph Corrigan , Richard Gerard Schafermeyer , Katherine Eleanor Flynn , Nelson James Holzschuh , David Joseph Bruno, Jr.
发明人： Ju-Nan Kao , John Keeney Howie , Patrick Joseph Corrigan , Richard Gerard Schafermeyer , Katherine Eleanor Flynn , Nelson James Holzschuh , David Joseph Bruno, Jr.
IPC分类号： C07H1302
摘要： An improved, solvent-free, two-stage transesterification process for preparing, from a polyol and fatty acid esters of an easily removable alcohol highly esterified polyol fatty acid polyesters having reduced levels of difatty ketones and &bgr;-ketoesters is disclosed. These reduced levels of difatty ketones/&bgr;-ketoesters are achieved by controlling the level of generated alcohol in the liquid phase of the reaction mixture and heating the reaction mixture to certain temperatures during the second stage of this improved process. Other optional reaction conditions, such as keeping the molar ratio of fatty acid esters to polyol within a specified range and reducing the level of basic catalyst, can also be used during the second stage reaction to further reduce the level of difatty ketones and/or &bgr;-ketoesters.
摘要翻译： 公开了一种改进的无溶剂的两阶段酯交换方法，用于由具有降低的二甲基酮和β-酮酯水平的容易除去的醇高度酯化的多元醇脂肪酸聚酯的多元醇和脂肪酸酯制备。 通过控制反应混合物的液相中产生的醇的水平并在该改进方法的第二阶段将反应混合物加热到某些温度来实现这些降低的酮/β-酮酯水平。 还可以在第二阶段反应期间使用其它任选的反应条件，例如将脂肪酸酯与多元醇的摩尔比保持在指定范围内并降低碱性催化剂的水平，以进一步降低二价酮和/或β的水平 -ketoesters。
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公开(公告)号：US5380891A
公开(公告)日：1995-01-10
申请号：US79202
申请日：1993-06-11
IPC分类号： C07C231/02 , C07C231/12 , C07C233/18 , C07C233/20 , C11D1/52 , C11C1/00 , C11C1/06
CPC分类号： C07C231/02 , C11D1/525
摘要： Disclosed is a process for manufacturing a linear glucamide surfactant comprising reacting an N-alkylglucamine, e.g., N-methylglucamine, a fatty ester, e.g., coconut oil in the presence of a phase transfer agent, generally a nonionic surfactant, preferably a preformed product of the process, the reaction preferably being conducted in the presence of an alkaline catalyst.
摘要翻译： 公开了一种制备线性葡糖酰胺表面活性剂的方法，其包括在相转移剂（通常为非离子表面活性剂）存在下使N-烷基葡糖胺例如N-甲基葡糖胺，脂肪酯，例如椰子油反应，优选预先形成的 该方法优选在碱性催化剂的存在下进行。
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