公开(公告)号：US08877345B2

公开(公告)日：2014-11-04

申请号：US12933448

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: G01F1/688 ,  C25D1/04 ,  C25D1/08 ,  C25D1/00 ,  B01J23/42 ,  B82Y30/00 ,  B01J35/00 ,  B01J23/72 ,  B22F3/00 ,  B01J19/00 ,  B82Y15/00 ,  B81C99/00 ,  B22F1/00 ,  C25D5/18

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns the production of segmented nanowires and components having said segmented nanowires.For the production of the nanowire structural element, a template based process is used preferably, wherein the electrochemical deposition of the nanowires in nanopores is carried out. In this manner, numerous nanowires are created in the template foil.For the electrochemical deposition of the nanowires, a reversed pulse procedure with an alternating sequence consisting of cathodic deposition pulses and anodic counter-pulses is carried out. By this means, segmented nanowires can be produced.

Abstract translation: 本发明涉及具有所述分段纳米线的分段纳米线和组分的生产。 为了制造纳米线结构元件，优选使用基于模板的方法，其中进行纳米线中的纳米线的电化学沉积。 以这种方式，在模板箔中形成许多纳米线。 对于纳米线的电化学沉积，执行具有由阴极沉积脉冲和阳极反向脉冲组成的交替序列的反向脉冲程序。 通过这种方式，可以生产分段的纳米线。

公开(公告)号：US20110211994A1

公开(公告)日：2011-09-01

申请号：US12933184

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: G01N25/00 ,  G01N33/00 ,  B01J19/00 ,  B01J37/34 ,  B01J37/02 ,  B01J35/06 ,  B82Y40/00 ,  B82Y30/00

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element suited for use in a microreactor system or microcatalyzer system.A template based process is used for the production of the nanowire structural element, wherein the nanowires are electrochemically depositioned in the nanopores. The irradiation is carried out at different angles, such that a nanowire network is formed. The hollow chamber-like structure in the nanowire network is established through the dissolving of the template foil and removal of the dissolved template material. The interconnecting of the nanowires provides stability to the nanowire structural element and an electrical connection between the nanowires is created thereby.

Abstract translation: 本发明涉及适用于微反应器系统或微型催化剂系统的纳米线结构元件。 使用基于模板的工艺来生产纳米线结构元件，其中纳米线被电化学沉积在纳米孔中。 以不同的角度进行照射，形成纳米线网络。 通过模板箔的溶解和去除溶解的模板材料来建立纳米线网络中的中空室状结构。 纳米线的互连提供了对纳米线结构元件的稳定性，并且由此形成纳米线之间的电连接。

公开(公告)号：US20110174069A1

公开(公告)日：2011-07-21

申请号：US12933448

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: G01F1/688 ,  C25D5/02 ,  C25D7/06 ,  B32B3/26 ,  B01J19/00 ,  B82Y99/00

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns the production of segmented nanowires and components having said segmented nanowires.For the production of the nanowire structural element, a template based process is used preferably, wherein the electrochemical deposition of the nanowires in nanopores is carried out. In this manner, numerous nanowires are created in the template foil.For the electrochemical deposition of the nanowires, a reversed pulse procedure with an alternating sequence consisting of cathodic deposition pulses and anodic counter-pulses is carried out. By this means, segmented nanowires can be produced.

Abstract translation: 本发明涉及具有所述分段纳米线的分段纳米线和组分的生产。 为了制造纳米线结构元件，优选使用基于模板的方法，其中进行纳米线中的纳米线的电化学沉积。 以这种方式，在模板箔中形成许多纳米线。 对于纳米线的电化学沉积，执行具有由阴极沉积脉冲和阳极反向脉冲组成的交替序列的反向脉冲程序。 通过这种方式，可以生产分段的纳米线。

公开(公告)号：US09222185B2

公开(公告)日：2015-12-29

申请号：US12933184

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  B01J19/00 ,  B01J23/42 ,  B01J23/72 ,  B01J35/00 ,  B22F1/00 ,  B22F3/00 ,  B81C99/00 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element suited for use in a microreactor system or microcatalyzer system. A template based process is used for the production of the nanowire structural element, wherein the nanowires are electrochemically depositioned in the nanopores. The irradiation is carried out at different angles, such that a nanowire network is formed. The hollow chamber-like structure in the nanowire network is established through the dissolving of the template foil and removal of the dissolved template material. The interconnecting of the nanowires provides stability to the nanowire structural element and an electrical connection between the nanowires is created thereby.

Abstract translation: 本发明涉及适用于微反应器系统或微型催化剂系统的纳米线结构元件。 使用基于模板的工艺来生产纳米线结构元件，其中纳米线被电化学沉积在纳米孔中。 以不同的角度进行照射，形成纳米线网络。 通过模板箔的溶解和去除溶解的模板材料来建立纳米线网络中的中空室状结构。 纳米线的互连提供了对纳米线结构元件的稳定性，并且由此形成纳米线之间的电连接。

公开(公告)号：US08685348B2

公开(公告)日：2014-04-01

申请号：US12933254

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: B01J8/00

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element which is suited for implementation in, for example, a microreactor system or microcatalyzer system. For the production of the nanowire structural element, a template based process is used wherein the electrochemical deposition of the nanowires in nanopores is ideally carried out at least until caps are formed and said caps ideally are at least partially merged together. After reinforcing the two cover layers the structured hollow chamber between the two cover layers is cleared by dissolving the template foil and removing the dissolved template material, wherein the two cover layers remain intact. In this manner, a stable sandwich-like nanostructure is constructed with a two-dimensional hollow chamber-like structure in the plane parallel to the cover layers contained on both sides by the cover layers and permeated in a column-like manner with nanowires.

Abstract translation: 本发明涉及一种纳米线结构元件，其适用于例如微反应器系统或微型催化剂系统。 为了生产纳米线结构元件，使用基于模板的方法，其中纳米线中的纳米线的电化学沉积理想地至少直到形成帽并且所述帽理想地至少部分地并入在一起。 在加强两个覆盖层之后，通过溶解模板箔并除去溶解的模板材料来清除两个覆盖层之间的结构化中空室，其中两个覆盖层保持完整。 以这种方式，在与覆盖层两侧包含的覆盖层平行的平面中，通过二维中空室状结构构造稳定的夹层状纳米结构，并以纳米线的柱状渗透。

公开(公告)号：US20110223412A1

公开(公告)日：2011-09-15

申请号：US12933254

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: B32B5/16 ,  H01R43/00 ,  G01N33/00 ,  B01J19/00 ,  B01J8/02 ,  B82Y99/00 ,  B82Y40/00

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element which is suited for implementation in, for example, a microreactor system or microcatalyzer system.For the production of the nanowire structural element, a template based process is used wherein the electrochemical deposition of the nanowires in nanopores is ideally carried out at least until caps are formed and said caps ideally are at least partially merged together. After reinforcing the two cover layers the structured hollow chamber between the two cover layers is cleared by dissolving the template foil and removing the dissolved template material, wherein the two cover layers remain intact. In this manner, a stable sandwich-like nanostructure is constructed with a two-dimensional hollow chamber-like structure in the plane parallel to the cover layers contained on both sides by the cover layers and permeated in a column-like manner with nanowires.

Abstract translation: 本发明涉及一种纳米线结构元件，其适用于例如微反应器系统或微型催化剂系统。 为了生产纳米线结构元件，使用基于模板的方法，其中纳米线中的纳米线的电化学沉积理想地至少直到形成帽并且所述帽理想地至少部分地并入在一起。 在加强两个覆盖层之后，通过溶解模板箔并除去溶解的模板材料来清除两个覆盖层之间的结构化中空室，其中两个覆盖层保持完整。 以这种方式，在与覆盖层两侧包含的覆盖层平行的平面中，通过二维中空室状结构构造稳定的夹层状纳米结构，并以纳米线的柱状渗透。