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1.发明授权Process and catalyst system for improving dewaxing catalyst stability and lubricant oil yield 有权提高脱蜡催化剂稳定性和润滑油产量的工艺和催化剂体系公开(公告)号：US08431014B2
公开(公告)日：2013-04-30
申请号：US12574500
申请日：2009-10-06
IPC分类号： C10G65/00
CPC分类号： B01J29/74 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/44 , B01J23/58 , B01J29/04 , B01J29/06 , B01J29/62 , B01J35/0006 , B01J35/1019 , B01J35/1042 , B01J37/0018 , B01J37/0201 , C10G2400/10
摘要： The invention provides for a process for dewaxing a waxy hydrocarbon feedstock to form a lubricant oil. The invention is also directed to a catalyst system comprising a hydrotreating catalyst upstream of a dewaxing catalyst, used in the dewaxing of a waxy hydrocarbon feedstock to form a lubricant oil. In particular, the invention is directed to a process and catalyst system designed to maintain yield of lubricant oil product. Specifically, the yield of lubricant oil does not decrease more than 2%, at a target pour point, over a dewaxing temperature range. The hydrotreating catalyst helps prevent aging of the dewaxing catalyst and maintains lubricant oil product yield at a target pour point over a wide temperature range. The hydrotreating catalyst comprises platinum, palladium, or combinations thereof on a low acidity inorganic oxide support where acidity is measured by a decalin conversion of less than 10% at 700° F.
摘要翻译： 本发明提供了一种蜡蜡原料脱蜡以形成润滑油的方法。 本发明还涉及包含在脱蜡催化剂上游的加氢处理催化剂的催化剂体系，用于蜡蜡原料的脱蜡以形成润滑油。 特别地，本发明涉及一种设计用于保持润滑油产品的产率的方法和催化剂体系。 具体地说，在目标倾点下，在脱蜡温度范围内，润滑油的收率不会降低2％以上。 加氢处理催化剂有助于防止脱蜡催化剂的老化，并在较宽的温度范围内将润滑油产品的产率保持在目标倾点。 加氢处理催化剂包括铂，钯或其组合在低酸性无机氧化物载体上，其酸度通过在700°F下低于10％的十氢化萘转化率来测量。
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2.发明申请Novel process and catalyst system for improving dewaxing catalyst stability and lubricant oil yield. 有权用于提高脱蜡催化剂稳定性和润滑油产率的新工艺和催化剂体系。公开(公告)号：US20110079540A1
公开(公告)日：2011-04-07
申请号：US12574500
申请日：2009-10-06
IPC分类号： C10G65/00 , B01J29/064
CPC分类号： B01J29/74 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/44 , B01J23/58 , B01J29/04 , B01J29/06 , B01J29/62 , B01J35/0006 , B01J35/1019 , B01J35/1042 , B01J37/0018 , B01J37/0201 , C10G2400/10
摘要： The invention provides for a process for dewaxing a waxy hydrocarbon feedstock to form a lubricant oil. The invention is also directed to a catalyst system comprising a hydrotreating catalyst upstream of a dewaxing catalyst, used in the dewaxing of a waxy hydrocarbon feedstock to form a lubricant oil. In particular, the invention is directed to a process and catalyst system designed to maintain yield of lubricant oil product. Specifically, the yield of lubricant oil does not decrease more than 2%, at a target pour point, over a dewaxing temperature range. The hydrotreating catalyst helps prevent aging of the dewaxing catalyst and maintains lubricant oil product yield at a target pour point over a wide temperature range. The hydrotreating catalyst comprises platinum, palladium, or combinations thereof on a low acidity inorganic oxide support where acidity is measured by a decalin conversion of less than 10% at 700° F.
摘要翻译： 本发明提供了一种蜡蜡原料脱蜡以形成润滑油的方法。 本发明还涉及包含在脱蜡催化剂上游的加氢处理催化剂的催化剂体系，用于蜡蜡原料的脱蜡以形成润滑油。 特别地，本发明涉及一种设计用于保持润滑油产品的产率的方法和催化剂体系。 具体地说，在目标倾点下，在脱蜡温度范围内，润滑油的收率不会降低2％以上。 加氢处理催化剂有助于防止脱蜡催化剂的老化，并在较宽的温度范围内将润滑油产品的产率保持在目标倾点。 加氢处理催化剂包括铂，钯或其组合在低酸性无机氧化物载体上，其酸度通过在700°F下低于10％的十氢化萘转化率来测量。
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公开(公告)号：US06468418B1
公开(公告)日：2002-10-22
申请号：US09590441
申请日：2000-06-09
申请人： Joseph A. Biscardi , Kamala R. Krishna , John M. Rosenbaum , Nadine L. Yenni , R. Larry Howell , Krishnia Parimi
发明人： Joseph A. Biscardi , Kamala R. Krishna , John M. Rosenbaum , Nadine L. Yenni , R. Larry Howell , Krishnia Parimi
IPC分类号： C10G2500
摘要： A base oil feed having a tendency to form a haze at ambient or sub-ambient temperatures is contacted with a solid adsorbent to remove at least a portion of the haze precursors, thereby reducing the haze-forming tendency of the base oil feed.
摘要翻译： 在环境温度或低于环境温度下具有雾度的基础油进料与固体吸附剂接触以除去至少一部分雾状前体，从而降低基础油进料的雾度形成趋势。
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4.发明授权公开(公告)号：US06458265B1
公开(公告)日：2002-10-01
申请号：US09474614
申请日：1999-12-29
IPC分类号： C10G35095
CPC分类号： C10L1/08 , C10G2400/04
摘要： A diesel fuel having at least 50% C10 to C20 paraffins, wherein the iso-paraffin to normal paraffin mole ratio is up to 21:1 and higher. This diesel fuel can be produced from a feed containing at least 90% C10+ normal paraffins. This diesel fuel is produced by contacting a feed in an isomerization reaction zone a feed with a catalyst comprising a SAPO-11 and platinum in the presence of hydrogen (hydrogen:feed ratio of from 1,000 to 10,000 SCFB) at a temperature of from 340° C. to 420° C., a pressure of from 100 psig to 600 psig, and a liquid hourly space velocity of from 0.1 hr−1 to 1.0 hr−1.
摘要翻译： 具有至少50％C 10至C 20链烷烃的柴油燃料，其中异链烷烃与正常链烷烃的摩尔比高达21:1。 这种柴油可以由含有至少90％的C10 +正链烷烃的进料生产。 该柴油燃料是通过使异构化反应区中的进料与含有SAPO-11和铂的催化剂在氢存在下（氢气：进料比为1,000至10,000SCFB）在340℃的温度下使进料接触而制备的 至420℃，压力为100psig至600psig，液时空速为0.1hr-1至1.0hr-1。
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公开(公告)号：US07390763B2
公开(公告)日：2008-06-24
申请号：US10698250
申请日：2003-10-31
申请人： Stacey I. Zones , Guang Zhang , Kamala R. Krishna , Joseph A. Biscardi , Paul Marcantonio , Euthimios Vittoratos
发明人： Stacey I. Zones , Guang Zhang , Kamala R. Krishna , Joseph A. Biscardi , Paul Marcantonio , Euthimios Vittoratos
IPC分类号： B01J29/06
CPC分类号： C01B39/04 , B01J29/70 , B01J29/7049 , B01J29/74 , B01J37/0009 , B01J2229/42 , C01B39/48 , C10G45/64
摘要： The invention is directed to a method of making a small crystal SSZ-32 zeolite, known as SSZ-32X. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is dewaxed to produce an isomerized product, with increased yield of isomerized material and decreased production of light ends.
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6.发明授权Process for producing a highly paraffinic diesel fuel having a high iso-paraffin to normal paraffin mole ratio 失效具有高异链烷烃与正常石蜡摩尔比的高度链烷烃类柴油燃料的方法公开(公告)号：US06723889B2
公开(公告)日：2004-04-20
申请号：US09765585
申请日：2001-01-22
IPC分类号： C07C522
CPC分类号： C10L1/08 , C10G2400/04 , Y10S208/95
摘要： A process for producing a diesel fuel having at least 70% C10+ paraffins, wherein the iso-paraffin to normal paraffin mole ratio is 5:1 and higher. This diesel fuel is produced by from a feed containing at least 40% C10+ normal paraffins and at least 20% C26+ normal paraffins. It is produced by contacting that feed in an isomerization/cracking reaction zone a feed with a catalyst comprising a SAPO-11 and platinum in the presence of hydrogen (hydrogen:feed ratio of from 1,000 to 10,000 SCFB) at a temperature of from 340° C. to 420° C., a pressure of from 100 psig to 600 psig, and a liquid hourly space velocity of from 0.1 hr−1 to 1.0 hr−1.
摘要翻译： 一种制备具有至少70％的C 10 +烷烃的柴油的方法，其中异链烷烃与正常的石蜡摩尔比为5:1以上。 该柴油由含有至少40％C 10 +正链烷烃和至少20％C26 +正链烷烃的原料生产。 通过在异构化/裂化反应区中将进料与含有SAPO-11和铂的催化剂在氢气存在下（氢气：进料比为1,000至10,000SCFB），使该进料在340℃的温度下接触而制备 至420℃，压力为100psig至600psig，液时空速为0.1小时-1.0小时-1。
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公开(公告)号：US06468417B1
公开(公告)日：2002-10-22
申请号：US09483305
申请日：2000-01-14
IPC分类号： C10G2500
摘要： A dewaxed oil having a tendency to form a haze at ambient or sub-ambient temperatures is contacted with a solid adsorbent to remove at least a portion of the haze precursors, thereby reducing the haze-forming tendency of the dewaxed oil.
摘要翻译： 在环境温度或亚环境温度下具有形成雾度的脱蜡油与固体吸附剂接触以除去至少一部分雾状前体，从而降低脱蜡油的雾度形成倾向。
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8.发明授权Process for producing a highly paraffinic diesel fuel having a high iso-paraffin to normal paraffin mole ratio 失效具有高异链烷烃与正常石蜡摩尔比的高度链烷烃类柴油燃料的方法公开(公告)号：US06204426B1
公开(公告)日：2001-03-20
申请号：US09474615
申请日：1999-12-29
IPC分类号： C07C522
CPC分类号： C10L1/08 , C10G2400/04 , Y10S208/95
摘要： A process for producing a diesel fuel having at least 70% C10+ paraffins, wherein the iso-paraffin to normal paraffin mole ratio is 5:1 and higher. This diesel fuel is produced by from a feed containing at least 40% C10+ normal paraffins and at least 20% C26+ normal paraffins. It is produced by contacting that feed in an isomerization/cracking reaction zone a feed with a catalyst comprising a SAPO-11 and platinum in the presence of hydrogen (hydrogen:feed ratio of from 1,000 to 10,000 SCFB) at a temperature of from 340° C. to 420° C., a pressure of from 100 psig to 600 psig, and a liquid hourly space velocity of from 0.1 hr−1 to 1.0 hr−1.
摘要翻译： 一种制备具有至少70％的C 10 +烷烃的柴油的方法，其中异链烷烃与正常的石蜡摩尔比为5:1以上。 该柴油由含有至少40％C 10 +正链烷烃和至少20％C26 +正链烷烃的原料生产。 通过在异构化/裂化反应区中将进料与含有SAPO-11和铂的催化剂在氢气存在下（氢气：进料比为1,000至10,000SCFB），使该进料在340℃的温度下接触而制备 至420℃，压力为100psig至600psig，液时空速为0.1hr-1至1.0hr-1。
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