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    Tire with circumferential rubber tread having a lateral outboard control element
    2.
    发明授权
    Tire with circumferential rubber tread having a lateral outboard control element 有权
    具有周向橡胶胎面的轮胎具有侧向外侧控制元件

    公开(公告)号：US07789117B2

    公开(公告)日：2010-09-07

    申请号：US11651133

    申请日：2007-01-09

    Applicant: Aaron Scott Puhala ,  Rachel Rebekah Barnette ,  David Charles Poling ,  Eric John Marazzi ,  Kuo-Chih Hua ,  Shingo Futamura

    Inventor： Aaron Scott Puhala ,  Rachel Rebekah Barnette ,  David Charles Poling ,  Eric John Marazzi ,  Kuo-Chih Hua ,  Shingo Futamura

    IPC: B60C1/00 ,  B60C11/00

    CPC classification number: B60C1/0016 ,  B60C11/005 ,  B60C11/0058 ,  B60C11/0066 ,  B60C11/14 ,  B60C2011/0025 ,  C08L9/00 ,  C08L9/06 ,  C08L19/006 ,  C08L2666/02

    Abstract: The invention relates to a tire having a circumferential tread of a cap/base configuration composed of an outer tread rubber cap layer with a running surface of the tread and an underlying tread rubber base layer, wherein said tread cap layer is composed of two longitudinal adjacent zones, namely a primary tread cap zone and a minor lateral outboard control element (zone). The primary tread cap zone and the lateral outboard tread cap element provide a significant gradation of cold dynamic storage moduli (G′) at −25° C. and hot tan delta values at 100° C., yet similar warm dynamic storage moduli (G′) at 60° C. The primary tread cap zone and lateral outboard control tread cap element are load bearing in the sense of extending from the running surface of the tread radially inward to the unitary (non-zoned) tread base rubber layer. The zoned rubber tread cap layer and unitary rubber tread base layer are an integral tread composite in a sense of being co-extruded. In one aspect of the invention, the primary tread cap zone rubber composition is silica-rich and the lateral, outboard element rubber composition is carbon black-rich and which furthermore provide a gradation of filler reinforcement content; provide a gradation of silica to carbon black ratio and provide a gradation of cis 1,4-polybutadiene rubber content.

    Abstract translation: 本发明涉及一种轮胎，其具有由具有胎面的行进表面的外胎面橡胶帽层和下面的胎面橡胶基层组成的帽/底座构造的圆周胎面，其中所述胎冠盖层由两个纵向相邻 区域，即主胎面区域和小侧向外侧控制元件（区域）。 主要胎冠区域和侧向外侧胎面花纹块元件在-25℃下提供了显着的冷动态储存模量（G'）和100℃下的热tanδ值，而类似的热动态储存模量（G '）在60℃。主胎面区域和侧向外侧控制踏板元件是从胎面的行进表面径向向内延伸到整体（未分区的）胎面基底橡胶层的意义上的负载轴承。 划分的橡胶胎冠层和整体橡胶胎面基层是共挤出的整体胎面复合材料。 在本发明的一个方面，一次胎面胎面橡胶组合物是二氧化硅富集的，并且外侧的外侧元件橡胶组合物是富含炭黑的，并且还提供填料增强含量的等级。 提供二氧化硅与炭黑的比例，并提供顺式1,4-聚丁二烯橡胶含量的等级。

    Pneumatic tire having built-In sealant layer and preparation thereof
    4.
    发明申请
    Pneumatic tire having built-In sealant layer and preparation thereof 审中-公开
    具有内置密封剂层的气动轮胎及其制备方法

    公开(公告)号：US20090084482A1

    公开(公告)日：2009-04-02

    申请号：US11863994

    申请日：2007-09-28

    Applicant: Ramendra Nath Majumdar ,  Aaron Scott Puhala

    Inventor： Ramendra Nath Majumdar ,  Aaron Scott Puhala

    IPC: B60C19/12 ,  B29D30/06

    CPC classification number: B60C19/122 ,  B29C73/22 ,  B29D30/0061 ,  B29D30/0685 ,  B29D30/16 ,  B29D30/30 ,  B29D2030/069 ,  B29D2030/0695 ,  B29L2030/00 ,  B60C5/14 ,  B60C19/12 ,  Y10T152/10684

    Abstract: A pneumatic tire is provided which includes an outer circumferential rubber tread and a supporting carcass. A rubber inner liner is disposed inwardly from the supporting carcass. A built-in sealant layer is situated adjacent to an innermost removable barrier layer and disposed inwardly from the rubber inner liner. The built-in sealant layer provides self-sealing properties to the pneumatic tire. The pneumatic tire, with its innermost removable barrier layer, keeps the sealant layer from sticking to a tire-building apparatus during tire assembly and, after curing of the assembled tire, is eventually removed to permit gas from the built-in sealant layer to become part of the tire's inflation air to prevent or reduce instances of inner liner blister formation.

    Abstract translation: 提供一种充气轮胎，其包括外周橡胶胎面和支撑胎体。 橡胶内衬从支撑胎体向内设置。 内置的密封剂层位于最内层的可移除阻挡层附近并且从橡胶内衬层向内设置。 内置的密封剂层为充气轮胎提供自密封性能。 具有最内层可拆卸阻挡层的充气轮胎在轮胎组装期间使密封剂层不会粘附到轮胎建造装置上，并且在组装的轮胎固化之后，最终被去除以允许来自内置密封剂层的气体成为 一部分轮胎的充气空气，以防止或减少内衬气泡形成的情况。

    ELASTOMERS CONTAINING SURFACE METALATED SILICEOUS FILLERS
    5.
    发明申请
    ELASTOMERS CONTAINING SURFACE METALATED SILICEOUS FILLERS 失效
    包含表面金属化硅胶填料的弹性体

    公开(公告)号：US20080295936A1

    公开(公告)日：2008-12-04

    申请号：US12098506

    申请日：2008-04-07

    Applicant: Frank James Feher ,  Bruce Raymond Hahn ,  Aaron Scott Puhala

    Inventor： Frank James Feher ,  Bruce Raymond Hahn ,  Aaron Scott Puhala

    IPC: B60C11/00 ,  C08K5/5415

    CPC classification number: C08K5/548 ,  C08K9/02 ,  C08K9/12 ,  Y02T10/862 ,  C08L21/00

    Abstract: This invention is based upon the concept of modifying the surface of silica with a metal, such as titanium or zirconium, which will catalyze silanol condensation reactions on the surface of the silica. In other words, modifying the surface of silica with titanium or zirconium provides a catalyst for the silanol condensation reaction between the silica surface and silane coupling agents used in silica filled compounds. The utilization of such metalated silica as a filler in rubber compositions results in improved polymer filler interaction and in turn improved physical properties. For instance, such surface metalated siliceous fillers can be used in tire tread compounds to attain improved rolling resistance and treadwear without compromising traction characteristics. The present invention more specifically discloses an elastomeric composition which is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler. The subject invention further reveals a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler.

    Abstract translation: 本发明是基于用二氧化硅表面上的硅烷醇缩合反应的金属如钛或锆改性二氧化硅表面的概念。 换句话说，用钛或锆改性二氧化硅表面提供二氧化硅表面和二氧化硅填充的化合物中使用的硅烷偶联剂之间的硅烷醇缩合反应的催化剂。 在橡胶组合物中使用这种金属化二氧化硅作为填料导致聚合物填料相互作用改善，从而改善了物理性能。 例如，这种表面金属化的硅质填料可用于轮胎胎面胶料中以获得改善的滚动阻力和胎面磨损，而不损害牵引特性。 本发明更具体地公开了一种弹性体组合物，其由（1）橡胶状聚合物，（2）二氧化硅偶联剂和（3）表面金属化硅质填料组成。 本发明进一步揭示了一种轮胎，其由具有外圆周胎面的大致环形胎体，两个间隔开的胎圈，从胎圈到胎圈延伸的至少一个帘布层和从所述胎面径向延伸并将所述胎面连接到所述胎圈的轮胎，其中 所述胎面适于与地面接触，并且其中所述胎面由（1）橡胶状聚合物，（2）二氧化硅偶联剂和（3）表面金属化硅质填料组成。

    Pneumatic tire having built-in sealant layer and preparation thereof
    7.
    发明授权
    Pneumatic tire having built-in sealant layer and preparation thereof 有权
    具有内置密封剂层的气动轮胎及其制备方法

    公开(公告)号：US08617333B2

    公开(公告)日：2013-12-31

    申请号：US11858491

    申请日：2007-09-20

    Applicant: Ramendra Nath Majumdar ,  Aaron Scott Puhala

    Inventor： Ramendra Nath Majumdar ,  Aaron Scott Puhala

    IPC: B60C19/12 ,  B29C73/22

    CPC classification number: B29C73/163 ,  B29C73/20 ,  B29D30/0685 ,  B29D2030/069 ,  B29D2030/0691 ,  B29D2030/0695 ,  B29L2030/00 ,  B60C19/12

    Abstract: In one embodiment, a pneumatic tire having a built-in sealant layer, before cure, includes an unvulcanized pneumatic tire assembly having an outer circumferential rubber tread and a supporting carcass. A precursor sealant layer is situated between the supporting carcass and an innermost rubber inner liner. The precursor sealant layer includes a non-flowing polyurethane composition that is neither gel-like nor tacky and is self-supporting. The precursor sealant layer, during curing of the unvulcanized pneumatic tire assembly, thermally degrades so as to provide a gel-like and tacky, self-healing polyurethane composition which defines the built-in sealant layer. The resulting tire, with its innermost polyurethane composition, allows for elimination or reduction in blister formation by reducing or elimination the amount of gases typically given off by organoperoxide-butyl based sealant layers, such as when the tire is at its running temperature. Consequently, the thickness of the inner liner may be reduced.

    Abstract translation: 在一个实施例中，具有内置密封剂层的充气轮胎在固化之前包括具有外周橡胶胎面和支撑胎体的未硫化充气轮胎组件。 前体密封剂层位于支撑胎体和最内侧的橡胶内衬之间。 前体密封剂层包括非流动性聚氨酯组合物，其既不凝胶也不发粘并且是自支撑的。 前体密封剂层在未硫化充气轮胎组件的固化期间热降解，以提供限定内置密封剂层的凝胶状和粘性的自愈合聚氨酯组合物。 所得到的具有其最内层聚氨酯组合物的轮胎允许通过减少或消除通常由有机过氧化物 - 丁基基密封剂层（例如当轮胎处于其运行温度）时排出的气体量来消除或减少气泡形成。 因此，可以减小内衬的厚度。

    Elastomers containing surface metalated siliceous filler
    8.
    发明授权
    Elastomers containing surface metalated siliceous filler 失效
    含有表面金属化硅质填料的弹性体

    公开(公告)号：US08329805B2

    公开(公告)日：2012-12-11

    申请号：US13081861

    申请日：2011-04-07

    Applicant: Frank James Feher ,  Bruce Raymond Hahn ,  Aaron Scott Puhala

    Inventor： Frank James Feher ,  Bruce Raymond Hahn ,  Aaron Scott Puhala

    IPC: C08K3/34 ,  C08F8/42

    CPC classification number: C08K5/548 ,  C08K9/02 ,  C08K9/12 ,  Y02T10/862 ,  C08L21/00

    Abstract: This invention is based upon the concept of modifying the surface of silica with a metal, such as titanium or zirconium, which will catalyze silanol condensation reactions on the surface of the silica. The utilization of such metalated silica as a filler in rubber compositions results in improved polymer filler interaction and in turn improved physical properties. For instance, such surface metalated siliceous fillers can be used in tire tread compounds to attain improved rolling resistance and treadwear without compromising traction characteristics. The present invention more specifically discloses a tire having a tread comprising (1) a rubbery polymer, (2) a silica coupling agent, and (3) a surface metalated siliceous filler.

    Abstract translation: 本发明是基于用二氧化硅表面上的硅烷醇缩合反应的金属如钛或锆改性二氧化硅表面的概念。 在橡胶组合物中使用这种金属化二氧化硅作为填料导致聚合物填料相互作用改善，从而改善了物理性能。 例如，这种表面金属化的硅质填料可用于轮胎胎面胶料中以获得改善的滚动阻力和胎面磨损，而不损害牵引特性。 本发明更具体地公开了一种具有胎面的轮胎，其包含（1）橡胶状聚合物，（2）二氧化硅偶联剂，和（3）表面金属化硅质填料。

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