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公开(公告)号：US08048193B2
公开(公告)日：2011-11-01
申请号：US12298313
申请日：2007-05-29
IPC分类号： B22F9/24
CPC分类号： B01J13/0043 , B22F1/0022 , B22F9/24 , B82Y30/00 , Y10S977/896
摘要： It is an object of the present invention to provide a method for producing gold colloid having a targeted particle size, a sharp particle size distribution and a uniform and perfect spherical shape. The present invention relates to a method for producing gold colloid including a nucleation step of forming nuclear colloidal particles by adding a first reducing agent to a first gold salt solution; and a growth step of growing nuclear colloid by adding a second gold salt and a second reducing agent to the solution of the nuclear colloidal particles, characterized in that the growth step is performed at least once; a citrate is used as the first reducing agent and an ascorbate is used as the second reducing agent; and the addition of the ascorbate in the growth step is performed simultaneously with addition of the second gold salt. According to the method for producing gold colloid of the present invention, gold colloid having a sharp particle size distribution and a uniform and perfect spherical shape can be obtained.
摘要翻译： 本发明的目的是提供一种具有目标粒度，尖锐的粒度分布和均匀且完美的球形形状的金胶体的制造方法。 本发明涉及一种生产金胶体的方法，包括通过向第一金盐溶液中加入第一还原剂形成核胶体颗粒的成核步骤; 以及通过向核胶体粒子的溶液中添加第二金盐和第二还原剂来生长核胶体的生长步骤，其特征在于，所述生长步骤至少进行一次; 使用柠檬酸盐作为第一还原剂，使用抗坏血酸作为第二还原剂; 并且在添加第二金盐的同时进行生长步骤中的抗坏血酸盐的添加。 根据本发明的金胶体的制造方法，可以获得具有尖锐的粒度分布和均匀且完美的球形的金胶体。
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2.发明授权Organoruthenium compound for chemical vapor deposition raw material and production method for the organoruthenium compound 有权用于化学气相沉积原料的有机钌化合物和有机钌化合物的制备方法公开(公告)号：US09290841B2
公开(公告)日：2016-03-22
申请号：US14007763
申请日：2012-07-24
IPC分类号： C07F15/00 , C23C16/00 , C23C16/16 , C23C16/30 , H01L21/285
CPC分类号： C23C16/16 , C07F15/0046 , C23C16/30 , H01L21/28556
摘要： The present invention is an organoruthenium compound for a chemical vapor deposition raw material, including dodecacarbonyl triruthenium represented by the following chemical formula, wherein the iron (Fe) concentration is 1 ppm or less. The DCR in the present invention can be produced by obtaining crude DCR by directly carbonylating ruthenium through allowing a ruthenium salt and carbon monoxide to react with each other and by purifying the crude DCR by a sublimation method. In the synthesis step, the concentration of Fe in the obtained crude DCR is preferably set at 10 ppm or less.
摘要翻译： 本发明是用于化学气相沉积原料的有机钌化合物，其包括由以下化学式表示的十二羰基三钌，其中铁（Fe）浓度为1ppm以下。 本发明中的DCR可以通过使钌盐和一氧化碳相互反应并通过升华法纯化粗制DCR，通过直接羰基化钌来获得粗制DCR来制备。 在合成步骤中，所得到的粗制DCR中的Fe浓度优选为10ppm以下。
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3.发明授权公开(公告)号：US08889582B2
公开(公告)日：2014-11-18
申请号：US13518976
申请日：2011-01-07
申请人： Hirosi Noguchi , Junichi Taniuchi , Hitoshi Kubo , Yasunori Iwai , Katsumi Sato
发明人： Hirosi Noguchi , Junichi Taniuchi , Hitoshi Kubo , Yasunori Iwai , Katsumi Sato
CPC分类号： G21B1/115 , B01J21/08 , B01J23/42 , B01J31/0274 , B01J33/00 , B01J37/0203 , B01J37/0207 , B01J37/0209 , C01B5/00 , Y02E60/324
摘要： The present invention is a hydrogen combustion catalyst including a catalyst metal supported on a carrier composed of an inorganic oxide, wherein a functional group having at the end thereof at least an alkyl group having three or less carbon atoms is bonded by substitution to each of a certain fraction or the whole of the hydroxyl groups on the surface of the carrier. The functional group bonded to each of a certain fraction or the whole of the hydroxyl groups on the surface of the carrier is preferably an organic silane. The hydrogen combustion catalyst according to the present invention is capable of maintaining the activity thereof even when a hydrogen-containing gas, a treatment object, contains a water content equal to or less than the saturated water vapor content and the reaction temperature is set at or around room temperature, namely, at 0 to 40° C.
摘要翻译： 本发明是一种氢燃烧催化剂，其包含负载在由无机氧化物构成的载体上的催化剂金属，其中末端至少具有3个以下碳原子的烷基的官能团通过取代键接至 载体表面上的某些部分或全部羟基。 与载体表面上的某一部分或全部羟基键合的官能团优选为有机硅烷。 本发明的氢燃烧催化剂即使在含氢气体，处理对象物含有等于或小于饱和水蒸汽含量的水含量并且反应温度设定在或等于或等于或等于 在室温附近，即在0至40℃
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4.发明申请Hydrogen Combustion Catalyst and Method for Producing Thereof, and Method For Combusting Hydrogen 有权氢燃烧催化剂及其生产方法，以及用于燃烧氢的方法公开(公告)号：US20120263636A1
公开(公告)日：2012-10-18
申请号：US13518976
申请日：2011-01-07
申请人： Hirosi Noguchi , Junichi Taniuchi , Hitoshi Kubo , Yasunori Iwai , Katsumi Sato
发明人： Hirosi Noguchi , Junichi Taniuchi , Hitoshi Kubo , Yasunori Iwai , Katsumi Sato
CPC分类号： G21B1/115 , B01J21/08 , B01J23/42 , B01J31/0274 , B01J33/00 , B01J37/0203 , B01J37/0207 , B01J37/0209 , C01B5/00 , Y02E60/324
摘要： The present invention is a hydrogen combustion catalyst including a catalyst metal supported on a carrier composed of an inorganic oxide, wherein a functional group having at the end thereof at least an alkyl group having three or less carbon atoms is bonded by substitution to each of a certain fraction or the whole of the hydroxyl groups on the surface of the carrier. The functional group bonded to each of a certain fraction or the whole of the hydroxyl groups on the surface of the carrier is preferably an organic silane. The hydrogen combustion catalyst according to the present invention is capable of maintaining the activity thereof even when a hydrogen-containing gas, a treatment object, contains a water content equal to or less than the saturated water vapor content and the reaction temperature is set at or around room temperature, namely, at 0 to 40° C.
摘要翻译： 本发明是一种氢燃烧催化剂，其包含负载在由无机氧化物构成的载体上的催化剂金属，其中末端至少具有3个以下碳原子的烷基的官能团通过取代键接至 载体表面上的某些部分或全部羟基。 与载体表面上的某一部分或全部羟基键合的官能团优选为有机硅烷。 本发明的氢燃烧催化剂即使在含氢气体，处理对象物含有等于或小于饱和水蒸汽含量的水含量并且反应温度设定在或等于或等于或等于 在室温附近，即在0至40℃
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5.发明申请ORGANORUTHENIUM COMPOUND FOR USE IN CHEMICAL VAPOR DEPOSITION AND CHEMICAL VAPOR DEPOSITION USING THE SAME 有权化学气相沉积中使用的有机金属化合物和使用该化合物的化学气相沉积公开(公告)号：US20110268878A1
公开(公告)日：2011-11-03
申请号：US13182720
申请日：2011-07-14
申请人： Junichi Taniuchi , Masayuki Saito , Minoru Ishida
发明人： Junichi Taniuchi , Masayuki Saito , Minoru Ishida
IPC分类号： C23C16/18
CPC分类号： C07F15/0046 , C07F17/02 , C23C16/18 , H01L21/28556
摘要： The present invention is an organoruthenium compound for use in production of a ruthenium or ruthenium compound thin film by chemical vapor deposition, including ruthenium and an arene group and norbornadiene both coordinated to the ruthenium and represented by the following formula. The present invention is an organoruthenium compound for use in chemical vapor deposition which does not require the coexistence of oxygen during the thin film formation, and moreover, is liquid at ordinary temperature, thereby having good handleability and recyclability. wherein the substituents, R1 to R6, of the arene group are each hydrogen or an alkyl group, and the total number of carbons of R1 to R6 (R1+R2+R3+R4+R5+R6) is 6 or less.
摘要翻译： 本发明是用于通过化学气相沉积制造钌或钌化合物薄膜的有机钌化合物，包括钌和芳族基团和降冰片二烯，二者均与钌配位并由下式表示。 本发明是用于化学气相沉积的有机钌化合物，其在薄膜形成期间不需要氧的共存，而且在常温下为液体，因此具有良好的可操作性和可回收性。 其中芳基的取代基R 1〜R 6各自为氢或烷基，R 1〜R 6（R 1 + R 2 + R 3 + R 4 + R 5 + R 6）的碳原子数为6以下。
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6.发明申请ORGANIC RUTHENIUM COMPOUND FOR CHEMICAL VAPOR DEPOSITION RAW MATERIAL AND PRODUCTION METHOD FOR SAID ORGANIC RUTHENIUM COMPOUND 有权用于化学蒸气沉积的有机钌化合物原材料和有机有机化合物的生产方法公开(公告)号：US20140057050A1
公开(公告)日：2014-02-27
申请号：US14007763
申请日：2012-07-24
IPC分类号： C23C16/16
CPC分类号： C23C16/16 , C07F15/0046 , C23C16/30 , H01L21/28556
摘要： The present invention is an organoruthenium compound for a chemical vapor deposition raw material, including dodecacarbonyl triruthenium represented by the following chemical formula, wherein the iron (Fe) concentration is 1 ppm or less. The DCR in the present invention can be produced by obtaining crude DCR by directly carbonylating ruthenium through allowing a ruthenium salt and carbon monoxide to react with each other and by purifying the crude DCR by a sublimation method. In the synthesis step, the concentration of Fe in the obtained crude DCR is preferably set at 10 ppm or less.
摘要翻译： 本发明是用于化学气相沉积原料的有机钌化合物，其包括由以下化学式表示的十二羰基三钌，其中铁（Fe）浓度为1ppm以下。 本发明中的DCR可以通过使钌盐和一氧化碳相互反应并通过升华法纯化粗制DCR，通过直接羰基化钌来获得粗制DCR来制备。 在合成步骤中，所得到的粗制DCR中的Fe浓度优选为10ppm以下。
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公开(公告)号：US08637422B2
公开(公告)日：2014-01-28
申请号：US13578067
申请日：2011-03-29
IPC分类号： B01J31/00
CPC分类号： B01J35/008 , B01J21/04 , B01J23/02 , B01J23/08 , B01J23/10 , B01J23/14 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/468 , B01J23/48 , B01J35/08 , B01J37/0018 , B01J37/0203 , B01J37/0207 , B01J37/035 , B01J37/16
摘要： A method for supporting a catalytic metal on the surface of a carrier by bringing an aqueous catalytic metal salt solution into contact a porous carrier. The method includes the steps of: impregnating the carrier with a liquid hydrophobic organic compound before bringing the aqueous catalytic metal salt solution into contact with the carrier, and drying the impregnated carrier to volatilize the hydrophobic organic compound on the surface of the carrier, followed by bringing the carrier into contact with the aqueous catalytic metal salt solution; and then bringing a reducing agent into contact with the catalytic metal salt on the surface of the carrier to reduce the catalytic metal salt to undergo insolubilization treatment. The catalytic component is supported in a region from the surface of the carrier to a depth of 50 μm or more and 500 μm or less. The supported state of the catalytic component is made controllable, and the catalytic component can be supported in the inner part of the carrier with a suitable depth.
摘要翻译： 通过使催化金属盐水溶液与多孔载体接触来在载体的表面上负载催化金属的方法。 该方法包括以下步骤：在使载体催化金属盐水溶液与载体接触之前，用液态疏水性有机化合物浸渍载体，干燥浸渍载体以使载体表面上的疏水性有机化合物挥发，然后 使载体与催化金属盐水溶液接触; 然后使还原剂与载体表面上的催化金属盐接触以还原催化金属盐进行不溶解处理。 催化组分从载体的表面到达50μm以上至500μm以下的区域被负载。 催化组分的负载状态可控制，并且催化组分可以以适当的深度负载在载体的内部。
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公开(公告)号：US20120316055A1
公开(公告)日：2012-12-13
申请号：US13578067
申请日：2011-03-29
IPC分类号： B01J31/02
CPC分类号： B01J35/008 , B01J21/04 , B01J23/02 , B01J23/08 , B01J23/10 , B01J23/14 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/468 , B01J23/48 , B01J35/08 , B01J37/0018 , B01J37/0203 , B01J37/0207 , B01J37/035 , B01J37/16
摘要： A method for supporting a catalytic metal on the surface of a carrier by bringing an aqueous catalytic metal salt solution into contact a porous carrier. The method includes the steps of: impregnating the carrier with a liquid hydrophobic organic compound before bringing the aqueous catalytic metal salt solution into contact with the carrier, and drying the impregnated carrier to volatilize the hydrophobic organic compound on the surface of the carrier, followed by bringing the carrier into contact with the aqueous catalytic metal salt solution; and then bringing a reducing agent into contact with the catalytic metal salt on the surface of the carrier to reduce the catalytic metal salt to undergo insolubilization treatment. The catalytic component is supported in a region from the surface of the carrier to a depth of 50 μm or more and 500 μm or less. The supported state of the catalytic component is made controllable, and the catalytic component can be supported in the inner part of the carrier with a suitable depth.
摘要翻译： 通过使催化金属盐水溶液与多孔载体接触来在载体的表面上负载催化金属的方法。 该方法包括以下步骤：在使载体催化金属盐水溶液与载体接触之前，用液态疏水性有机化合物浸渍载体，干燥浸渍载体以使载体表面上的疏水性有机化合物挥发，然后 使载体与催化金属盐水溶液接触; 然后使还原剂与载体表面上的催化金属盐接触以还原催化金属盐进行不溶解处理。 催化剂成分从载体表面的一个区域被支撑到50μm以上且500μm以下的深度。 催化组分的负载状态可控制，并且催化组分可以以适当的深度负载在载体的内部。
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9.发明授权Organic ruthenium compound for chemical vapor deposition, and chemical vapor deposition method using the organic ruthenium compound 有权用于化学气相沉积的有机钌化合物和使用有机钌化合物的化学气相沉积方法公开(公告)号：US08097299B2
公开(公告)日：2012-01-17
申请号：US12091782
申请日：2007-09-27
申请人： Junichi Taniuchi , Masayuki Saito , Minoru Ishida
发明人： Junichi Taniuchi , Masayuki Saito , Minoru Ishida
CPC分类号： C07F15/0046 , C07F17/02 , C23C16/18 , H01L21/28556
摘要： The present invention is an organoruthenium compound for use in production of a ruthenium or ruthenium compound thin film by chemical vapor deposition, including ruthenium and an arene group and norbornadiene both coordinated to the ruthenium and represented by the following formula. The present invention is an organoruthenium compound for use in chemical vapor deposition which does not require the coexistence of oxygen during the thin film formation, and moreover, is liquid at ordinary temperature, thereby having good handleability and recyclability. wherein the substituents, R1 to R6, of the arene group are each hydrogen or an alkyl group, and the total number of carbons of R1 to R6 (R1+R2+R3+R4+R5+R6) is 6 or less.
摘要翻译： 本发明是用于通过化学气相沉积制造钌或钌化合物薄膜的有机钌化合物，包括钌和芳族基团和降冰片二烯，二者均与钌配位并由下式表示。 本发明是用于化学气相沉积的有机钌化合物，其在薄膜形成期间不需要氧的共存，而且在常温下为液体，因此具有良好的可操作性和可回收性。 其中芳基的取代基R 1〜R 6各自为氢或烷基，R 1〜R 6（R 1 + R 2 + R 3 + R 4 + R 5 + R 6）的碳原子数为6以下。
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公开(公告)号：US20100159471A1
公开(公告)日：2010-06-24
申请号：US12298313
申请日：2007-05-29
IPC分类号： G01N33/553
CPC分类号： B01J13/0043 , B22F1/0022 , B22F9/24 , B82Y30/00 , Y10S977/896
摘要： It is an object of the present invention to provide a method for producing gold colloid having a targeted particle size, a sharp particle size distribution and a uniform and perfect spherical shape. The present invention relates to a method for producing gold colloid including a nucleation step of forming nuclear colloidal particles by adding a first reducing agent to a first gold salt solution; and a growth step of growing nuclear colloid by adding a second gold salt and a second reducing agent to the solution of the nuclear colloidal particles, characterized in that the growth step is performed at least once; a citrate is used as the first reducing agent and an ascorbate is used as the second reducing agent; and the addition of the ascorbate in the growth step is performed simultaneously with addition of the second gold salt. According to the method for producing gold colloid of the present invention, gold colloid having a sharp particle size distribution and a uniform and perfect spherical shape can be obtained.
摘要翻译： 本发明的目的是提供一种具有目标粒度，尖锐的粒度分布和均匀且完美的球形形状的金胶体的制造方法。 本发明涉及一种生产金胶体的方法，包括通过向第一金盐溶液中加入第一还原剂形成核胶体颗粒的成核步骤; 以及通过向核胶体粒子的溶液中添加第二金盐和第二还原剂来生长核胶体的生长步骤，其特征在于，所述生长步骤至少进行一次; 使用柠檬酸盐作为第一还原剂，使用抗坏血酸作为第二还原剂; 并且在添加第二金盐的同时进行生长步骤中的抗坏血酸盐的添加。 根据本发明的金胶体的制造方法，可以获得具有尖锐的粒度分布和均匀且完美的球形的金胶体。
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