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1.发明申请Selective Oxidation Agent of Hydrocarbons to Synthesis Gas Based on Separate Particles of O-Carrier and Hydrocarbon Activator 审中-公开基于O载体和烃活化剂分离颗粒的合成气体烃选择性氧化剂公开(公告)号：US20120018678A1
公开(公告)日：2012-01-26
申请号：US13247048
申请日：2011-09-28
IPC分类号： C01B3/34
CPC分类号： C01B13/0203 , C01B3/386 , C01B2203/0261 , C01B2203/0805 , C01B2203/0866 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1241 , Y02P20/52
摘要： A solid material is presented for the partial oxidation of natural gas. The solid material includes a solid oxygen carrying agent and a hydrocarbon activation agent. The material precludes the need for gaseous oxygen for the partial oxidation and provides better control over the reaction.
摘要翻译： 提供固体材料用于天然气的部分氧化。 固体材料包括固体氧气载体和烃活化剂。 该材料排除了对氧气进行部分氧化的需要，并提供对反应的更好控制。
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公开(公告)号：US07759282B2
公开(公告)日：2010-07-20
申请号：US12328503
申请日：2008-12-04
IPC分类号： B01J23/00
CPC分类号： C01G53/00 , B01D53/8603 , B01D2255/20753 , B01D2257/306 , B01J23/002 , B01J23/007 , B01J23/755 , B01J35/1019 , B01J35/1038 , B01J35/1061 , C01B3/48 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/0485 , C01B2203/1058 , C01P2002/54 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C10J2300/1618 , C10K1/00 , C10K3/04 , Y02P20/52
摘要： The present invention involves a process and materials for simultaneous desulfurization and water gas shift of a gaseous stream comprising contacting the gas stream with a nickel aluminate catalyst. The nickel aluminate catalyst is preferably selected from the group consisting of Ni2xAl2O2x+3, Ni(2−y)Ni0yAl2O(5−y), Ni(4−y)Ni0yAl2O(7−y), Ni(6−y)Ni0yAl2O(9−y), and intermediates thereof, wherein x≧0.5 and 0.01≦y≦2. Preferably, x is between 1 and 3. More preferably, the nickel containing compound further comprises Ni2xAl2O2x+3−zSz wherein 0≦z≦2x.
摘要翻译： 本发明涉及用于气态物流的同时脱硫和水煤气变换的方法和材料，包括使气流与铝酸镍催化剂接触。 镍酸镍催化剂优选选自Ni2xAl2O2x + 3，Ni（2-y）Ni0yAl2O（5-y），Ni（4-y）NiOyAl2O（7-y），Ni（6-y）Ni0Al2O2O 9-y）及其中间体，其中x≥0.5和0.01＆amp; nlE; y＆nlE; 2。 优选地，x在1和3之间。更优选地，含镍化合物还包含Ni 2 x Al 2 O x + 3-z S z，其中0和n 1; z和n 1; 2x。
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3.发明申请Simultaneous Warm Gas Desulfurization and CO-Shift for Improved Syngas Cleanup 有权同时进行暖气脱硫和CO转化，改善合成气净化公开(公告)号：US20100143229A1
公开(公告)日：2010-06-10
申请号：US12328501
申请日：2008-12-04
IPC分类号： B01D53/48
CPC分类号： B01D53/8603 , B01D2255/20753 , B01D2257/306 , B01J20/0225 , B01J20/08 , B01J23/002 , B01J23/007 , B01J23/755 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/031 , C01B3/16 , C01B3/48 , C01B2203/0283 , C01B2203/0415 , C01B2203/045 , C01B2203/0475 , C01B2203/0485 , C01G53/00 , C01G53/006 , C01P2002/22 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02P20/52
摘要： The present invention involves a process and materials for simultaneous desulfurization and water gas shift of a gaseous stream comprising contacting the gas stream with a nickel aluminate catalyst. The nickel aluminate catalyst is preferably selected from the group consisting of Ni2xAl2O2x+3, Ni(2−y)Ni0yAl2O(5−y), Ni(4−y)Ni0yAl2O(7−y), Ni(6−y)Ni0yAl2O(9−y), and intermediates thereof, wherein x≧0.5 and 0.01≦y≦2. Preferably, x is between 1 and 3. More preferably, the nickel containing compound further comprises Ni2xAl2O2x+3−zSz wherein 0≧z≧2x.
摘要翻译： 本发明涉及用于气态物流的同时脱硫和水煤气变换的方法和材料，包括使气流与铝酸镍催化剂接触。 镍酸镍催化剂优选选自Ni2xAl2O2x + 3，Ni（2-y）Ni0yAl2O（5-y），Ni（4-y）NiOyAl2O（7-y），Ni（6-y）Ni0Al2O2O 9-y）及其中间体，其中x≥0.5和0.01＆amp; nlE; y＆nlE; 2。 优选地，x在1和3之间。更优选地，含镍化合物还包含Ni2xAl2O2x + 3-zSz，其中0≥z≥2x。
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4.发明申请Selective Oxidation Agent of Hydrocarbons to Synthesis Gas Based on Separate Particles of O-Carrier and Hydrocarbon Activator 审中-公开基于O载体和烃活化剂分离颗粒的合成气体烃选择性氧化剂公开(公告)号：US20090123354A1
公开(公告)日：2009-05-14
申请号：US11939781
申请日：2007-11-14
CPC分类号： C01B13/0203 , C01B3/386 , C01B2203/0261 , C01B2203/0805 , C01B2203/0866 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1241 , Y02P20/52
摘要： A solid material is presented for the partial oxidation of natural gas. The solid material includes a solid oxygen carrying agent and a hydrocarbon activation agent. The material precludes the need for gaseous oxygen for the partial oxidation and provides better control over the reaction.
摘要翻译： 提供固体材料用于天然气的部分氧化。 固体材料包括固体氧气载体和烃活化剂。 该材料排除了对氧气进行部分氧化的需要，并提供对反应的更好控制。
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公开(公告)号：US06379641B1
公开(公告)日：2002-04-30
申请号：US09562730
申请日：2000-05-01
IPC分类号： C01B3320
CPC分类号： C01B39/06
摘要： Crystalline microporous rare earth silicates are provided. These microporous compositions have a three dimensional framework structure of at least silicon tetrahedral oxide units and at least one M oxide unit. M is a rare earth element. Optionally, the microporous compositions may contain as part of the framework an M′ element having a valence of +2, +3, +4 or +5 such as zinc (+2), iron (+3), zirconium (+4) and tantalum (+5). The composition is represented by the empirical formula: An(M1−zM′z)wSi1−yGeyOx where A is a cation such as sodium and “n”, “z”, “w”, “y” and “x” are the mole fractions of the various elements.
摘要翻译： 提供结晶微孔稀土硅酸盐。 这些微孔组合物具有至少硅四面体氧化物单元和至少一个M氧化物单元的三维骨架结构。 M是稀土元素。 任选地，微孔组合物可以作为骨架的一部分含有价数为+2，+ 3，+ 4或+ 5的M'元素，例如锌（+2），铁（+3），锆（+4） 和钽（+5）。 该组合物由经验式表示：其中A是阳离子如钠，“n”，“z”，“w”，“y”和“x”是各种元素的摩尔分数。
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6.发明授权Crystalline multinary metal oxide compositions, process for preparing and processes for using the composition 有权结晶多金属氧化物组合物，制备方法和使用该组合物的方法公开(公告)号：US06171571B2
公开(公告)日：2001-01-09
申请号：US09309040
申请日：1999-05-10
IPC分类号： C07C25326
CPC分类号： B01J23/002 , B01J23/04 , B01J23/20 , B01J23/28 , B01J35/002 , B01J35/1014 , B01J37/04 , B01J37/08 , B01J37/10 , B01J2523/00 , C01G33/006 , C01G39/006 , C01G41/006 , C01P2002/72 , C01P2006/12 , C01P2006/80 , C01P2006/82 , C07C253/24 , Y02P20/52 , B01J2523/11 , B01J2523/56 , B01J2523/68 , B01J2523/55 , B01J2523/69 , C07C255/08
摘要： A new family of crystalline metal oxide compositions have been synthesized. These compositions are described by the empirical formula: AnNbMxM′yM″mOp where A is an alkali metal cation, ammonium ion and mixtures thereof, M is tungsten, molybdenum, or mixtures thereof. M′ is vanadium, tantalum and mixtures thereof, and M″ is antimony, tellurium and mixtures thereof. M′ and M″ are optional metals. These compositions are characterized by having an x-ray diffraction pattern having at least one peak at a d spacing of about 3.9 Å. A hydrothermal synthesis procedure as well as processes using the composition, e.g., ammoxidation of propane, are also disclosed.
摘要翻译： 已经合成了一系列结晶金属氧化物组合物。 这些组合物由经验公式描述：其中A是碱金属阳离子，铵离子及其混合物，M是钨，钼或其混合物。 M'是钒，钽及其混合物，M“是锑，碲及其混合物。 M'和M“是任选的金属。 这些组合物的特征在于具有在约3.9的d间距具有至少一个峰的x射线衍射图。 还公开了水热合成方法以及使用该组合物的方法，例如丙烷的氨氧化。
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7.发明授权Process for removing contaminant metal ions from liquid streams using metallo germanate molecular sieves 失效使用金属锗酸盐分子筛从液体流中除去污染金属离子的方法
公开(公告)号：US5667695A
公开(公告)日：1997-09-16
申请号：US650566
申请日：1996-05-20
申请人： Robert L. Bedard , Lisa M. King , John D. Sherman
发明人： Robert L. Bedard , Lisa M. King , John D. Sherman
摘要： This invention relates to a process for removing contaminant metal ions from a liquid stream. The process involves contacting the liquid stream with a crystalline molecular sieve having the pharmacosiderite structure and having germanium and M metals as framework elements. Optionally, titanium and silicon can also be framework elements. The M metals can be any metal which has octahedral coordination and has a valence of +2, +3, +4 or +5. Illustrative of these M metals are niobium, tin, antimony, aluminum, gallium and tantalum. These molecular sieves are particularly effective in removing cesium and strontium ions from aqueous streams.
摘要翻译： 本发明涉及从液体流中除去污染金属离子的方法。 该方法包括使液体物流与具有药物依赖石结构并具有锗和M金属作为框架元件的结晶分子筛接触。 任选地，钛和硅也可以是框架元件。 M金属可以是具有八面体配位并具有+2，+3，+4或+5价态的任何金属。 这些M金属的例子是铌，锡，锑，铝，镓和钽。 这些分子筛特别有效地从水流中除去铯和锶离子。
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8.发明授权Simultaneous warm gas desulfurization and CO-shift for improved syngas cleanup 有权同时进行暖气脱硫和CO转化，改善合成气净化公开(公告)号：US07811474B2
公开(公告)日：2010-10-12
申请号：US12328501
申请日：2008-12-04
CPC分类号： B01D53/8603 , B01D2255/20753 , B01D2257/306 , B01J20/0225 , B01J20/08 , B01J23/002 , B01J23/007 , B01J23/755 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/031 , C01B3/16 , C01B3/48 , C01B2203/0283 , C01B2203/0415 , C01B2203/045 , C01B2203/0475 , C01B2203/0485 , C01G53/00 , C01G53/006 , C01P2002/22 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02P20/52
摘要： The present invention involves a process and materials for simultaneous desulfurization and water gas shift of a gaseous stream comprising contacting the gas stream with a nickel aluminate catalyst. The nickel aluminate catalyst is preferably selected from the group consisting of Ni2xAl2O2x+3, Ni(2−y)Ni0yAl2O(5−y), Ni(4−y)Ni0yAl2O(7−y), Ni(6−y)Ni0yAl2O(9−y), and intermediates thereof, wherein x≧0.5 and 0.01≦y≦2. Preferably, x is between 1 and 3. More preferably, the nickel containing compound further comprises Ni2xAl2O2x+3−zSz wherein 0≦z≦2x.
摘要翻译： 本发明涉及用于气态物流的同时脱硫和水煤气变换的方法和材料，包括使气流与铝酸镍催化剂接触。 镍酸镍催化剂优选选自Ni2xAl2O2x + 3，Ni（2-y）Ni0yAl2O（5-y），Ni（4-y）NiOyAl2O（7-y），Ni（6-y）Ni0Al2O2O 9-y）及其中间体，其中x≥0.5和0.01＆amp; nlE; y＆nlE; 2。 优选地，x在1和3之间。更优选地，含镍化合物还包含Ni 2 x Al 2 O x + 3-z S z，其中0和n 1; z和n 1; 2x。
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公开(公告)号：US20100135884A1
公开(公告)日：2010-06-03
申请号：US12492499
申请日：2009-06-26
IPC分类号： B01D53/48
CPC分类号： B01D53/02 , B01D53/48 , B01D53/8612 , B01D2255/2073 , B01D2255/2092 , B01D2257/30 , C01B3/56 , C01B2203/042 , C01B2203/048 , C01B2203/0485 , C10K1/20 , C10K1/34
摘要： The present invention involves a process and materials for desulfurization of a gaseous stream comprising contacting the gas stream with a manganese aluminate catalyst. The manganese aluminate catalyst is preferably selected from the group consisting of Mn2xAl2O2x+3, Mn(2−y)(MnO)yAl2O(5−y), Mn(4−y)(MnO)yAl2O(7−y), Mn(6−y)(MnO)yAl2O(9−y), Mn(1−z)(MnO)zAlO(3−z) and intermediates thereof, wherein x≧0.5, 0≦y≦2 and 0≦z≦1. Preferably, x is between 1 and 3.
摘要翻译： 本发明涉及用于气流脱硫的方法和材料，包括使气流与铝酸锰催化剂接触。 铝酸锰催化剂优选选自Mn2xAl2O2x + 3，Mn（2-y）（MnO）yAl2O（5-y），Mn（4-y）（MnO）yAl2O（7-y） 6-y）（MnO）yAl 2 O（9-y），Mn（1-z）（MnO）zAlO（3-z）及其中间体，其中x≥0.5,0和nlE; y和nlE; 2和0＆ 优选地，x在1和3之间。
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公开(公告)号：US07361792B2
公开(公告)日：2008-04-22
申请号：US11311037
申请日：2005-12-19
IPC分类号： C07C407/00
CPC分类号： C10L1/1811 , B01J23/002 , B01J23/34 , B01J2523/00 , C07B41/14 , B01J2523/22 , B01J2523/72 , B01J2523/11 , B01J2523/12 , B01J2523/51 , B01J2523/48
摘要： A process and catalyst for preparing organic hydroperoxides by oxidizing hydrocarbon compounds in the presence of an oxygen-containing gas and a catalyst containing a transition metal on a solid support.
摘要翻译： 一种通过在含氧气体和含有过渡金属的催化剂存在下在固体载体上氧化烃化合物来制备有机氢过氧化物的方法和催化剂。
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