公开(公告)号：US20120292661A1

公开(公告)日：2012-11-22

申请号：US13566342

申请日：2012-08-03

Applicant: Norihide SUGIYAMA ,  Keigo Matsuura

Inventor： Norihide SUGIYAMA ,  Keigo Matsuura

IPC: C08F8/34 ,  C08L27/18 ,  H01L33/56 ,  C07C323/03

CPC classification number: C08F214/182 ,  C08F214/18 ,  C08F216/1408 ,  C08F216/1416 ,  C08K5/37 ,  G02B1/04 ,  C08L57/10 ,  C08L57/08

Abstract: To provide a fluorinated curable resin composition which is excellent in thermal stability and thermal adhesive property. A fluorinated curable resin composition comprising a fluoropolymer (P) having a polymerizable double bond and a thiol compound (S), wherein the fluoropolymer (P) is a copolymer having repeating units derived from a fluoromonoene (a) and a fluorodiene (b) having a residual unsaturated side chain, and the content of the thiol compound (S) is from 0.01 to 1 part by mass per 100 parts by mass of the fluoropolymer (P).

Abstract translation: 提供热稳定性和热粘合性优异的氟化固化性树脂组合物。 包含具有可聚合双键的含氟聚合物（P）和硫醇化合物（S）的氟化可固化树脂组合物，其中所述含氟聚合物（P）是具有衍生自氟代烯烃（a）和氟二烯（b）的重复单元的共聚物， 剩余不饱和侧链，并且硫醇化合物（S）的含量相对于含氟聚合物（P）为100质量份为0.01〜1质量份。

公开(公告)号：US07847028B2

公开(公告)日：2010-12-07

申请号：US12326932

申请日：2008-12-03

Applicant: Norihide Sugiyama ,  Masahiro Ohkura

Inventor： Norihide Sugiyama ,  Masahiro Ohkura

IPC: C08F8/00 ,  C08L27/12 ,  B32B27/00

CPC classification number: C08F259/08 ,  C08F214/18 ,  C08F230/08 ,  C08F279/00 ,  C08K5/02 ,  C08L51/003 ,  H01L33/56 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2924/181 ,  Y10T428/3154 ,  Y10T428/31544 ,  C08L27/12 ,  C08L2666/02 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: The present invention provides a curable composition which can yield a fluorinated cured product excellent in transparency, light resistance, heat resistance, and mechanical strength, and minimally damaged by stress concentration. The invention relates to a curable composition comprising a perfluoro polymer (a) containing a unit derived from a perfluorodiene having two polymerizable carbon-carbon double bonds, wherein two carbon atoms in one carbon-carbon double bond form the main chain, and the other carbon-carbon double bond forms a side chain; a perfluorocyclic monoene (b) having at least 8 carbon atoms, which has an alicyclic structure made of carbon atoms and optionally containing an oxygen atom, and one polymerizable carbon-carbon double bond, wherein at least one of two carbon atoms forming the carbon-carbon double bond is a carbon atom constituting the alicyclic structure; and a polymerization initiator (i).

Abstract translation: 本发明提供一种能够得到透明性，耐光性，耐热性和机械强度优异且最小程度受应力集中损伤的氟化固化物的固化性组合物。 本发明涉及一种包含全氟聚合物（a）的可固化组合物，该全氟聚合物（a）含有源自具有两个可聚合碳 - 碳双键的全氟二烯的单元，其中一个碳 - 碳双键中的两个碳原子形成主链，另一碳 碳双键形成侧链; 具有至少8个碳原子的全氟环单烯（b），其具有由碳原子和任选含有氧原子的脂环族结构和一个可聚合碳 - 碳双键，其中形成碳 - 碳双键的两个碳原子中的至少一个， 碳双键是构成脂环结构的碳原子; 和聚合引发剂（i）。

公开(公告)号：US06750294B2

公开(公告)日：2004-06-15

申请号：US09877056

申请日：2001-06-11

Applicant: Norihide Sugiyama ,  Tsuyoshi Onishi

Inventor： Norihide Sugiyama ,  Tsuyoshi Onishi

IPC: C08L2712

CPC classification number: G02B6/02038 ,  G02B1/046 ,  G02B6/03633

Abstract: A plastic optical fiber which is a graded index optical fiber having a concentric inner/outer at least two layer structure, wherein the inner layer has a graded index structure made of a non-crystalline fluoropolymer (a) having substantially no C—H bond, and the outer layer has a refractive index lower than the refractive index of the outermost portion of the inner layer and is made of a fluoropolymer material (c) selected from the following 1) and 2): 1) a fluoropolymer (d) containing the same polymerized units as the polymerized units in the fluoropolymer (a), and 2) a mixture (f) of a fluoropolymer (a) with another fluoropolymer (e).

Abstract translation: 一种塑料光纤，其是具有同心的内/外至少两层结构的渐变折射率光纤，其中内层具有由基本上没有CH键的非结晶含氟聚合物（a）制成的渐变折射率结构，并且 外层的折射率低于内层的最外部分的折射率，并由选自以下1）和2）中的含氟聚合物材料（c）制成：1）含有相同聚合物的含氟聚合物（d） 单元作为氟聚合物（a）中的聚合单元，和2）含氟聚合物（a）与另一种含氟聚合物（e）的混合物（f）。

公开(公告)号：US06500910B1

公开(公告)日：2002-12-31

申请号：US09621359

申请日：2000-07-21

Applicant: Yasuhiro Koike ,  Norihide Sugiyama

Inventor： Yasuhiro Koike ,  Norihide Sugiyama

IPC: C08F11612

CPC classification number: G02B6/02038 ,  C08K5/0091 ,  G02B1/045 ,  G02B1/046 ,  G02B6/02033 ,  C08L27/12

Abstract: A refractive index distribution type light transmitting device comprising a non-crystalline polymer (a) and a metal chelate compound (b) having a difference in refractive index of at least 0.001 as compared with the non-crystalline polymer (a) and having a molecular weight of at least 400, wherein the metal chelate compound (b) is distributed in the non-crystalline polymer (a) with a concentration gradient in a specific direction.

Abstract translation: 折射率分布型透光装置，其包含与非结晶性聚合物（a）相比，折射率差为0.001以上的非结晶性聚合物（a）和金属螯合物（b），并且具有分子 重量至少为400，其中金属螯合物（b）以特定方向的浓度梯度分布在非结晶聚合物（a）中。

公开(公告)号：US06448452B2

公开(公告)日：2002-09-10

申请号：US09841592

申请日：2001-04-25

Applicant: Kimiaki Kashiwagi ,  Hidenobu Murofushi ,  Norihide Sugiyama ,  Masakuni Sato ,  Atsushi Watakabe

Inventor： Kimiaki Kashiwagi ,  Hidenobu Murofushi ,  Norihide Sugiyama ,  Masakuni Sato ,  Atsushi Watakabe

IPC: C07C4100

CPC classification number: C07C43/123 ,  C07C43/17 ,  C08F16/32 ,  C08F36/18 ,  C08F36/20

Abstract: A polymer which contains monomer units formed by polymerization of a fluorine-containing diene of formula 1: CF2═CF(CF2)nCXYOCF═CF2 Wherein X and Y are hydrogen and chlorine, hydrogen and-bromine, hydrogen and iodine, fluorine and chlorine, fluorine and bromine, fluorine and iodine, chlorine and bromine, chlorine and iodine, bromine and bromine, bromine and iodine, or iodine and iodine and n is an integer from 1 to 3.

Abstract translation: 含有由式1的含氟二烯聚合形成的单体单元的聚合物：其中X和Y分别是氢和氯，氢和溴，氢和碘，氟和氯，氟和溴，氟和碘，氯 和溴，氯和碘，溴和溴，溴和碘，或碘和碘，n是1至3的整数。

公开(公告)号：US06221987B1

公开(公告)日：2001-04-24

申请号：US09291050

申请日：1999-04-14

Applicant: Norihide Sugiyama

Inventor： Norihide Sugiyama

IPC: C08F434

CPC classification number: C08F214/184 ,  C08F14/18 ,  C08F2/02

Abstract: A method for producing a fluorine-containing polymer, which comprises subjecting the following fluorine-containing monomer (a), (b), (c) or (d) to bulk polymerization by means of a polymerization initiator comprising a fluorine-containing organic peroxide having a 10 hour half value temperature of from 30 to 130° C., to obtain a fluorine-containing polymer having a fluorine-containing alicyclic structure in its main chain: (a) a fluorine-containing monomer having a fluorine-containing alicyclic structure, (b) a fluorine-containing monomer having at least two polymerizable double bonds, (c) the fluorine-containing monomer (a) and the fluorine-containing monomer (b), (d) at least one fluorine-containing monomer selected from the fluorine-containing monomers (a) and (b), and another fluorine-containing monomer other than the fluorine-containing monomers (a) and (b).

Abstract translation: 一种含氟聚合物的制造方法，其特征在于，含有下述含氟单体（a），（b），（c）或（d））通过包含含氟有机过氧化物 10小时半值温度为30〜130℃，得到主链具有含氟脂环结构的含氟聚合物：（a）具有含氟脂环结构的含氟单体 ，（b）具有至少两个可聚合双键的含氟单体，（c）含氟单体（a）和含氟单体（b），（d）至少一种选自以下的含氟单体 含氟单体（a）和（b），以及除含氟单体（a）和（b）以外的其它含氟单体。

公开(公告)号：USRE37022E1

公开(公告)日：2001-01-16

申请号：US09037887

申请日：1998-03-10

Applicant: Norihide Sugiyama ,  Atsushi Watakabe ,  Shunsuke Yokotsuka ,  Atsuo Hiroi ,  Masaki Naritomi ,  Naoko Shirota ,  Ko Aosaki ,  Masaru Nakamura

Inventor： Norihide Sugiyama ,  Atsushi Watakabe ,  Shunsuke Yokotsuka ,  Atsuo Hiroi ,  Masaki Naritomi ,  Naoko Shirota ,  Ko Aosaki ,  Masaru Nakamura

IPC: C08J500

CPC classification number: C08J3/091 ,  C08J3/093 ,  C08J2327/12 ,  C08K5/0008 ,  H05K3/4676 ,  Y10T428/3154 ,  Y10T428/31544 ,  C08L27/12

Abstract: A fluorine-containing polymer composition comprising a polymer having a functional group and a fluorine-containing aliphatic cyclic structure dissolved in a solvent mixture of an aprotic fluorine-containing solvent and a protic fluorine-containing solvent.

Abstract translation: 一种包含溶解在非质子含氟溶剂和质子性含氟溶剂的溶剂混合物中的具有官能团和含氟脂肪族环状结构的聚合物的含氟聚合物组合物。

公开(公告)号：US5916971A

公开(公告)日：1999-06-29

申请号：US659365

申请日：1996-06-06

Applicant: Yasuhiro Koike ,  Hidenobu Murofushi ,  Norihide Sugiyama

Inventor： Yasuhiro Koike ,  Hidenobu Murofushi ,  Norihide Sugiyama

IPC: G02B1/04 ,  G02B6/028 ,  C08G65/48

CPC classification number: G02B6/02038 ,  G02B1/046

Abstract: A graded-refractive-index optical plastic material composed of an amorphous fluoropolymer (a) which has substantially no C--H bond and at least one material (b) which has substantially no C--H bond and differs from the fluoropolymer (a) in refractive index by at least 0.001, wherein the material (b) is distributed in the fluoropolymer (a) so as to have a concentration gradient in a specific direction, and the optical plastic material has a glass transition temperature which is substantially uniform throughout it.

Abstract translation: 由基本上没有CH键的无定形含氟聚合物（a）和至少一种基本上没有CH键的材料（b）组成的渐变折射率光学塑料材料，其折射率与氟聚合物（a）的不同在于 至少0.001，其中所述材料（b）分布在所述含氟聚合物（a）中以具有在特定方向上的浓度梯度，并且所述光学塑料材料具有在其中基本均匀的玻璃化转变温度。

公开(公告)号：US5760139A

公开(公告)日：1998-06-02

申请号：US659867

申请日：1996-06-07

Applicant: Yasuhiro Koike ,  Masaki Naritomi ,  Hidenobu Murofushi ,  Norihide Sugiyama

Inventor： Yasuhiro Koike ,  Masaki Naritomi ,  Hidenobu Murofushi ,  Norihide Sugiyama

IPC: B29C39/00 ,  B29C39/02 ,  B29D11/00 ,  G02B1/04 ,  C08L27/12

CPC classification number: G02B6/02038 ,  B29C39/006 ,  B29D11/00682 ,  G02B1/046 ,  B29C39/025 ,  B29C39/028 ,  B29K2995/0031 ,  G02B6/02033

Abstract: A graded-refractive-index optical plastic material composed of an amorphous fluoropolymer (a) which substantially has no C-H bond and at least one material (b) which differs from the fluoropolymer (a) in refractive index by at least 0.001, wherein the material (b) is distributed in the fluoropolymer (a) so as to have a concentration gradient in a specific direction.

Abstract translation: 由基本上没有CH键的无定形含氟聚合物（a）和折射率不同于氟聚合物（a）的至少一种材料（b）组成的渐变折射率光学塑料材料至少为0.001，其中材料 （b）分布在含氟聚合物（a）中以具有特定方向的浓度梯度。

公开(公告)号：US5502132A

公开(公告)日：1996-03-26

申请号：US194124

申请日：1994-02-09

Applicant: Norihide Sugiyama ,  Hidenobu Murohushi ,  Masaru Nakamura

Inventor： Norihide Sugiyama ,  Hidenobu Murohushi ,  Masaru Nakamura

IPC: C08F216/12 ,  C08F224/00 ,  C08F16/24

CPC classification number: C08F224/00 ,  C08F216/125

Abstract: A process for producing a perfluoro copolymer, which comprises subjecting a perfluoro monomer having a carbon-carbon double bond with a different polymerization ability at each terminal of the molecule and perfluoro-2,2-dimethyl-1,3-dioxol to radical copolymerization.

Abstract translation: 一种全氟共聚物的制造方法，其特征在于，使分子的各末端具有不同聚合能力的碳 - 碳双键的全氟单体和全氟-2,2-二甲基-1,3-间二氧杂环己烷进行自由基共聚。