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    PRODUCTION OF MYRTANAL FROM BETA-PINENE EPOXIDE
    3.
    发明申请
    PRODUCTION OF MYRTANAL FROM BETA-PINENE EPOXIDE 有权
    由环戊二烯环氧化物生产木质素

    公开(公告)号：US20120330065A1

    公开(公告)日：2012-12-27

    申请号：US13517403

    申请日：2010-12-17

    申请人： Avelino Corma Canós ,  Michael Renz ,  Olalla De La Torre Alfaro

    发明人： Avelino Corma Canós ,  Michael Renz ,  Olalla De La Torre Alfaro

    IPC分类号： C07C45/58

    CPC分类号： B01J29/7615 ,  B01J29/7057 ,  B01J29/7815 ,  B01J35/002 ,  C01B39/02 ,  C07C45/58 ,  C07C47/347

    摘要： The present invention refers to a process for the production of myrtanal from β-pinene epoxide that comprises at least of putting this epoxide in contact with a microporous and crystalline catalyst with pores of a diameter of at least 0.52 nm with an empirical formula for the calcinated and dehydrated form of Hw(MwTixSnyZrzSi1-w-x-y-z)O2 where M is at least a metal with valence+3 selected from Al, B, Ga, Fe, Cr and combinations of these; w is a molar fraction of M with a value of between 0 and 2(x+y+z); x is a molar fraction of titanium and has a value of between 0 and 0.06; y is a molar fraction of tin and has a value of between 0 and 0.06; z is a molar fraction of zirconium and has a value of between 0 and 0.06; and where at least one of the three values “x”, “y” or “z” is different from zero. In the present invention, the microporous and crystalline catalyst preferably has pores of at least 0.52 nm and has a crystalline structure with an X-ray diffractogram of a zeolite beta.

    摘要翻译： 本发明涉及一种从环氧丙烷生产木药的方法，该方法至少包括使该环氧化物与直径为至少0.52nm的孔的微孔和结晶催化剂接触，其经验公式为 煅烧和脱水形式的Hw（MwTixSnyZrzSi1-wxyz）O2，其中M至少为选自Al，B，Ga，Fe，Cr的价数+3的金属及其组合; w是0至2（x + y + z）之间的M的摩尔分数; x是钛的摩尔分数，其值在0和0.06之间; y是锡的摩尔分数，其值在0和0.06之间; z是锆的摩尔分数，其值在0和0.06之间; 并且其中三个值x，y或z中的至少一个不同于零。 在本发明中，微孔和结晶催化剂优选具有至少0.52nm的孔，并具有具有β沸石的X射线衍射图的晶体结构。

    Separation method using an ITQ-29 zeolite material
    5.
    发明授权
    Separation method using an ITQ-29 zeolite material 失效
    使用ITQ-29沸石材料的分离方法

    公开(公告)号：US07611623B2

    公开(公告)日：2009-11-03

    申请号：US11662762

    申请日：2005-09-15

    申请人： Avelino Corma Canós ,  Fernando Rey Garcia ,  Susana Valencia Valencia

    发明人： Avelino Corma Canós ,  Fernando Rey Garcia ,  Susana Valencia Valencia

    IPC分类号： C07C7/13 ,  B01D53/85 ,  B01D53/86

    CPC分类号： C07C7/12 ,  B01D53/02 ,  B01D2253/108 ,  B01D2257/702 ,  B01D2257/80 ,  C01B39/145

    摘要： The invention relates to a method of separating the components of a mixture. The inventive method is characterised in that it comprises the following steps: (a) the bringing into contact of the components of a mixture selected from (i) at least two hydrocarbons, (ii) a mixture containing at least nitrogen and oxygen, and (iii) at least one hydrocarbon and water, with an ITQ-29 zeolite material having a T(IV)/T(III) ratio of greater than 7, whereby T(IV) denotes one or more tetravalent elements and T(III) denotes one or more trivalent elements; (b) preferential adsorption of one or more of the components by the ITQ-29 zeolite material and (c) recovery of one or more of the components, preferably for the separation of hydrocarbon mixtures, such as linear or branched olefins from paraffins.

    摘要翻译： 本发明涉及一种分离混合物组分的方法。 本发明的方法的特征在于其包括以下步骤：（a）使选自（i）至少两种烃的混合物的组分与（ii）至少含有氮和氧的混合物和（ iii）至少一种烃和水，其具有T（IV）/ T（III）比大于7的ITQ-29沸石材料，由此T（IV）表示一种或多种四价元素，并且T（III）表示 一种或多种三价元素; （b）通过ITQ-29沸石材料优先吸附一种或多种组分，和（c）回收一种或多种组分，优选用于从石蜡中分离烃混合物，例如直链或支链烯烃。

    Microporous crystalline material (ITQ-19) with laminar characteristics, preparation method and use thereof as a catalyst in the catalytic conversion of organic compounds
    7.
    发明授权
    Microporous crystalline material (ITQ-19) with laminar characteristics, preparation method and use thereof as a catalyst in the catalytic conversion of organic compounds 失效
    具有层状特性的微孔结晶材料（ITQ-19），其制备方法和用途作为催化转化有机化合物中的催化剂

    公开(公告)号：US07029651B2

    公开(公告)日：2006-04-18

    申请号：US10630368

    申请日：2003-07-30

    申请人： Avelino Corma Canós ,  Urbano Díaz Morales ,  Vicente Fornes Segui

    发明人： Avelino Corma Canós ,  Urbano Díaz Morales ,  Vicente Fornes Segui

    IPC分类号： C01B39/48

    CPC分类号： C01B33/38 ,  B01J29/035 ,  B01J29/70 ,  C01B37/02 ,  C01B39/48 ,  C10G45/64

    摘要： The invention relates to a novel microporous crystalline material ITQ-19 used in the catalytic conversion of organic compounds, such as, for example, the dewaxing and isodewaxing of paraffins and the disproportionation of toluene. Said material has a characteristic X-ray diffractogram, a high absorption capacity and the empirical formula x(M1/nXO2):yYO2:(1−y)SiO2 wherein x has a value less than 0.2; y has a value less than 0.1; M is at least an inorganic cation with a +n charge; X is at least a chemical element having oxidation state +3, preferably selected among Al, Ga, B, Cr, Fe; Y is at least a chemical element with oxidation stated +4, preferably selected among Ge, Ti, Sn, V. The inventive material can be obtained by means of a preparation process involving the use of one or more organic additives in a reaction mix which is crystallized by heating.

    摘要翻译： 本发明涉及用于有机化合物的催化转化的新型微孔结晶材料ITQ-19，例如石蜡的脱蜡和异戊二烯化和甲苯的歧化。 所述材料具有特征X射线衍射图，高吸收能力和经验公式x（M 1 / n 2 X 2 2）：y Y 2 O 2 >：（1-y）SiO 2其中x的值小于0.2; y的值小于0.1; M至少为+ n电荷的无机阳离子; X至少是氧化态为+3的化学元素，优选选自Al，Ga，B，Cr，Fe; Y至少是一种化学元素，其氧化值为+4，优选选自Ge，Ti，Sn，V。本发明的材料可以通过涉及在反应混合物中使用一种或多种有机添加剂的制备方法获得， 通过加热结晶。

    Acid oxide with micro and mesoporous characteristics: ITQ-36
    9.
    发明授权
    Acid oxide with micro and mesoporous characteristics: ITQ-36 有权
    具有微孔和介孔特性的酸性氧化物：ITQ-36

    公开(公告)号：US06555090B1

    公开(公告)日：2003-04-29

    申请号：US09830819

    申请日：2001-07-06

    申请人： Antonio Chica Lara ,  Avelino Corma Canós ,  Vicente Fornés Segúi ,  Urbano Díaz Morales

    发明人： Antonio Chica Lara ,  Avelino Corma Canós ,  Vicente Fornés Segúi ,  Urbano Díaz Morales

    IPC分类号： C01B3400

    CPC分类号： C01B39/48 ,  B01J29/049 ,  B01J29/70 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42

    摘要： The invention deals with a microporous crystalline material, with a characteristic X-ray diffractogram, comprised of oxygen tetrahedra and a metal (T+4 and T+3) with the possibility of introducing surface acidity produced by the substitution in the lattice of some T+4 cations by T+3 cations, which gives rise to a structural charge deficiency that may be compensated by protons, Brönsted acidity, and/or high ratio radium charge cations, Lewis acidity; and the obtaining method thereof, based on the preparation of a gel, its hydrothermal treatment under controlled conditions and the treatment of the resulting laminar material with a solution of an organic compound, a swollen material being obtained, which is subjected to a treatment for the formation of interlaminar pillars of polymeric oxides, obtaining a pillared material that maintains the separation between the sheets, even after calcination.

    摘要翻译： 本发明涉及一种微孔结晶材料，具有由氧四面体和金属（T + 4和T + 3）组成的特征X射线衍射图，其可能性通过在一些T的晶格中引入由取代产生的表面酸度 + 4阳离子，其导致结构电荷缺陷，其可以通过质子，布朗斯台德酸度和/或高比例镭电荷阳离子，路易斯酸度; 以及其获得方法，基于凝胶的制备，其在受控条件下的水热处理，以及所得到的层状材料用有机化合物（获得的溶胀物质）的溶液进行处理， 形成聚合物氧化物的层间柱，获得即使在煅烧之后也保持片材之间的分离的柱状材料。

    Process for the direct synthesis of Cu-SAPO-34
    10.
    发明授权
    Process for the direct synthesis of Cu-SAPO-34 有权
    直接合成Cu-SAPO-34的方法

    公开(公告)号：US09561498B2

    公开(公告)日：2017-02-07

    申请号：US14395872

    申请日：2012-04-27

    申请人： Raquel Martinez Franco ,  Manuel Moliner Marin ,  Avelino Corma Canós ,  Arkady Kustov ,  Joakim Reimer Thøgersen

    发明人： Raquel Martinez Franco ,  Manuel Moliner Marin ,  Avelino Corma Canós ,  Arkady Kustov ,  Joakim Reimer Thøgersen

    IPC分类号： C01B39/54 ,  B01J29/85 ,  C01B37/08 ,  B01D53/86 ,  B01J37/08

    CPC分类号： B01J29/85 ,  B01D53/8628 ,  B01D2255/50 ,  B01D2257/404 ,  B01J37/08 ,  B01J2229/183 ,  C01B37/08 ,  C01B39/54

    摘要： A process for the direct synthesis of Cu-SAPO-34 comprising at least the steps: preparation of a mixture of water, at least one silicon source, at least one Al source, at least one P source, at least one Cu source, at least one 0SDA1 (any polyamine), and at least one OSDA2 source (where OSDA2 is any organic molecule capable of directing the synthesis of SAPO 34); and where the final synthesis mixture has the molar composition: a Si:0.5 Al:c Cu:d OSDA1:e OSDA2:f H2O wherein a is in the range from 0.01 to 0.3; b is in the range from 0.2 to 0.49; c is in the range from 0.001 to 0.6; d is in the range from 0.001 to 0.6; e is in the range from 0.001 to 2; f is in the range 1 to 200; hydrothermal treatment of the mixture at 80−200° C. until formation of the crystalline material, and recovery of the crystalline material.

    摘要翻译： 一种用于直接合成Cu-SAPO-34的方法，至少包括以下步骤：制备水，至少一种硅源，至少一种Al源，至少一种P源，至少一种Cu源， 至少一个0SDA1（任何多胺）和至少一个OSDA2源（其中OSDA2是能够指导SAPO 34的合成的任何有机分子）; 并且其中最终合成混合物具有以下摩尔组成：Si：0.5 Al：c Cu：d OSDA1：e OSDA2：fH2O，其中a在0.01至0.3的范围内; b在0.2〜0.49的范围内; c在0.001至0.6的范围内; d在0.001至0.6的范围内; e在0.001至2的范围内; f在1到200的范围内; 在80-200℃下对混合物进行水热处理，直到形成结晶材料，并回收结晶材料。