公开(公告)号：US06896869B2

公开(公告)日：2005-05-24

申请号：US10412641

申请日：2003-04-11

申请人： Avelino Corma Canós ,  María Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  María Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

IPC分类号： B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C01B39/06 ,  C01B39/08 ,  C01B39/46 ,  C01B39/48 ,  C10G11/05 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16

CPC分类号： C10G45/64 ,  B01J29/04 ,  B01J29/046 ,  B01J29/70 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  C10G11/05 ,  C10G29/205 ,  C10G47/16

摘要： A microporous crystalline material of a zeolitic nature, that corresponds to the empirical formula x(M1/nXO2):yYO2:zGeO2:(1−z)TO2 wherein x has a value between 0 and 0.2; y has a value between 0 and 0.1; z has a value between 0 and 0.67; being at least one of the z, x and y above zero; M is selected between H+ and inorganic cations with a +n charge; X is at least one chemical element with a +3 oxidation status; Y is at least one chemical element with a +4 oxidation status; and T is at least one chemical element with a +4 oxidation status; and is also characterised by its X-ray diffraction pattern and its microporous properties, and can be employed as a catalyst or oxidating agent in the separation and transformation of organic compounds.

摘要翻译： 沸石性质的微孔结晶材料，其对应于经验公式<？in-line-formula description =“In-line Formulas”end =“lead”？> x（M 1 / n） XO 2 2）：y Y 2 2：zGeO 2：（1-z）2＆lt; 2＆lt;＆gt;＆lt; -formulae description =“In-line Formulas”end =“tail”？>其中x的值介于0和0.2之间; y的值在0到0.1之间; z的值介于0和0.67之间; 是z，x和y中的至少一个高于零; 在H +和无机阳离子之间选择一个+ n电荷; X是至少一种具有+3氧化状态的化学元素; Y是至少一种具有+4氧化状态的化学元素; 和T是具有+4氧化状态的至少一种化学元素; 并且其特征在于其X射线衍射图及其微孔性质，并且可用作有机化合物的分离和转化中的催化剂或氧化剂。

公开(公告)号：US07014836B2

公开(公告)日：2006-03-21

申请号：US10750329

申请日：2003-12-31

申请人： Avelino Corma Canós ,  Fernando Rey García ,  María Teresa Navarro Villalba ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  Fernando Rey García ,  María Teresa Navarro Villalba ,  Susana Valencia Valencia

IPC分类号： C01B39/48

CPC分类号： B01J29/70 ,  B01J29/035 ,  B01J29/04 ,  C01B37/005 ,  C01B39/06 ,  Y10S423/27

摘要： The present invention refers to a crystalline material that does not contain fluorides, with a composition in a roasted state corresponding to that of the material called ITQ-17 and that has a composition on an anhydrous base and in terms of oxide moles upon being synthesized, unroasted, represented by: xX2O3:(1−z)YO2:zGeO2:r/nRnO wherein: X is at least one trivalent element, Y is one or more tetravalent elements other than germanium, R is an organic structure directing compound, preferably the cation 1-methyl-4-aza,1-azoniumbicyclo[2.2.2]octane (DABMe+) or the cation 1,4-bis[N-(4-aza,1-azoniumbicyclo[2.2.2]octane)methyl]benzene (d-DABBz)+2 x varies between 0 and 0.02, z is comprised between 0.02 and 0.67, r varies between 0.01 and 0.5, and n is 1 or 2. It also refers to a process for synthesizing said material, as well as to the material obtained by said process and subjected to a step of post-synthesis to eliminate the organic component from its structure.

摘要翻译： 本发明涉及不含氟化物的结晶材料，其组成为与称为ITQ-17的材料相当的焙烧状态，其组成为无水碱和合成后的氧化物摩尔数， 未加工的，由以下代表：<？in-line-formula description =“In-line Formulas”end =“lead”？> xX 2 3（1-z ）YO 2：zGeO 2：r / n R n +2X在0和0.02之间变化，z在0.02和0.67之间，r在0.01和0.5之间变化，n是1或2.它也是指sy 使所述材料固化，以及通过所述方法获得的材料，并进行后合成步骤以从其结构中除去有机组分。