公开(公告)号：US09222185B2

公开(公告)日：2015-12-29

申请号：US12933184

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  B01J19/00 ,  B01J23/42 ,  B01J23/72 ,  B01J35/00 ,  B22F1/00 ,  B22F3/00 ,  B81C99/00 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element suited for use in a microreactor system or microcatalyzer system. A template based process is used for the production of the nanowire structural element, wherein the nanowires are electrochemically depositioned in the nanopores. The irradiation is carried out at different angles, such that a nanowire network is formed. The hollow chamber-like structure in the nanowire network is established through the dissolving of the template foil and removal of the dissolved template material. The interconnecting of the nanowires provides stability to the nanowire structural element and an electrical connection between the nanowires is created thereby.

Abstract translation: 本发明涉及适用于微反应器系统或微型催化剂系统的纳米线结构元件。 使用基于模板的工艺来生产纳米线结构元件，其中纳米线被电化学沉积在纳米孔中。 以不同的角度进行照射，形成纳米线网络。 通过模板箔的溶解和去除溶解的模板材料来建立纳米线网络中的中空室状结构。 纳米线的互连提供了对纳米线结构元件的稳定性，并且由此形成纳米线之间的电连接。

公开(公告)号：US08685348B2

公开(公告)日：2014-04-01

申请号：US12933254

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: B01J8/00

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element which is suited for implementation in, for example, a microreactor system or microcatalyzer system. For the production of the nanowire structural element, a template based process is used wherein the electrochemical deposition of the nanowires in nanopores is ideally carried out at least until caps are formed and said caps ideally are at least partially merged together. After reinforcing the two cover layers the structured hollow chamber between the two cover layers is cleared by dissolving the template foil and removing the dissolved template material, wherein the two cover layers remain intact. In this manner, a stable sandwich-like nanostructure is constructed with a two-dimensional hollow chamber-like structure in the plane parallel to the cover layers contained on both sides by the cover layers and permeated in a column-like manner with nanowires.

Abstract translation: 本发明涉及一种纳米线结构元件，其适用于例如微反应器系统或微型催化剂系统。 为了生产纳米线结构元件，使用基于模板的方法，其中纳米线中的纳米线的电化学沉积理想地至少直到形成帽并且所述帽理想地至少部分地并入在一起。 在加强两个覆盖层之后，通过溶解模板箔并除去溶解的模板材料来清除两个覆盖层之间的结构化中空室，其中两个覆盖层保持完整。 以这种方式，在与覆盖层两侧包含的覆盖层平行的平面中，通过二维中空室状结构构造稳定的夹层状纳米结构，并以纳米线的柱状渗透。

公开(公告)号：US07713397B2

公开(公告)日：2010-05-11

申请号：US11891124

申请日：2007-08-09

Applicant: Dobri Dobrev ,  Johann Vetter ,  Reinhard Neumann ,  Norbert Angert

Inventor： Dobri Dobrev ,  Johann Vetter ,  Reinhard Neumann ,  Norbert Angert

IPC: C25D1/00 ,  C25D1/08

CPC classification number: B01D67/0069 ,  B01D67/006 ,  B01D67/0072 ,  B01D67/009 ,  B01D69/02 ,  B01D71/022 ,  B01D2325/021 ,  C25D1/08

Abstract: The invention relates to a metal membrane filter (1) and to a method and apparatus for the production thereof. The metal membrane filter (1) has rectilinear, cylindrical filter pores (2), which are arranged statistically distributed on the metal membrane filter surface (3) in a density of from a single filter pore (2) per cm2 up to 107 filter pores (2) per cm2. The average diameter of the filter pores (2) is uniform for all filter pores (2) and is from a few tens of nm up to several micrometers. The metal membrane filter (1) comprises a metal electro-deposited with rectilinear, cylindrical filter pores (2) or a correspondingly electro-deposited metal alloy.

Abstract translation: 本发明涉及一种金属膜过滤器（1）及其制造方法和装置。 金属膜过滤器（1）具有直线，圆柱形的过滤器孔（2），其以从每单位过滤器孔（2）至101个过滤孔的密度统计分布在金属膜过滤器表面（3）上 （2）/ cm2。 过滤器孔（2）的平均直径对于所有过滤器孔（2）是均匀的，并且是从几十nm到几微米。 金属膜过滤器（1）包括电沉积有直线的圆柱形过滤器孔（2）或相应的电沉积金属合金的金属。

公开(公告)号：US06923651B2

公开(公告)日：2005-08-02

申请号：US10952974

申请日：2004-09-29

Applicant: Norbert Angert ,  Dobri Dobrev ,  Reinhard Neumann ,  Johann Vetter

Inventor： Norbert Angert ,  Dobri Dobrev ,  Reinhard Neumann ,  Johann Vetter

IPC: H01L21/48 ,  H01L23/498 ,  H05K3/00 ,  H05K3/42 ,  H01R12/00

CPC classification number: H01L23/49827 ,  H01L21/486 ,  H01L2924/0002 ,  H05K3/002 ,  H05K3/423 ,  H05K2201/09827 ,  H05K2201/10378 ,  H05K2203/0733 ,  H05K2203/092 ,  Y10T428/24273 ,  Y10T428/24322 ,  H01L2924/00

Abstract: The invention relates to a sheet material having metal points (8) and surfaces (2 and 3) located opposite one another, wherein the sheet material (1) has through-holes (4) from one surface (2) to the surface (3) located opposite. Those through-holes (4) are filled with needle-point-shaped conical pins (5) or through-contacts (6) of electrically conducting material, whereas the surrounding sheet material in a preferred embodiment of the invention consists of an insulating plastics material (7). In a further embodiment of the invention, instead of the insulating plastics material (7) there are provided needle-shaped pins that are surrounded by air or some other gaseous medium. The invention further relates to a method for the production of such a sheet material (1) and to forms of use of the sheet material (1).

Abstract translation: 本发明涉及具有金属点（8）和彼此相对定位的表面（2和3）的片材，其中片材（1）具有从一个表面（2）到表面（3）的通孔（4） ）位于对面。 那些通孔（4）填充有导电材料的针尖形锥形销（5）或通孔（6），而在本发明的优选实施例中，周围的片材由绝缘塑料 （7）。 在本发明的另一实施例中，代替绝缘塑料材料（7），提供了被空气或一些其它气体介质包围的针状销。 本发明还涉及生产这种片材（1）的方法和片材（1）的使用形式。

公开(公告)号：US20050064139A1

公开(公告)日：2005-03-24

申请号：US10952974

申请日：2004-09-29

Applicant: Norbert Angert ,  Dobri Dobrev ,  Reinhard Neumann ,  Johann Vetter

Inventor： Norbert Angert ,  Dobri Dobrev ,  Reinhard Neumann ,  Johann Vetter

IPC: H01L21/48 ,  H01L23/498 ,  H05K3/00 ,  H05K3/42 ,  B32B3/10

CPC classification number: H01L23/49827 ,  H01L21/486 ,  H01L2924/0002 ,  H05K3/002 ,  H05K3/423 ,  H05K2201/09827 ,  H05K2201/10378 ,  H05K2203/0733 ,  H05K2203/092 ,  Y10T428/24273 ,  Y10T428/24322 ,  H01L2924/00

Abstract: The invention relates to a sheet material having metal points (8) and surfaces (2 and 3) located opposite one another, wherein the sheet material (1) has through-holes (4) from one surface (2) to the surface (3) located opposite. Those through-holes (4) are filled with needle-point-shaped conical pins (5) or through-contacts (6) of electrically conducting material, whereas the surrounding sheet material in a preferred embodiment of the invention consists of an insulating plastics material (7). In a further embodiment of the invention, instead of the insulating plastics material (7) there are provided needle-shaped pins that are surrounded by air or some other gaseous medium. The invention further relates to a method for the production of such a sheet material (1) and to forms of use of the sheet material (1).

Abstract translation: 本发明涉及具有金属点（8）和彼此相对定位的表面（2和3）的片材，其中片材（1）具有从一个表面（2）到表面（3）的通孔（4） ）位于对面。 那些通孔（4）填充有导电材料的针尖形锥形销（5）或通孔（6），而在本发明的优选实施例中，周围的片材由绝缘塑料 （7）。 在本发明的另一实施例中，代替绝缘塑料材料（7），提供了被空气或一些其它气体介质包围的针状销。 本发明还涉及生产这种片材（1）的方法和片材（1）的使用形式。

公开(公告)号：US07708871B2

公开(公告)日：2010-05-04

申请号：US10528520

申请日：2003-09-24

Applicant: Zuzanna Siwy ,  Jan Behrends ,  Niels Fertig ,  Andrzej Fulinski ,  Charles R Martin ,  Reinhard Neumann ,  Christina Trautmann ,  Eugenia Toimil Molares

Inventor： Zuzanna Siwy ,  Jan Behrends ,  Niels Fertig ,  Andrzej Fulinski ,  Charles R Martin ,  Reinhard Neumann ,  Christina Trautmann ,  Eugenia Toimil Molares

IPC: G01N27/447 ,  G01N27/453

CPC classification number: G01N33/48721 ,  B01D61/425 ,  B01D67/0032 ,  B01D67/0088 ,  B01D69/02 ,  B01D71/38 ,  B01D71/50 ,  B01D71/64 ,  B01D2323/34 ,  B01D2325/021 ,  B01D2325/26

Abstract: The present invention relates to an apparatus having a nanodevice (1) for controlling the flow of charged particles in an electrolyte. Such apparatus comprises an electrolytic bath container (2) divided by a polymeric membrane foil (3) into a first (4) and a second compartment (5), wherein each compartment (4, 5) comprises an electrode (6, 7) connected to a voltage supply (8). Further the apparatus comprises at least one asymmetric pore (9) forming a via hole through said foil (3), wherein said pore (9) provides a narrow opening (10) of a diameter in the range of several nanometers down to about one nanometer on a front side (11) of said foil (3) and a wide opening (12) in the range of several ten nanometers up to several hundred nanometers on a back side (13) of said foil (3). Further, the apparatus comprises an electrically conductive layer (14) surrounding said narrow opening (10) on said front side (11) and a gate voltage supply (15) connected to said electrically conductive layer (14) on said front side (11) of said foil (3) controlling the flow of charged particles within said nanodevice (1) from said first compartment (4) to said second compartment (5) vice versa. The invention further relates to a method for producing such a nanodevice (1).

Abstract translation: 本发明涉及一种具有用于控制电解质中带电粒子的流动的纳米装置（1）的装置。 这种设备包括由聚合物膜片（3）分成第一（4）和第二隔室（5）的电解浴容器（2），其中每个隔室（4,5）包括连接的电极（6,7） 到电源（8）。 此外，该装置包括形成穿过所述箔（3）的通孔的至少一个不对称孔（9），其中所述孔（9）提供直径在几纳米至约一纳米范围内的直径的窄开口（10） 在所述箔（3）的前侧（11）和在所述箔（3）的背面（13）上的几十纳米至几百纳米范围内的宽开口（12）。 此外，该装置包括围绕所述前侧（11）上的所述窄开口（10）的导电层（14）和连接到所述前侧（11）上的所述导电层（14）的栅极电压源（15） 所述箔（3）控制所述纳米装置（1）内从所述第一隔室（4）到所述第二隔室（5）的带电粒子的流动反之亦然。 本发明还涉及一种用于制造这种纳米器件（1）的方法。

公开(公告)号：US20110223412A1

公开(公告)日：2011-09-15

申请号：US12933254

申请日：2009-03-12

Applicant: Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

Inventor： Thomas Cornelius ,  Wolfgang Ensinger ,  Reinhard Neumann ,  Markus Rauber

IPC: B32B5/16 ,  H01R43/00 ,  G01N33/00 ,  B01J19/00 ,  B01J8/02 ,  B82Y99/00 ,  B82Y40/00

CPC classification number: C25D1/006 ,  B01J19/0093 ,  B01J23/42 ,  B01J23/72 ,  B01J35/0006 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00846 ,  B01J2219/00853 ,  B01J2219/0086 ,  B01J2219/00873 ,  B22F1/0025 ,  B22F3/002 ,  B81B2201/0292 ,  B81B2201/051 ,  B81C99/0085 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25D1/00 ,  C25D1/003 ,  C25D1/04 ,  C25D1/08 ,  C25D5/18 ,  G01F1/688 ,  G01N25/00 ,  Y10S977/762 ,  Y10T29/49117 ,  Y10T428/12201 ,  Y10T428/12389 ,  Y10T428/24562 ,  Y10T428/24893 ,  Y10T428/25

Abstract: The invention concerns a nanowire structural element which is suited for implementation in, for example, a microreactor system or microcatalyzer system.For the production of the nanowire structural element, a template based process is used wherein the electrochemical deposition of the nanowires in nanopores is ideally carried out at least until caps are formed and said caps ideally are at least partially merged together. After reinforcing the two cover layers the structured hollow chamber between the two cover layers is cleared by dissolving the template foil and removing the dissolved template material, wherein the two cover layers remain intact. In this manner, a stable sandwich-like nanostructure is constructed with a two-dimensional hollow chamber-like structure in the plane parallel to the cover layers contained on both sides by the cover layers and permeated in a column-like manner with nanowires.

Abstract translation: 本发明涉及一种纳米线结构元件，其适用于例如微反应器系统或微型催化剂系统。 为了生产纳米线结构元件，使用基于模板的方法，其中纳米线中的纳米线的电化学沉积理想地至少直到形成帽并且所述帽理想地至少部分地并入在一起。 在加强两个覆盖层之后，通过溶解模板箔并除去溶解的模板材料来清除两个覆盖层之间的结构化中空室，其中两个覆盖层保持完整。 以这种方式，在与覆盖层两侧包含的覆盖层平行的平面中，通过二维中空室状结构构造稳定的夹层状纳米结构，并以纳米线的柱状渗透。

公开(公告)号：US20080023337A1

公开(公告)日：2008-01-31

申请号：US11891124

申请日：2007-08-09

Applicant: Dobri Dobrev ,  Johann Vetter ,  Reinhard Neumann ,  Norbert Angert

Inventor： Dobri Dobrev ,  Johann Vetter ,  Reinhard Neumann ,  Norbert Angert

IPC: C23C28/00 ,  C25D3/00

CPC classification number: B01D67/0069 ,  B01D67/006 ,  B01D67/0072 ,  B01D67/009 ,  B01D69/02 ,  B01D71/022 ,  B01D2325/021 ,  C25D1/08

Abstract: The invention relates to a metal membrane filter (1) and to a method and apparatus for the production thereof. The metal membrane filter (1) has rectilinear, cylindrical filter pores (2), which are arranged statistically distributed on the metal membrane filter surface (3) in a density of from a single filter pore (2) per cm2 up to 107 filter pores (2) per cm2. The average diameter of the filter pores (2) is uniform for all filter pores (2) and is from a few tens of nm up to several micrometres. The metal membrane filter (1) comprises a metal electro-deposited with rectilinear, cylindrical filter pores (2) or a correspondingly electro-deposited metal alloy.

Abstract translation: 本发明涉及一种金属膜过滤器（1）及其制造方法和装置。 金属膜过滤器（1）具有直线，圆柱形的过滤器孔（2），它们以每cm 2的单个过滤器孔（2）的密度统计分布在金属膜过滤器表面（3）上， / SUP>高达10 7个过滤孔（2）/ cm 2。 过滤器孔（2）的平均直径对于所有过滤器孔（2）是均匀的，并且从几十nm到几微米。 金属膜过滤器（1）包括电沉积有直线的圆柱形过滤器孔（2）或相应的电沉积金属合金的金属。

公开(公告)号：US20060163071A1

公开(公告)日：2006-07-27

申请号：US10528520

申请日：2003-09-24

Applicant: Zuzanna Siwy ,  Jan Behrends ,  Niels Fertig ,  Andrzej Fulinski ,  Charles Martin ,  Reinhard Neumann ,  Christina Trautmann ,  Toimil Molares

Inventor： Zuzanna Siwy ,  Jan Behrends ,  Niels Fertig ,  Andrzej Fulinski ,  Charles Martin ,  Reinhard Neumann ,  Christina Trautmann ,  Toimil Molares

IPC: C25D1/00

CPC classification number: G01N33/48721 ,  B01D61/425 ,  B01D67/0032 ,  B01D67/0088 ,  B01D69/02 ,  B01D71/38 ,  B01D71/50 ,  B01D71/64 ,  B01D2323/34 ,  B01D2325/021 ,  B01D2325/26

Abstract: The present invention relates to an apparatus having a nanodevice (1) for controlling the flow of charged particles in an electrolyte. Such apparatus comprises an electrolytic bath container (2) divided by a polymeric membrane foil (3) into a first (4) and a second compartment (5), wherein each compartment (4, 5) comprises an electrode (6, 7) connected to a voltage supply (8). Further the apparatus comprises at least one asymmetric pore (9) forming a via hole through said foil (3), wherein said pore (9) provides a narrow opening (10) of a diameter in the range of several nanometers down to about one nanometer on a front side (11) of said foil (3) and a wide opening (12) in the range of several ten nanometers up to several hundred nanometers on a back side (13) of said foil (3). Further, the apparatus comprises an electrically conductive layer (14) surrounding said narrow opening (10) on said front side (11) and a gate voltage supply (15) connected to said electrically conductive layer (14) on said front side (11) of said foil (3) controlling the flow of charged particles within said nanodevice (1) from said first compartment (4) to said second compartment (5) vice versa. The invention further relates to a method for producing such a nanodevice (1).

Abstract translation: 本发明涉及一种具有用于控制电解质中带电粒子的流动的纳米装置（1）的装置。 这种设备包括由聚合物膜片（3）分成第一（4）和第二隔室（5）的电解浴容器（2），其中每个隔室（4,5）包括连接的电极（6,7） 到电源（8）。 此外，该装置包括形成穿过所述箔（3）的通孔的至少一个不对称孔（9），其中所述孔（9）提供直径在几纳米至约一纳米范围内的直径的窄开口（10） 在所述箔（3）的前侧（11）和在所述箔（3）的背面（13）上的几十纳米至几百纳米范围内的宽开口（12）。 此外，该装置包括围绕所述前侧（11）上的所述窄开口（10）的导电层（14）和连接到所述前侧（11）上的所述导电层（14）的栅极电压源（15） 所述箔（3）控制所述纳米装置（1）内从所述第一隔室（4）到所述第二隔室（5）的带电粒子的流动反之亦然。 本发明还涉及一种用于制造这种纳米器件（1）的方法。

公开(公告)号：US06908552B2

公开(公告)日：2005-06-21

申请号：US10085523

申请日：2002-02-26

Applicant: Zuzanna Siwy ,  Dobri D. Dobrev ,  Reinhard Neumann ,  Christina Trautmann ,  Kai Voss

Inventor： Zuzanna Siwy ,  Dobri D. Dobrev ,  Reinhard Neumann ,  Christina Trautmann ,  Kai Voss

IPC: B01D67/00 ,  B01D69/02 ,  B01D71/64 ,  B01D39/00

CPC classification number: B01D71/64 ,  B01D69/02 ,  B01D2325/022

Abstract: The invention relates to a method of producing nanostructures in membranes, in which method a membrane consisting of a polymer material is irradiated with charged particles, especially ions, to produce particle tracks. The particle tracks in the membrane are etched using an etching liquid and the etching operation is stopped using a stop liquid, in such a manner that asymmetrical structures are formed. Polyimide is used as the membrane material.

Abstract translation: 本发明涉及一种在膜中生产纳米结构的方法，其中由聚合物材料组成的膜用带电粒子，特别是离子照射以产生粒子轨迹。 使用蚀刻液蚀刻膜中的颗粒轨迹，并且以形成非对称结构的方式使用停止液停止蚀刻操作。 聚酰亚胺用作膜材料。