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    Functionalized siloxy compound, silica reinforced rubber compositions thereof and tire with component comprised thereof
    2.
    发明授权
    Functionalized siloxy compound, silica reinforced rubber compositions thereof and tire with component comprised thereof 有权
    官能化甲硅烷氧基化合物，二氧化硅增强橡胶组合物和其组成的组分的轮胎

    公开(公告)号：US07368587B2

    公开(公告)日：2008-05-06

    申请号：US11117106

    申请日：2005-04-28

    Applicant: Martin Paul Cohen

    Inventor： Martin Paul Cohen

    IPC: C07F7/08

    CPC classification number: C08K5/549 ,  C08K3/36 ,  C08L21/00

    Abstract: The present invention relates to a functionalized siloxy compound which is useful in silica-filled rubber compositions and the processing of a sulfur curable rubber composition containing silica. Accordingly, the invention further relates to a rubber composition containing at least one diene-based elastomer, particulate synthetic amorphous silica (e.g. precipitated silica) and said functionalized siloxy compound as a coupling agent and to an article of manufacture (e.g. tire) containing a component comprised of such rubber composition.

    Abstract translation: 本发明涉及一种功能化的甲硅烷氧基化合物，其可用于二氧化硅填充的橡胶组合物和加工含有二氧化硅的硫可固化橡胶组合物。 因此，本发明还涉及含有至少一种二烯基弹性体，颗粒状合成无定形二氧化硅（例如沉淀二氧化硅）和所述官能化甲硅烷氧基化合物作为偶联剂的橡胶组合物和含有组分 由这种橡胶组合物组成。

    Tire with low hydrocarbon emission rubber combination of tread and sidewall components with compositional limitations
    3.
    发明授权
    Tire with low hydrocarbon emission rubber combination of tread and sidewall components with compositional limitations 有权
    轮胎与低碳氢化合物橡胶组合的胎面和侧壁组件具有组成限制

    公开(公告)号：US07214731B2

    公开(公告)日：2007-05-08

    申请号：US10778502

    申请日：2004-02-13

    Applicant: David John Zanzig ,  Martin Paul Cohen ,  Paul Harry Sandstrom

    Inventor： David John Zanzig ,  Martin Paul Cohen ,  Paul Harry Sandstrom

    IPC: B60C1/00

    CPC classification number: C08L23/283 ,  B60C1/0016 ,  B60C1/0025 ,  C08K3/013 ,  C08K9/06 ,  C08L9/00 ,  C08L21/00 ,  C08L23/16 ,  Y10T152/10 ,  C08L2666/06 ,  C08L2666/08

    Abstract: The invention relates to a tire of a structural combination of tire tread and sidewall components with compositional limitations containing minimal, if any, of in situ formed alcohol and methyl isobutyl ketone byproducts. The tread component rubber composition contains pre-hydrophobated silica reinforcement. The sidewall component contains low unsaturation EPDM or brominated copolymer of isobutylene and p-methylstyrene and may contain pre-hydrophobated silica reinforcement. The silica reinforcement for said tread and sidewall components is a pre-hydrophobated precipitated silica. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or a combination of an alkoxyorganomercaptosilane and a substituted alkylsilane or with a bis-3(trialkoxysilylalkyl) polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof. The alcohol byproduct therefrom is removed from the composite prior to its introduction into the rubber composition(s). In another aspect of the invention, the connecting sidewall rubber composition, and optionally the tread composition is free of N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine antidegradant (referred herein to as 6PPD) in order to prevent in situ formation of methyl isobutyl ketone byproduct from the reaction of 6PPD with atmospheric oxygen and/or ozone.

    Abstract translation: 本发明涉及轮胎胎面和侧壁部件的结构组合的轮胎，其组成限制包含原位形成的醇和甲基异丁基酮副产物的最小（如果有的话）。 胎面部件橡胶组合物含有预疏水化的二氧化硅增强物。 侧壁组分含有低不饱和度的EPDM或异丁烯和对甲基苯乙烯的溴化共聚物，并且可以含有预疏水化的二氧化硅增强物。 用于所述胎面和侧壁组分的二氧化硅增强剂是预疏水化沉淀二氧化硅。 将预疏水化的二氧化硅在与弹性体混合之前通过将沉淀二氧化硅的表面上所含的羟基（例如硅烷醇基）与烷氧基有机硅烷或烷氧基有机硅氧烷和取代的烷基硅烷的组合或与 在其多硫桥中含有平均2至4个连接硫原子的双-3（三烷氧基甲硅烷基烷基）多硫化物以形成其复合物。 在其引入橡胶组合物之前，将其醇副产物从复合材料中除去。 在本发明的另一方面，连接侧壁橡胶组合物和任选的胎面组合物不含N-（1,3-二甲基丁基）-N'-苯基对苯二胺抗降解剂（以下称为6PPD），以便 防止6PPD与大气氧和/或臭氧的反应原位形成甲基异丁基酮副产物。

    Dual phase rubber composition and tire with nanocomposite-containing sidewall thereof
    8.
    发明授权
    Dual phase rubber composition and tire with nanocomposite-containing sidewall thereof 失效
    双相橡胶组合物和具有纳米复合材料侧壁的轮胎

    公开(公告)号：US07473728B2

    公开(公告)日：2009-01-06

    申请号：US11014017

    申请日：2004-12-16

    Applicant: Junling Zhao ,  Michael Julian Crawford ,  Aaron Scott Puhala ,  Martin Paul Cohen

    Inventor： Junling Zhao ,  Michael Julian Crawford ,  Aaron Scott Puhala ,  Martin Paul Cohen

    IPC: C08K9/04

    CPC classification number: C08L7/00 ,  C08K3/346 ,  C08K3/36 ,  C08L23/16 ,  C08L23/22 ,  C08L23/283 ,  C08L2666/02 ,  C08L2666/08

    Abstract: This invention relates to a dual phase rubber composition and pneumatic tire with a rubber sidewall thereof, namely a dual phased non-black colored rubber composition composed of a first pre-formed elastomer phase comprised of butyl-type rubber and EPDM rubber containing a dispersion therein of reinforcing filler comprised of a particulate amorphous precipitated silica and a second pre-formed elastomer phase comprised of a nanocomposite of natural rubber containing a dispersion therein of exfoliated clay platelets. Said exfoliated clay platelets may be substantially oriented within the tire sidewall in a parallel direction to each and may also be substantially oriented in an annular direction about the axis of the tire. The tire sidewall rubber composition may contain at least one additional elastomer which may be included in either or both of said elastomer phases. Such tire sidewall rubber composition may contain a non-black colorant pigment, such as for example a white colored titanium dioxide pigment. The dual phased tire sidewall rubber composition is prepared by a phase mixing process comprised of pre-blending said butyl-type rubber and EPDM rubber together with said precipitated silica reinforcing filler to form a pre-mix thereof, and thereafter mixing therewith said nanocomposite as a pre-formed blend of natural rubber and exfoliated clay platelets.

    Abstract translation: 本发明涉及一种双相橡胶组合物和具有橡胶侧壁的充气轮胎，即双相非黑色橡胶组合物，其由包含丁基橡胶的第一预成型弹性体相和含有分散体的EPDM橡胶组成 的由无定形沉淀二氧化硅颗粒构成的增强填料和由纳米复合材料组成的第二预成形弹性体相，其中所述天然橡胶含有分散在其中的剥离粘土片晶。 所述剥离的粘土小片可以在轮胎侧壁内基本上在与每个平行的方向上定向并且也可以基本上围绕轮胎的轴线在环形方向上取向。 轮胎侧壁橡胶组合物可以含有至少一种另外的弹性体，其可以包括在所述弹性体相中的一个或两个中。 这种轮胎侧壁橡胶组合物可以含有非黑色着色剂颜料，例如白色二氧化钛颜料。 双相轮胎侧壁橡胶组合物通过相混合方法制备，该相混合方法包括将所述丁基橡胶和EPDM橡胶与所述沉淀二氧化硅增强填料一起预混合以形成其预混物，然后与所述纳米复合材料混合， 预先形成的天然橡胶和剥离粘土血小板的混合物。

    Tire with component comprised of rubber composition containing pre-hydrophobated silica aggregates
    9.
    发明授权
    Tire with component comprised of rubber composition containing pre-hydrophobated silica aggregates 有权
    轮胎与含有预疏水化二氧化硅骨料的橡胶组合物组成

    公开(公告)号：US06573324B1

    公开(公告)日：2003-06-03

    申请号：US09542571

    申请日：2000-04-04

    Applicant: Martin Paul Cohen ,  Richard Robinson Smith ,  Fredrick Lewis Magnus

    Inventor： Martin Paul Cohen ,  Richard Robinson Smith ,  Fredrick Lewis Magnus

    IPC: C08K334

    CPC classification number: B60C1/0016 ,  C08K9/06 ,  C08L21/00

    Abstract: The invention relates to a tire having at least one component comprised of a rubber composition which contains pre-hydrophobated precipitated silica aggregates. Such tire component may be, for example although not limited to, a tire tread, sidewalls and/or sidewall insert. Such pre-hydrophobated precipitated silica aggregates are contemplated as being prepared, for example, by treatment of a colloidal silica with a combination of both an organomercaptosilane and an alkylsilane.

    Abstract translation: 本发明涉及具有至少一种组分的轮胎，该组分由含有疏水化沉淀二氧化硅聚集体的橡胶组合物组成。 这种轮胎部件可以是例如但不限于轮胎胎面，侧壁和/或侧壁插入件。 考虑这样的预疏水化沉淀二氧化硅聚集体，例如通过用有机硅烷和烷基硅烷的组合处理胶体二氧化硅来制备。

    Silica-filled diene-based rubbers containing tin organoacid salt compounds
    10.
    发明授权
    Silica-filled diene-based rubbers containing tin organoacid salt compounds 失效
    含有锡有机酸盐化合物的填充二氧化硅的二氧化硅橡胶

    公开(公告)号：US06177495B1

    公开(公告)日：2001-01-23

    申请号：US09256552

    申请日：1999-02-24

    Applicant: Martin Paul Cohen

    Inventor： Martin Paul Cohen

    IPC: C08L524

    CPC classification number: C08K5/548 ,  C08K5/57 ,  C08L21/00

    Abstract: The present invention relates to a composition and a method of processing a composition containing from 0.1 to 10 phr of a tin organoacid salt selected from the group consisting of compounds of the formula  where R3 and R4 are independently selected from the group consisting of alkyls having from 1 to 20 carbon atoms, alkenyls having from 1 to 20 carbon atoms and aryls and alkaryls having from 6 to 20 carbon atoms.

    Abstract translation: 本发明涉及组合物和加工方法，该组合物含有0.1至10phr的选自下式的化合物的锡有机酸盐，其中R 3和R 4独立地选自具有1个 至20个碳原子，具有1至20个碳原子的烯基和具有6至20个碳原子的芳基和烷芳基。

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