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    Continuously operable method for producing carbonyl compounds by means of a catalyst containing a nitroxyl radical
    1.
    发明授权
    Continuously operable method for producing carbonyl compounds by means of a catalyst containing a nitroxyl radical 有权
    通过含有硝酰自由基的催化剂生产羰基化合物的连续可操作的方法

    公开(公告)号：US08981159B2

    公开(公告)日：2015-03-17

    申请号：US14110450

    申请日：2011-12-06

    申请人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    发明人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    IPC分类号： C07C45/59 ,  C07D493/04

    CPC分类号： C07C45/59 ,  C07D493/04

    摘要： The invention relates to a method for the oxidation of a primary or secondary alcohol, preferably to form an aldehyde or ketone, comprising the following steps: a) providing a catalyst composition comprising at least one compound containing a nitroxyl radical, at least one NO source, at least one carbon or mineral acid or an anhydride of a carbon or mineral acid; b) producing a reaction mixture by adding at least one primary or secondary alcohol and a gas comprising oxygen and optionally one or more than one solvent to the catalyst composition from step a) or step e); c) incubating the reaction mixture from step b) at a temperature of between 0 and 100° C. or at the boiling point of the solvent; d) simultaneously with or subsequent to step c): crystallizing the reaction product; and e) recovering the catalyst composition by removing the crystallized reaction product from the reaction mixture obtained in step d).

    摘要翻译： 本发明涉及氧化伯醇或仲醇，优选形成醛或酮的方法，包括以下步骤：a）提供包含至少一种含有硝酰基的化合物的催化剂组合物，至少一种NO源 ，至少一种碳或无机酸或碳或无机酸的酸酐; b）通过从步骤a）或步骤e）向催化剂组合物中加入至少一种伯醇或仲醇和包含氧气和任选的一种或多种溶剂的气体产生反应混合物; c）在0-100℃的温度或溶剂的沸点下温育来自步骤b）的反应混合物; d）与步骤c）同时或之后步骤：使反应产物结晶; 和e）通过从步骤d）中获得的反应混合物中除去结晶的反应产物来回收催化剂组合物。

    METHODS AND SYSTEMS FOR AUTOMATIC COLORING OF DIGITAL IMAGES
    2.
    发明申请
    METHODS AND SYSTEMS FOR AUTOMATIC COLORING OF DIGITAL IMAGES 有权
    数字图像自动着色的方法与系统

    公开(公告)号：US20120063675A1

    公开(公告)日：2012-03-15

    申请号：US13206427

    申请日：2011-08-09

    申请人： Leslie Dittert ,  James Perry ,  Steven Wiener ,  Michael Volland

    发明人： Leslie Dittert ,  James Perry ,  Steven Wiener ,  Michael Volland

    IPC分类号： G06K9/00

    CPC分类号： G06T11/40

    摘要： Methods and systems for coloring media are described. A first sequence of images at a first resolution is received, wherein the first sequence of images includes images with color information. A second sequence of images is received. Optionally, image registration is performed for a plurality of images in the first sequence with respect to the second sequence and/or for a plurality of images in the second sequence with respect to the first sequence. A color analysis is performed using (optionally aligned) images from the first sequence of images and the second sequence of images, and the results are used to color the second sequence of images.

    摘要翻译： 描述了着色介质的方法和系统。 接收第一分辨率的第一图像序列，其中第一图像序列包括具有颜色信息的图像。 接收第二个图像序列。 可选地，对于关于第二序列的第一序列中的多个图像和/或针对第一序列的第二序列中的多个图像执行图像配准。 使用来自第一图像序列和第二图像序列的（可选地对准的）图像执行颜色分析，并且使用结果来对第二图像序列进行着色。

    Method for Producing a Beta-1,3-Glucan With Improved Characteristics
    4.
    发明申请
    Method for Producing a Beta-1,3-Glucan With Improved Characteristics 审中-公开
    生产具有改进特性的β-1,3-葡聚糖的方法

    公开(公告)号：US20090221806A1

    公开(公告)日：2009-09-03

    申请号：US10544820

    申请日：2004-03-04

    申请人： Werner Frohnwieser ,  Michael Volland ,  Evi Wittmann ,  Fabienne Skorupinsui ,  Jean Jacques Lebehot ,  Yves Lemoigne ,  Thomas Lötzbeyer

    发明人： Werner Frohnwieser ,  Michael Volland ,  Evi Wittmann ,  Fabienne Skorupinsui ,  Jean Jacques Lebehot ,  Yves Lemoigne ,  Thomas Lötzbeyer

    IPC分类号： C07G3/00 ,  C12P19/44

    CPC分类号： C12P19/04 ,  C08B37/0024 ,  C12P19/14

    摘要： In this process for preparing a β-1,3-glucan, the glucan-containing matrix is treated with a protein having β(1,3)-glucanase activity, wherein the concentration of the glucanase amounts from 0.001 to 3.0% by weight. The glucan-containing matrix can be a fermentation broth, a culture medium or a suspension, where appropriate containing unsolved solids, cell constituents and/or cell fragments, or else a mycelium, a hydrocolloid or a powder preparation having a solvent proportion of from 20 to 99.9% by weight. The duration of the enzymatic treatment should be between 15 minutes and 24 hours and the treatment should be carried out continuously. The invention also envisages the glucan-containing matrix being filtered or centrifuged, after it has been treated enzymatically, and the glucan finally being separated off. A β-1,3-glucan which has been prepared in this way and which exhibits, for example, improved solubility in cold water, reduced proportions of insoluble constituents, an increased viscosity or improved filterability, is also claimed. A solid formulation and the use of these glucans for cosmetic applications, foodstuffs or oil production are also coclaimed.

    摘要翻译： 在制备β-1,3-葡聚糖的该方法中，含有葡聚糖的基质用具有β（1,3） - 葡聚糖酶活性的蛋白质处理，其中葡聚糖酶的浓度为0.001至3.0重量％。 含有葡聚糖的基质可以是发酵液，培养基或悬浮液，其中适当地含有未溶解的固体，细胞成分和/或细胞碎片，或者是溶剂比例为20的菌丝体，水胶体或粉末制剂 至99.9重量％。 酶处理的持续时间应在15分钟至24小时之间，治疗应持续进行。 本发明还设想在经酶处理的葡聚糖的基质被过滤或离心后，最后分离出葡聚糖。 已经以这种方式制备并且例如显示出在冷水中的改善的溶解性，减少的不溶性组分的比例，增加的粘度或改进的过滤性的β-1,3-葡聚糖也被要求保护。 固体制剂和这些葡聚糖用于化妆品应用，食品或油品生产也被广泛使用。

    Medium containing water with increased viscosity, method for production and use thereof
    5.
    发明申请
    Medium containing water with increased viscosity, method for production and use thereof 审中-公开
    含有增加粘度的水的培养基，生产方法和使用方法

    公开(公告)号：US20060165802A1

    公开(公告)日：2006-07-27

    申请号：US10528710

    申请日：2003-09-23

    申请人： Thomas Lotzbeyer ,  Michael Volland ,  Eva Wittmann

    发明人： Thomas Lotzbeyer ,  Michael Volland ,  Eva Wittmann

    IPC分类号： C12P19/04 ,  A61K9/14

    CPC分类号： C12P19/04

    摘要： The invention concerns a water-containing medium with an increased viscosity containing a gellable polymer component with phenolic substituents modified with the aid of oxidases, characterized in that it was modified by a) a protein with polyphenol oxidase activity and/or b) an enzyme mixture containing hydrolases, oxidoreductases and peroxidases. The medium modified in this manner can be a gel that is preferably in a (partially) dried or (partially) rehydrated state, whose viscosity or gel strength can be selectively adjusted and which, even after a drying process and rehydration, again stably attains the original viscosity or gel strength. In addition the water-containing medium does not have any by-products that could have an adverse effect on quality of the gel or its sensory properties. In addition to the water-containing medium, a process is also proposed that can be used to produce the corresponding media with increased viscosity and which relies on the use of oxidoreductases, peroxidases, hydrolases and/or catalases. Food industry, cosmetics and pharmaceutical purposes are intended as areas of application for the proposed water-containing media.

    摘要翻译： 本发明涉及粘度增加的含水介质，其含有可借助于氧化酶修饰的酚取代基的可胶凝聚合物组分，其特征在于其被a）具有多酚氧化酶活性的蛋白质和/或b）酶混合物 含水解酶，氧化还原酶和过氧化物酶。 以这种方式改性的介质可以是优选处于（部分）干燥或（部分）再水合状态的凝胶，其可以选择性地调节其粘度或凝胶强度，并且即使在干燥过程和再水合后，再次稳定地达到 原始粘度或凝胶强度。 此外，含水介质不具有可能对凝胶质量或其感官特性产生不利影响的任何副产物。 除了含水介质之外，还提出了可用于生产具有增加的粘度并且依赖于使用氧化还原酶，水解酶和/或过氧化氢酶的相应介质的方法。 食品工业，化妆品和制药目的是拟议含水介质的应用领域。

    CONTINUOUSLY OPERABLE METHOD FOR PRODUCING CARBONYL COMPOUNDS BY MEANS OF A CATALYST CONTAINING A NITROXYL RADICAL
    6.
    发明申请
    CONTINUOUSLY OPERABLE METHOD FOR PRODUCING CARBONYL COMPOUNDS BY MEANS OF A CATALYST CONTAINING A NITROXYL RADICAL 有权
    通过含有硝基吡咯的催化剂生产碳化合物的连续可操作方法

    公开(公告)号：US20140039223A1

    公开(公告)日：2014-02-06

    申请号：US14110450

    申请日：2011-12-06

    申请人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    发明人： Florian Klasovsky ,  Thomas Haas ,  Thomas Tacke ,  Jan Christoph Pfeffer ,  Michael Rimbach ,  Michael Volland ,  Michiel Janssen ,  Roger Sheldon ,  Juergen Haberland

    IPC分类号： C07C45/59

    CPC分类号： C07C45/59 ,  C07D493/04

    摘要： The invention relates to a method for the oxidation of a primary or secondary alcohol, preferably to form an aldehyde or ketone, comprising the following steps: a) providing a catalyst composition comprising at least one compound containing a nitroxyl radical, at least one NO source, at least one carbon or mineral acid or an anhydride of a carbon or mineral acid; b) producing a reaction mixture by adding at least one primary or secondary alcohol and a gas comprising oxygen and optionally one or more than one solvent to the catalyst composition from step a) or step e); c) incubating the reaction mixture from step b) at a temperature of between 0 and 100° C. or at the boiling point of the solvent; d) simultaneously with or subsequent to step c): crystallizing the reaction product; and e) recovering the catalyst composition by removing the crystallized reaction product from the reaction mixture obtained in step d).

    摘要翻译： 本发明涉及氧化伯醇或仲醇，优选形成醛或酮的方法，包括以下步骤：a）提供包含至少一种含有硝酰基的化合物的催化剂组合物，至少一种NO源 ，至少一种碳或无机酸或碳或无机酸的酸酐; b）通过从步骤a）或步骤e）向催化剂组合物中加入至少一种伯醇或仲醇和包含氧气和任选的一种或多种溶剂的气体产生反应混合物; c）在0-100℃的温度或溶剂的沸点下温育来自步骤b）的反应混合物; d）与步骤c）同时或之后步骤：使反应产物结晶; 和e）通过从步骤d）中获得的反应混合物中除去结晶的反应产物来回收催化剂组合物。

    Method for the enzymatic production of emulsifiers containing mono- and diacylglycerides
    7.
    发明授权
    Method for the enzymatic production of emulsifiers containing mono- and diacylglycerides 有权
    用于酶促生产含有单和二酰基甘油酯的乳化剂的方法

    公开(公告)号：US08637278B2

    公开(公告)日：2014-01-28

    申请号：US10570613

    申请日：2004-09-02

    申请人： Michael Volland ,  Thomas Lötzbeyer ,  Volker Sieber ,  Eva Wittmann

    发明人： Michael Volland ,  Thomas Lötzbeyer ,  Volker Sieber ,  Eva Wittmann

    IPC分类号： C12P7/62

    CPC分类号： C12P7/00 ,  C12P7/6454

    摘要： The invention relates to a method for the enzymatic production of emulsifiers containing mono- and diacylglycerides. In a first step a), a mixture of a phospholipid component and a triacylglyceride component is prepared, then in step b) a quantity of an aqueous solution containing a (phospho)lipase is added to the mixture obtained, to produce a water content of the mixture of between 3 and 15 wt. %. In a subsequent step c), the mixture obtained in the previous step is reacted at a temperature ranging between 20° and 80° C. over a period of at least two hours and said mixture is then dried.

    摘要翻译： 本发明涉及一种用于酶促生产含有单和二酰基甘油酯的乳化剂的方法。 在第一步骤a）中，制备磷脂成分和三酰基甘油酯组分的混合物，然后在步骤b）中，向所得混合物中加入一定量的含有（磷酸）脂肪酶的水溶液，以产生 3至15重量份的混合物 ％。 在随后的步骤c）中，将上述步骤中获得的混合物在20℃至80℃的温度下反应至少2小时，然后将所述混合物干燥。

    Methods and systems for automatic coloring of digital images
    8.
    发明授权
    Methods and systems for automatic coloring of digital images 有权
    数字图像自动着色的方法和系统

    公开(公告)号：US08467629B2

    公开(公告)日：2013-06-18

    申请号：US13206427

    申请日：2011-08-09

    申请人： Leslie Dittert ,  James Perry ,  Steven Wiener ,  Michael Volland

    发明人： Leslie Dittert ,  James Perry ,  Steven Wiener ,  Michael Volland

    IPC分类号： G06K9/32 ,  G06K9/00

    CPC分类号： G06T11/40

    摘要： Methods and systems for coloring media are described. A first sequence of images at a first resolution is received, wherein the first sequence of images includes images with color information. A second sequence of images is received. Optionally, image registration is performed for a plurality of images in the first sequence with respect to the second sequence and/or for a plurality of images in the second sequence with respect to the first sequence. A color analysis is performed using (optionally aligned) images from the first sequence of images and the second sequence of images, and the results are used to color the second sequence of images.

    摘要翻译： 描述了着色介质的方法和系统。 接收第一分辨率的第一图像序列，其中第一图像序列包括具有颜色信息的图像。 接收第二个图像序列。 可选地，对于关于第二序列的第一序列中的多个图像和/或针对第一序列的第二序列中的多个图像执行图像配准。 使用来自第一图像序列和第二图像序列的（可选地对准的）图像执行颜色分析，并且使用结果来对第二图像序列进行着色。