公开(公告)号：US06380318B1

公开(公告)日：2002-04-30

申请号：US09095992

申请日：1998-06-11

申请人： Kuniyoshi Saito ,  Eiji Komiya ,  Jun Okabe

发明人： Kuniyoshi Saito ,  Eiji Komiya ,  Jun Okabe

IPC分类号： C08S26510

CPC分类号： C08F8/32 ,  C08F8/14 ,  C08F8/26 ,  C08F8/30 ,  C08F2800/20 ,  C08F2810/10 ,  C08F2810/30 ,  C08F2810/50 ,  C08F2220/1808 ,  C08F2220/1825 ,  C08F210/02 ,  C08F220/14

摘要： A modified acrylic rubber having distinguished molding characteristics and O-ring compression set characteristic is produced by mixing an acrylic rubber having reactive functional groups such as active chlorine groups, carboxylic groups, epoxy groups, active ester groups, etc. with an unsaturated compound reactive with the reactive functional group with heating in the absence of a solvent.

摘要翻译： 通过将具有活性氯基，羧基，环氧基，活性酯基等反应性官能团的丙烯酸类橡胶与不饱和化合物反应的丙烯酸类橡胶与具有与O形环压缩变形特性反应的不饱和化合物 反应性官能团在不存在溶剂的情况下加热。

公开(公告)号：US08056903B2

公开(公告)日：2011-11-15

申请号：US12086211

申请日：2006-12-05

申请人： Noriyuki Matsui ,  Manabu Hirano ,  Yoshihiro Kuzumaki ,  Kuniyoshi Saito ,  Hayato Takada

发明人： Noriyuki Matsui ,  Manabu Hirano ,  Yoshihiro Kuzumaki ,  Kuniyoshi Saito ,  Hayato Takada

IPC分类号： F16J15/16

CPC分类号： C09K3/1021 ,  C08G18/10 ,  C08G18/44 ,  C08G2140/00 ,  C08G18/3206

摘要： In a rod sealing system, which comprises a buffer ring, a rod seal, and a dust seal, provided successively in this order from a fluid hydraulic side toward the outside in an annular clearance between two members in reciprocating motion, the buffer ring is made up of a thermoplastic polyurethane molding product obtained by subjecting a thermoplastic polyurethane molding product prepared by reaction of (A) a high molecular weight polycarbonatediol having a number average molecular weight Mn of 500-6,000, (B) an aromatic diisocyanate, and (C) a low molecular weight diol as a chain elongation agent in an NCO/OH ratio of 0.95-1.20, to heat treatment under conditions that a glass transition point (Tg) of hard phases becomes 170° C. or higher, preferably 170-230° C., and an endothermic peak area (ΔH) at Tg becomes 5 J/g or more, by differential scanning calorimetry. The buffer ring made up of the thermoplastic polyurethane molding product has a distinguished heat resistance capable of withstanding the service environmental temperature, particularly maximum 120° C., compression set characteristics, follow-up to eccentricity, etc.

摘要翻译： 在包括缓冲环，杆密封和防尘密封的杆密封系统中，以往复运动中的两个构件之间的环形间隙从液压侧朝向外部依次提供缓冲环，制成缓冲环 （A）数均分子量Mn为500〜6000的高分子量聚碳酸酯二醇，（B）芳香族二异氰酸酯和（C）的反应制得的热塑性聚氨酯成型体， 作为NCO / OH比为0.95-1.20的链延长剂的低分子量二醇，在硬相的玻璃化转变温度（Tg）为170℃以上，优选为170〜230℃的条件下进行热处理 通过差示扫描量热法测定Tg的吸热峰面积（＆Dgr; H）为5J / g以上。 由热塑性聚氨酯成型制品制成的缓冲环具有耐受使用环境温度，特别是最大120℃，压缩永久变形特性，偏心率等特性的耐热性。

公开(公告)号：US6114459A

公开(公告)日：2000-09-05

申请号：US969000

申请日：1997-11-12

申请人： Yoshihiro Kuzumaki ,  Eiji Komiyama ,  Kuniyoshi Saito ,  Jun Okabe

发明人： Yoshihiro Kuzumaki ,  Eiji Komiyama ,  Kuniyoshi Saito ,  Jun Okabe

IPC分类号： C08F259/00 ,  C08F265/04 ,  C08F265/06 ,  C08F271/02

CPC分类号： C08F265/06 ,  C08F259/00 ,  C08F265/04 ,  C08F271/02

摘要： An acrylic elastomer obtained by copolymerization of about 60 to about 99.9% by weight of at least one of alkyl acrylate and alkoxyalkyl acrylate; about 10 to about 0.1% by weight of a halogen-containing vinyl compound having a secondary or tertiary halogenoalkyl group; and about 30 to 0% by weight of a monomer copolymerizable with the acrylate and the vinyl compound, sum total being 100% by weight, is an acrylic elastomer containing the halogen-containing vinyl compound as a cross-linking site monomer capable of forming an active halogen group cross-linkable with an organic peroxide or the like, and has a high vulcanization torque.

摘要翻译： 通过共聚合约60-约99.9重量％的丙烯酸烷基酯和丙烯酸烷氧基烷基酯中的至少一种得到的丙烯酸类弹性体; 约10至约0.1重量％的具有仲或叔卤代烷基的含卤素的乙烯基化合物; 和约30至0重量％的可与丙烯酸酯和乙烯基化合物共聚的单体，总和为100重量％，是含有含卤素的乙烯基化合物作为可形成交联部位的交联部位单体的丙烯酸类弹性体 与有机过氧化物等可交联的活性卤素基团，并且具有高硫化扭矩。

公开(公告)号：US6001932A

公开(公告)日：1999-12-14

申请号：US38775

申请日：1998-03-11

申请人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

发明人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

IPC分类号： C08F212/14 ,  C08F216/14 ,  C08F218/10 ,  C08F220/12 ,  C08F220/30 ,  C08L27/12 ,  C08L33/08

CPC分类号： C08F220/30 ,  C08F212/14 ,  C08F216/14 ,  C08F218/10 ,  C08F220/12 ,  C08L33/08 ,  C08L27/12

摘要： A copolymer comprising an alkyl acrylate and an unsaturated ester compound represented by the following general formula:CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR', (1)CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (2)CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (3)CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or (4)CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR' (5)where R is a hydrogen atom or a methyl group; R' is a hydrogen atom, an acyl group or a trialkylsilyl group; and Ph is a phenylene group, forms a blend rubber having a good heat resistance and a good amine resistance with a fluorine-containing elastomer.

摘要翻译： 包含丙烯酸烷基酯和由以下通式表示的不饱和酯化合物的共聚物：CH 2 = CRCOO（CH 2）n PhOR'，（1）CH 2 = CRCOO（CH 2）nOCO（CH 2）m PhOR'，（2）CH 2 = CHOCO CH2）nOCO（CH2）mPhOR'，（3）CH2 = CHO（CH2）nOCO（CH2）mPhOR'或（4）CH2 = CHPh（CH2）nOCO（CH2）mPhOR'（5）其中R是氢原子或 甲基; R'是氢原子，酰基或三烷基甲硅烷基; 并且Ph是亚苯基，与含氟弹性体形成具有良好耐热性和良好耐胺性的共混橡胶。

公开(公告)号：US5744562A

公开(公告)日：1998-04-28

申请号：US686078

申请日：1996-07-24

申请人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

发明人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

IPC分类号： C08L19/00 ,  C08F212/14 ,  C08F216/14 ,  C08F218/10 ,  C08F220/10 ,  C08F220/12 ,  C08F220/30 ,  C08L21/00 ,  C08L27/12 ,  C08L33/04 ,  C08L33/06 ,  C08L33/08 ,  C08F30/08

CPC分类号： C08F220/30 ,  C08F212/14 ,  C08F216/14 ,  C08F218/10 ,  C08F220/12 ,  C08L33/08 ,  C08L27/12

摘要： A copolymer comprising an alkyl acrylate and an. unsaturated ester compound represented by the following general formula: (1) CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR', (2) CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (3) CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (4) CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or (5) CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR' where R is a hydrogen atom or a methyl group; R' is a hydrogen atom, an acyl group or a trialkylsilyl group; and Ph is a phenylene group, forms a blend rubber having a good heat resistance and a good amine resistance with a fluorine-containing elastomer.

摘要翻译： 一种包含丙烯酸烷基酯和 由下列通式表示的不饱和酯化合物：（1）CH2 = CRCOO（CH2）nPhOR'，（2）CH2 = CRCOO（CH2）nOCO（CH2）mPhOR'，（3）CH2 = CHOCO（CH2）nOCO ）mPhOR'，（4）CH2 = CHO（CH2）nOCO（CH2）mPhOR'或（5）CH2 = CHPh（CH2）nOCO（CH2）mPhOR'其中R是氢原子或甲基; R'是氢原子，酰基或三烷基甲硅烷基; 并且Ph是亚苯基，与含氟弹性体形成具有良好耐热性和良好耐胺性的共混橡胶。

公开(公告)号：US20090166984A1

公开(公告)日：2009-07-02

申请号：US12086211

申请日：2006-12-05

申请人： Noriyuki Matsui ,  Manabu Hirano ,  Yoshihiro Kuzumaki ,  Kuniyoshi Saito ,  Hayato Takada

发明人： Noriyuki Matsui ,  Manabu Hirano ,  Yoshihiro Kuzumaki ,  Kuniyoshi Saito ,  Hayato Takada

IPC分类号： F16J15/32

CPC分类号： C09K3/1021 ,  C08G18/10 ,  C08G18/44 ,  C08G2140/00 ,  C08G18/3206

摘要： In a rod sealing system, which comprises a buffer ring, a rod seal, and a dust seal, provided successively in this order from a fluid hydraulic side toward the outside in an annular clearance between two members in reciprocating motion, the buffer ring is made up of a thermoplastic polyurethane molding product obtained by subjecting a thermoplastic polyurethane molding product prepared by reaction of (A) a high molecular weight polycarbonatediol having a number average molecular weight Mn of 500-6,000, (B) an aromatic diisocyanate, and (C) a low molecular weight diol as a chain elongation agent in an NCO/OH ratio of 0.95-1.20, to heat treatment under conditions that a glass transition point (Tg) of hard phases becomes 170° C. or higher, preferably 170-230° C., and an endothermic peak area (ΔH) at Tg becomes 5 J/g or more, by differential scanning calorimetry. The buffer ring made up of the thermoplastic polyurethane molding product has a distinguished heat resistance capable of withstanding the service environmental temperature, particularly maximum 120° C., compression set characteristics, follow-up to eccentricity, etc.

摘要翻译： 在包括缓冲环，杆密封和防尘密封的杆密封系统中，以往复运动中的两个构件之间的环形间隙从液压侧朝向外部依次提供缓冲环，制成缓冲环 （A）数均分子量Mn为500〜6000的高分子量聚碳酸酯二醇，（B）芳香族二异氰酸酯和（C）的反应制得的热塑性聚氨酯成型体， 作为NCO / OH比为0.95-1.20的链延长剂的低分子量二醇，在硬相的玻璃化转变温度（Tg）为170℃以上，优选为170〜230℃的条件下进行热处理 通过差示扫描量热法测定Tg的吸热峰面积（DeltaH）为5J / g以上。 由热塑性聚氨酯成型制品制成的缓冲环具有耐受使用环境温度，特别是最高120℃，压缩永久变形特性，偏心率等特性的耐热性。

公开(公告)号：US5959037A

公开(公告)日：1999-09-28

申请号：US692686

申请日：1996-08-06

申请人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

发明人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

IPC分类号： C08K5/19 ,  C08F220/10 ,  C08F220/12 ,  C08F220/28 ,  C08K5/42 ,  C08K5/49 ,  C08L27/12 ,  C08L33/00 ,  C08L33/04 ,  C08L33/06 ,  C08L33/14 ,  C08L15/02

CPC分类号： C08F220/12 ,  C08L27/12 ,  C08L33/06

摘要： A novel acrylic copolymer elastomer comprising �I! an alkyl acrylate; �II! (a) CH.sub.a .dbd.CRCOOR.sub.2 OCOR.sub.1, (b) CH.sub.2 .dbd.CRCO�O(CH.sub.2) pCO!qOR.sub.1 or (c) CH.sub.2 .dbd.CRCOOR.sub.2 �CO(CH.sub.2)pO!qCOR.sub.1 ; and �III! (1) CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR', (2) CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (3) CH.sub.2 .dbd.CHOCO(CH.sub.2)mPhOR', (4) CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (5) CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or (6) CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR' where R is a hydrogen atom or a methyl group, R.sub.1 is an alkyl group, R.sub.2 is an alkylene group, R' is a hydrogen atom, an acyl group or a trialkylsilyl group and Ph is a phenylene group, provides a blend rubber having an improved cold resistance and an intermediate heat resistance between the heat resistance of acrylic copolymer elastomer and that of fluorine-containing elastomer, when blended with the fluorine-containing elastomer.

摘要翻译： 包含[I]丙烯酸烷基酯的新型丙烯酸共聚物弹性体; [II]（a）CHa = CRCOOR2OCOR1，（b）CH2 = CRCO [O（CH2）pCO] qOR1或（c）CH2 = CRCOOR2 [CO（CH2）pO] qCOR1; 和（III）（1）CH2 = CRCOO（CH2）nPhOR'，（2）CH2 = CRCOO（CH2）nOCO（CH2）mPhOR'，（3）CH2 = CHOCO（CH2）mPhOR'，（4）CH2 = CHOCO （CH2）nOCO（CH2）mPhOR'，（5）CH2 = CHO（CH2）nOCO（CH2）mPhOR'或（6）CH2 = CHPh（CH2）nOCO（CH2）mPhOR'其中R是氢原子或甲基 基团，R 1是烷基，R 2是亚烷基，R'是氢原子，酰基或三烷基甲硅烷基，Ph是亚苯基，提供了具有改善的耐寒性和中间耐热性的共混橡胶， 当与含氟弹性体共混时，丙烯酸共聚物弹性体和含氟弹性体的耐热性。

公开(公告)号：US5859144A

公开(公告)日：1999-01-12

申请号：US712701

申请日：1996-09-12

申请人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

发明人： Kuniyoshi Saito ,  Iwao Moriyama ,  Jun Okabe

IPC分类号： C08F259/08 ,  C08L15/02

CPC分类号： C08F259/08 ,  Y10S526/911

摘要： A rubber compound comprising a fluorine rubber component and an acrylic rubber component is produced by adding an acrylic monomer to an aqueous emulsion of fluorine-containing elastomer obtained by emulsion polymerization, using a fluorine-containing surfactant, followed by radical polymerization reaction. The obtained rubber compound can satify both of vulcanization moldability and heat aging resistance, and is at a lower cost than the expensive fluorine rubber.

摘要翻译： 通过使用含氟表面活性剂，然后进行自由基聚合反应，将丙烯酸类单体加入到通过乳液聚合得到的含氟弹性体的水性乳液中，从而制造包含氟橡胶组分和丙烯酸橡胶组分的橡胶混合物。 得到的橡胶化合物既可以使硫化成型性和耐热老化性均饱和，并且成本低于昂贵的氟橡胶。