公开(公告)号：US4500682A

公开(公告)日：1985-02-19

申请号：US495655

申请日：1983-05-18

申请人： Hiromasa Chiba ,  Kenjiro Obama ,  Shunji Kawazoe ,  Takahiro Oka ,  Akihiro Sato

发明人： Hiromasa Chiba ,  Kenjiro Obama ,  Shunji Kawazoe ,  Takahiro Oka ,  Akihiro Sato

IPC分类号： C08F2/00 ,  C08F8/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F297/00 ,  C08F297/08 ,  C08L23/12 ,  C08L23/16

CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/06

摘要： A polypropylene (PP) having a superior post-processability and blow moldability is provided, which PP is obtained by polymerizing propylene at multiple stages using a catalyst comprising a TiCl.sub.3 composition, an organoaluminum compound and a molecular weight (M.W.) modifier, the resulting final polymer comprising a higher M.W. portion and a lower M.W. portion having a melt flow index of 0.03 to 2.0 g/10 min., and between this index and a melt flow index (10.2 kg/10 minutes, 230.degree. C.) as measured under 5 times the load applied in the measurement of the former melt flow index, there being a relationship log HMI.gtoreq.0.922 log MI+1.44, and the final polymer consisting of 40 to 60 weight % of a PP portion corresponding to the higher M.W. portion and 60 to 40 weight % of a PP portion corresponding to the lower M.W. portion.

摘要翻译： 提供具有优异的后加工性和吹塑成型性的聚丙烯（PP），其通过使用包含TiCl 3组合物，有机铝化合物和分子量（MW）改性剂的催化剂在多个阶段聚合丙烯而获得，所得最终 聚合物，其包含较高MW部分和较低MW部分，其熔体流动指数为0.03至2.0g / 10min，并且在该指数和熔体流动指数（10.2kg / 10分钟，230℃）之间测量， 在前一个熔体流动指数的测量中施加的载荷的5倍，存在关系日志HMI> / = 0.922log MI + 1.44，并且最终聚合物由对应于较高MW的40至60重量％的PP部分组成 部分和对应于较低MW部分的PP部分的60至40重量％。

公开(公告)号：US5124383A

公开(公告)日：1992-06-23

申请号：US707751

申请日：1991-05-30

申请人： Kenjiro Obama ,  Hiroshi Takasu ,  Susumu Arase ,  Hiroyuki Fujii

发明人： Kenjiro Obama ,  Hiroshi Takasu ,  Susumu Arase ,  Hiroyuki Fujii

IPC分类号： B29C47/08 ,  C08K5/42 ,  C08L23/06 ,  C11D1/22 ,  C11D3/37

CPC分类号： C08K5/42 ,  B29C47/0877 ,  C08L23/06 ,  C11D1/22 ,  C11D3/3749 ,  B29C47/0009 ,  C08K3/36 ,  C08L2205/02 ,  C08L2205/03 ,  C08L25/06 ,  C08L55/02 ,  C08L91/06

摘要： A resin composition for cleaning the inside of molding machines, capable of easily achieving color exchange and the resin exchange of thermoplastic resins in various molding machines, in a small quantity, by a simple operation and in a short time is provided, which resin composition is a cleaning resin composition having 1-10 wt. % of a polyethylene wax, 1-20 wt. % of a neutral salt of an alkylbenzenesulfonic acid and 1-20 wt. % of an inorganic filler, blended with a high density polyethylene resin having a melt index of 1.0 or less and a Q value expressing a molecular weight distribution, of 10 or less.

摘要翻译： 提供了一种用于清洗成型机内部的树脂组合物，其能够通过简单的操作和在短时间内容易地实现少量的在各种成型机中的颜色交换和树脂交换的树脂组合物。 具有1-10重量份的清洁树脂组合物， ％的聚乙烯蜡，1-20wt。 ％的烷基苯磺酸的中性盐和1-20重量％ ％的无机填料与熔体指数为1.0以下，表示分子量分布的Q值为10以下的高密度聚乙烯树脂共混。

公开(公告)号：US4510292A

公开(公告)日：1985-04-09

申请号：US522013

申请日：1983-08-11

申请人： Hiromasa Chiba ,  Kenjiro Obama ,  Shunji Kawazoe ,  Takahiro Oka ,  Akihiro Satoh

发明人： Hiromasa Chiba ,  Kenjiro Obama ,  Shunji Kawazoe ,  Takahiro Oka ,  Akihiro Satoh

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F297/00 ,  C08F297/08 ,  C08J9/04 ,  C08J9/06 ,  C08L23/10 ,  C08L23/16

CPC分类号： C08F297/083 ,  C08L23/10 ,  C08L2205/02 ,  C08L23/16

摘要： An ethylene-propylene block copolymer capable of producing foamed shaped articles having a structure of uniform and fine foams even without adding any other resins, and a process for producing the same are provided, which copolymer consists of a propylene homopolymer portion and an ethylene-propylene (EP) copolymer portion and is characterized in that .circle.1 the former portion is obtained by polymerizing propylene at two stages so that the portion can further consist of a lower molecular weight portion and a higher molecular portion; .circle.2 between the melt flow rates of the resulting block copolymer under a specified load and five times the load, there is a specified relationship; .circle.3 the EP copolymer portion has an ethylene content of 60 to 95% by weight based on this portion; and .circle.4 the block copolymer has an ethylene content of 10 to 40% by weight based on the copolymer.

摘要翻译： 提供能够生产具有均匀和细小泡沫的结构的发泡成型制品的乙烯 - 丙烯嵌段共聚物，即使不添加任何其它树脂，以及其制备方法，该共聚物由丙烯均聚物部分和乙烯 - 丙烯 （EP）共聚物部分，其特征在于，前一部分通过在两个阶段聚合丙烯获得，使得该部分可以进一步由较低分子量部分和较高分子部分组成; 所得嵌段共聚物在规定负荷下的熔体流动速率与负荷的5倍之间，有一个特定的关系; ＆lt; 3＆gt; EP共聚物部分基于该部分的乙烯含量为60〜95重量％ 和＆lt; c＆lt; 4＆gt;嵌段共聚物的乙烯含量基于共聚物为10〜40重量％。

公开(公告)号：US5087653A

公开(公告)日：1992-02-11

申请号：US521549

申请日：1990-05-10

申请人： Kenjiro Obama ,  Hiroshi Takasu ,  Susumu Arase ,  Hiroyuki Fujii

发明人： Kenjiro Obama ,  Hiroshi Takasu ,  Susumu Arase ,  Hiroyuki Fujii

IPC分类号： B29C47/08 ,  C08K5/42 ,  C08L23/06 ,  C11D1/22 ,  C11D3/37

CPC分类号： C08K5/42 ,  B29C47/0877 ,  C08L23/06 ,  C11D1/22 ,  C11D3/3749 ,  B29C47/0009 ,  C08K3/36 ,  C08L2205/02 ,  C08L2205/03 ,  C08L25/06 ,  C08L55/02 ,  C08L91/06

摘要： A resin composition for cleaning the inside of molding machines, capable of easily achieving the color exchange and resin exchange of thermoplastic resins in various molding machines, in a small quantity, by a simple operation and in a short time is provided, which resin composition is a cleaning resin composition having (a) 1-10 wt. % of a polystyrene resin, 1-20 wt. % of a neutral salt of an alkylbenzenesulfonic acid, 1-30 wt. % of an inorganic filler and 0.5-10 wt. % of a water-repellent compound blended with a high density polyethylene resin having a melt index of 1.0 or less and a Q value expressing a molecular weight distribution, of 10 or less.

公开(公告)号：US5108645A

公开(公告)日：1992-04-28

申请号：US620832

申请日：1990-12-03

申请人： Kenjiro Obama ,  Kentaro Yamada ,  Hiroyuki Fujii

发明人： Kenjiro Obama ,  Kentaro Yamada ,  Hiroyuki Fujii

IPC分类号： B29C33/72 ,  B29C47/08 ,  C08K3/00 ,  C08K3/22 ,  C08K3/26 ,  C08K5/42 ,  C08L25/00 ,  C08L25/04 ,  C08L25/08 ,  C08L33/00 ,  C08L33/12 ,  C11D1/22 ,  C11D3/12 ,  C11D3/37 ,  C11D10/02

CPC分类号： C11D3/3761 ,  B29C33/722 ,  B29C47/0877 ,  C08K3/22 ,  C08K3/26 ,  C08K5/42 ,  C08L25/04 ,  C11D1/22 ,  C11D3/1213 ,  C11D3/1233 ,  C11D3/3749 ,  B29C47/0011 ,  C08L33/12

摘要： A detergent resin composition is provided which is, in a small quantity, capable of very effectively deterging the inside of molding machines in a short period of time at the time of change-over of chlorine-containing resins inside the machines, which composition is obtained by blending 50 to 95% by weight of a polystyrene resin, 0.1 to 15% by weight of a polymethyl methacrylate, 2 to 30% by weight of a neutral salt of a sulfonic acid and 0.1 to 10% by weight of basic magnesium carbonate, magnesium hydroxide, aluminum hydroxide, zinc carbonate or a mixture thereof, the respective proportions being based upon the weight of the composition.

公开(公告)号：US06277809B1

公开(公告)日：2001-08-21

申请号：US09275428

申请日：1999-03-24

申请人： Kenjiro Obama

发明人： Kenjiro Obama

IPC分类号： C11D1700

CPC分类号： C11D3/37 ,  C11D1/76 ,  C11D17/0039

摘要： The resin granule of the present invention for washing comprises a resin granule, a detergent component and, optionally, a third component, wherein the external surface of each particle of the resin granule is coated with the detergent component. The method for producing the resin granule for washing, comprising a resin granule, a detergent component and, optionally, a third component brings the resin granule into contact with the detergent component for a sufficient time so that the external surface of the former is coated with the latter by at least one of the processes selected from the group consisting of: (a) immersion of the resin granule in a solution of the detergent component, (b) spraying a solution of the detergent component onto the resin granule, (c) mixing the resin granule with a solution of the detergent component under no heating, and (d) adsorption of the detergent component vapor on the external surface of the resin granule, and then separates the resin granule coated with the detergent component. The method for washing resin molders using the above resin granule for washing is also provided.

摘要翻译： 用于洗涤的本发明的树脂颗粒包括树脂颗粒，洗涤剂组分和任选的第三组分，其中树脂颗粒的每个颗粒的外表面涂覆有洗涤剂组分。 制备用于洗涤的树脂颗粒的方法包括树脂颗粒，洗涤剂组分和任选的第三组分使得树脂颗粒与洗涤剂组分接触足够的时间，使得前者的外表面被涂覆 （a）将树脂颗粒浸入洗涤剂组分的溶液中，（b）将洗涤剂组分的溶液喷射到树脂颗粒上，（c）将洗涤剂组分溶解在树脂颗粒中， 在不加热下将树脂颗粒与洗涤剂组分的溶液混合，和（d）将洗涤剂组分蒸气吸附在树脂颗粒的外表面上，然后分离涂有洗涤剂组分的树脂颗粒。 还提供了使用上述树脂颗粒洗涤树脂成型机的方法。

公开(公告)号：US5238608A

公开(公告)日：1993-08-24

申请号：US822132

申请日：1992-01-17

申请人： Kenjiro Obama ,  Nobukazu Atsumi ,  Hiroyuki Fujii

发明人： Kenjiro Obama ,  Nobukazu Atsumi ,  Hiroyuki Fujii

IPC分类号： C08K3/20 ,  B29C33/72 ,  B29C47/00 ,  C08K3/16 ,  C08K3/22 ,  C08K3/26 ,  C08K5/41 ,  C08K5/42 ,  C08L23/00 ,  C08L23/02 ,  C08L29/00

CPC分类号： C08K3/26 ,  B29B7/802 ,  B29C33/722 ,  B29C47/0881 ,  C08K3/22 ,  C08K5/42 ,  C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  B29C47/00 ,  B29C47/0011 ,  B29C47/0014 ,  B29C47/0066

摘要： The present invention provides a cleaning composition for a resin molding machine which comprises 50 to 95% by weight of a polyolefin resin having a melt index of 0.01 to 0.5, 0.1 to 15% by weight of an acrylic copolymer, 2 to 30% by weight of a neutral salt of organic sulfonic acid and 0.1 to 10% by weight of basic magnesium carbonate, magnesium hydroxide, potassium carbonate, zinc carbonate or a mixture of two or more thereof.This composition is suitable for the cleaning of the molding machine at a time of changeover of super-engineering plastics at the molding temperature of the plastics which is about 400.degree. C.

摘要翻译： 本发明提供一种树脂成型机用清洗组合物，其含有50〜95重量％的熔融指数为0.01〜0.5，0.1〜15重量％的丙烯酸共聚物，2〜30重量％ 的中性有机磺酸盐和0.1至10重量％的碱式碳酸镁，氢氧化镁，碳酸钾，碳酸锌或其两种或多种的混合物。 该组合物适合于在塑料的成型温度下在超过400℃的超塑性塑料的切换时对成型机的清洁。

公开(公告)号：US4499247A

公开(公告)日：1985-02-12

申请号：US501893

申请日：1983-06-07

申请人： Hiromasa Chiba ,  Kenjiro Obama ,  Shunji Kawazoe ,  Takahiro Oka ,  Akihiro Satoh

发明人： Hiromasa Chiba ,  Kenjiro Obama ,  Shunji Kawazoe ,  Takahiro Oka ,  Akihiro Satoh

IPC分类号： C08F2/00 ,  C08F2/04 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F8/00 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

CPC分类号： C08F10/06 ,  Y10S526/905

摘要： A superior high-rigidity and high-melt-viscoelasticity polypropylene for sheets to be post-processed and for blow molding is provided which polypropylene is produced by subjecting propylene to a multi-stage polymerization into polymer portions of two sections in the presence of a specified Ziegler Natta catalyst, the relationship between the intrinsic viscosities of the polymer portions of the respective sections being regulated within a specified range and also the amount ratio of the polymer portions of the respective sections being regulated.

摘要翻译： 提供了用于后处理和吹塑的片材的优异的高刚性和高熔点粘弹性聚丙烯，其通过在规定的存在下将丙烯进行多段聚合成两段聚合物部分来制备聚丙烯 齐格勒纳塔催化剂，将各部分的聚合物部分的特性粘度之间的关系调节在规定范围内，并且调节各部分的聚合物部分的量比。