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1.发明授权公开(公告)号：US09527037B2
公开(公告)日：2016-12-27
申请号：US13883099
申请日：2011-11-08
CPC分类号： B01D53/96 , B01D9/0013 , B01D9/0054 , B01D53/1425 , B01D53/1475 , B01D2009/0086 , B01D2251/104 , B01D2251/106 , B01D2251/306 , B01D2251/604 , B01D2251/606 , B01D2252/20484 , B01D2252/20494 , B01D2257/504 , C01B17/56 , Y02C10/06 , Y02P20/152
摘要： A method for processing an amine-based solvent contaminated by the introduction of sulfur oxides is provided. A potassium compound is introduced into a contaminated solvent, and the contaminated solvent is cooled so that a solubility of a potassium sulfate becomes less than a specified concentration of potassium sulfate. Further, an oxidizing agent is introduced into the contaminated solvent so that a potassium sulfite is oxidized to potassium sulfate. The potassium sulfate is filtered out, wherein a prepared solvent is formed. Further, a device for processing an amine-based, sulfur oxide-contaminated solvent is provided.
摘要翻译： 提供了通过引入硫氧化物而污染的胺类溶剂的加工方法。 将钾化合物引入污染的溶剂中，并将被污染的溶剂冷却，使得硫酸钾的溶解度变得小于规定浓度的硫酸钾。 此外，将氧化剂引入污染的溶剂中，使得亚硫酸钾被氧化成硫酸钾。 过滤出硫酸钾，其中形成制备的溶剂。 此外，提供了用于处理胺类，硫氧化物污染溶剂的装置。
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2.发明授权Absorbing agent, method for manufacturing an absorbing agent and use of an absorbent agent 有权吸收剂，吸收剂的制造方法和吸收剂的使用公开(公告)号：US09067170B2
公开(公告)日：2015-06-30
申请号：US13123757
申请日：2009-09-14
申请人： Ralph Joh , Rüdiger Schneider
发明人： Ralph Joh , Rüdiger Schneider
IPC分类号： B01D53/14
CPC分类号： B01D53/1475 , B01D53/1493 , B01D2252/20494 , B01D2257/504 , Y02A50/2342 , Y02C10/06
摘要： An absorbent agent is provided. The absorbent agent is particularly for separating carbon dioxide from the flue gas of a fossil-fired combustion device. The absorbent agent comprises a two-component mixture including a free amino acid and an amino acid salt, wherein the free amino acid exhibits a surplus compared to the amino acid salt based on the molar concentration. This creates variability in the PCBN value, which may be attained through different absorption and desorption process temperatures. A method for manufacturing the absorbent agent is also provided.
摘要翻译： 提供吸收剂。 吸收剂特别用于从化石燃烧装置的烟道气中分离二氧化碳。 吸收剂包括含有游离氨基酸和氨基酸盐的双组分混合物，其中与氨基酸盐相比，游离氨基酸与摩尔浓度相比表现出过剩。 这导致PCBN值的变化，这可以通过不同的吸收和解吸过程温度来实现。 还提供了制造吸收剂的方法。
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3.发明申请SOLVENT, PROCESS FOR PROVIDING AN ABSORPTION LIQUID, AND USE OF THE SOLVENT 审中-公开溶剂，提供吸收液体的方法和溶剂的使用公开(公告)号：US20140084208A1
公开(公告)日：2014-03-27
申请号：US13981392
申请日：2012-01-12
申请人： Björn Fischer , Ralph Joh , Rüdiger Schneider
发明人： Björn Fischer , Ralph Joh , Rüdiger Schneider
IPC分类号： B01D53/62
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , Y02C10/06
摘要： A solvent for selective absorption of CO2 from the flue gas from a combustion plant is provided. The solvent includes an aqueous solution of a secondary amine as an active scrubbing substance and an additive which inhibits the formation of nitrosamine, the additive including a primary amine. A process for providing an absorption liquid is also provided.
摘要翻译： 提供了用于从来自燃烧设备的烟道气中选择性吸收CO 2的溶剂。 溶剂包括作为活性洗涤物质的仲胺水溶液和抑制亚硝胺形成的添加剂，该添加剂包括伯胺。 还提供了一种提供吸收液体的方法。
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4.发明申请SOLVENT, PROCESS FOR PROVIDING AN ABSORPTION LIQUID, AND USE OF THE SOLVENT 审中-公开溶剂，提供吸收液体的方法和溶剂的使用公开(公告)号：US20130320259A1
公开(公告)日：2013-12-05
申请号：US13979701
申请日：2012-01-12
申请人： Björn Fischer , Ralph Joh , Rüdige Schneider
发明人： Björn Fischer , Ralph Joh , Rüdige Schneider
IPC分类号： B01D53/62
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , Y02C10/06
摘要： A solvent for selective absorption of CO2 from the flue gas from a combustion plant is provided. The solvent includes an aqueous solution of a secondary amine an active scrubbing substance and an additive, the additive including a salt of vitamin C or E. A process for providing an absorption liquid, and to the use of the solvent for selective absorption of CO2 from the flue gas from a combustion plant is also provided.
摘要翻译： 提供了用于从来自燃烧设备的烟道气中选择性吸收CO 2的溶剂。 溶剂包括仲胺的水溶液，活性洗涤物质和添加剂，该添加剂包括维生素C或E的盐。提供吸收液体的方法，以及使用该溶剂选择性吸收CO 2的方法 还提供来自燃烧设备的烟道气。
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5.发明申请PREPARATION OF AN AMINE BASED SOLVENT CONTAMINATED BY THE INTRODUCTION OF SULFUR OXIDES 有权由硫氧化物介绍污染的基于胺的溶剂的制备公开(公告)号：US20130214202A1
公开(公告)日：2013-08-22
申请号：US13883099
申请日：2011-11-08
IPC分类号： B01D53/96
CPC分类号： B01D53/96 , B01D9/0013 , B01D9/0054 , B01D53/1425 , B01D53/1475 , B01D2009/0086 , B01D2251/104 , B01D2251/106 , B01D2251/306 , B01D2251/604 , B01D2251/606 , B01D2252/20484 , B01D2252/20494 , B01D2257/504 , C01B17/56 , Y02C10/06 , Y02P20/152
摘要： A method for processing an amine-based solvent contaminated by the introduction of sulfur oxides is provided. A potassium compound is introduced into a contaminated solvent, and the contaminated solvent is cooled so that a solubility of a potassium sulfate becomes less than a specified concentration of potassium sulfate. Further, an oxidizing agent is introduced into the contaminated solvent so that a potassium sulfite is oxidized to potassium sulfate. The potassium sulfate is filtered out, wherein a prepared solvent is formed. Further, a device for processing an amine-based, sulfur oxide-contaminated solvent is provided.
摘要翻译： 提供了通过引入硫氧化物而污染的胺类溶剂的加工方法。 将钾化合物引入污染的溶剂中，并将被污染的溶剂冷却，使得硫酸钾的溶解度变得小于规定浓度的硫酸钾。 此外，将氧化剂引入污染的溶剂中，使得亚硫酸钾被氧化成硫酸钾。 过滤出硫酸钾，其中形成制备的溶剂。 此外，提供了用于处理胺类，硫氧化物污染溶剂的装置。
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6.发明申请公开(公告)号：US20120086218A1
公开(公告)日：2012-04-12
申请号：US13318902
申请日：2010-04-15
申请人： Ewa Bozek , Michael Fenz , Klaus Himmler , Ralph Joh , Jörg Lengert
发明人： Ewa Bozek , Michael Fenz , Klaus Himmler , Ralph Joh , Jörg Lengert
摘要： In a method for generating electrical energy by means of at least one low-temperature heat source (2), a VPT cyclic process (1, 10, 100) is carried out. Certain working substances are used to increase the efficiency of the VPT cyclic process.
摘要翻译： 在通过至少一个低温热源（2）产生电能的方法中，执行VPT循环过程（1,10,100）。 使用某些工作物质来提高VPT循环过程的效率。
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7.发明授权Method and device for treating a contaminated alkaline amino acid saline solution 有权用于处理污染的碱性氨基酸盐溶液的方法和装置公开(公告)号：US09327241B2
公开(公告)日：2016-05-03
申请号：US13808113
申请日：2011-06-08
申请人： Erwin Johannes Martinus Giling , Earl Lawrence Vincent Goetheer , Ralph Joh , Rüdiger Schneider , Johannes Van Der Meer , Dirk Verdoes
发明人： Erwin Johannes Martinus Giling , Earl Lawrence Vincent Goetheer , Ralph Joh , Rüdiger Schneider , Johannes Van Der Meer , Dirk Verdoes
CPC分类号： B01D53/96 , B01D53/62 , B01D2252/20494 , B01D2257/504 , Y02C10/04
摘要： A method for treating a contaminated alkaline amino acid salt solution is provided. First, carbon dioxide is introduced into the amino acid salt solution, with the result that carbonate or carbonate salts is or are precipitated, these being filtered off. The remaining filtrate is then cooled, amino acid or amino acid salts being crystallized out and likewise being filtered off. The amino acid or amino acid salt is then dissolved again, with the result that a treated amino acid salt solution is recovered.
摘要翻译： 提供了一种处理污染的碱性氨基酸盐溶液的方法。 首先，将二氧化碳引入氨基酸盐溶液中，结果碳酸盐或碳酸盐被沉淀，这些被滤出。 然后将剩余的滤液冷却，使氨基酸或氨基酸盐结晶出来并同样被滤出。 然后氨基酸或氨基酸盐再次溶解，结果是回收经处理的氨基酸盐溶液。
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8.发明申请METHOD AND DEVICE FOR EXTRACTING HIGHLY VOLATILE DEGRADATION PRODUCTS FROM THE ABSORBENT LOOP OF A CO2 SEPARATION PROCESS 审中-公开从二氧化碳分离过程的吸收环中提取高挥发性降解产物的方法和装置公开(公告)号：US20150083964A1
公开(公告)日：2015-03-26
申请号：US14236469
申请日：2012-08-01
申请人： Björn Fischer , Erwin Johannes Martinus Giling , Earl Lawrence Vincent Goetheer , Ralph Joh , Markus Kinzl , Diego Andres Kuettel , Rüdiger Schneider , Jan Harm Urbanus
发明人： Björn Fischer , Erwin Johannes Martinus Giling , Earl Lawrence Vincent Goetheer , Ralph Joh , Markus Kinzl , Diego Andres Kuettel , Rüdiger Schneider , Jan Harm Urbanus
IPC分类号： B01D53/96
CPC分类号： B01D53/96 , B01D53/1425 , B01D53/1475 , B01D2251/606 , B01D2251/70 , B01D2251/80 , B01D2252/204 , B01D2257/504 , B01D2258/0283 , C02F1/04 , C02F1/283 , C02F2103/18 , Y02C10/04 , Y02C10/06
摘要： Apparatus and process for removal of volatile degradation products from the absorbent circuit of a CO2 separation process are provided. The CO2 separation process may use the absorbent circuit in an absorption process and a desorption process. Condensate is withdrawn from a condensation process connected downstream of the desorption process, and purified to substantially free such condensate of degradation products. The purified condensate is recycled back to the absorbent circuit.
摘要翻译： 提供了用于从CO 2分离过程的吸收回路中除去挥发性降解产物的装置和方法。 CO 2分离过程可以在吸收过程和解吸过程中使用吸收剂回路。 从与解吸过程下游连接的冷凝过程中取出冷凝物，并纯化至基本上释放降解产物的这种缩合物。 净化的冷凝物再循环回吸收回路。
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9.发明申请METHOD AND DEVICE FOR TREATING A CONTAMINATED ALKALINE AMINO ACID SALINE SOLUTION 有权用于处理污染的碱性氨基酸酸性溶液的方法和装置公开(公告)号：US20150034867A1
公开(公告)日：2015-02-05
申请号：US13808113
申请日：2011-06-08
申请人： Erwin Johannes Martinus Giling , Earl Lawrence Vincent Goetheer , Ralph Joh , Rüdiger Schneider , Johannes Van der Meer , Dirk Verdoes
发明人： Erwin Johannes Martinus Giling , Earl Lawrence Vincent Goetheer , Ralph Joh , Rüdiger Schneider , Johannes Van der Meer , Dirk Verdoes
CPC分类号： B01D53/96 , B01D53/62 , B01D2252/20494 , B01D2257/504 , Y02C10/04
摘要： A method for treating a contaminated alkaline amino acid salt solution is provided. First, carbon dioxide is introduced into the amino acid salt solution, with the result that carbonate or carbonate salts is or are precipitated, these being filtered off. The remaining filtrate is then cooled, amino acid or amino acid salts being crystallized out and likewise being filtered off. The amino acid or amino acid salt is then dissolved again, with the result that a treated amino acid salt solution is recovered.
摘要翻译： 提供了一种处理污染的碱性氨基酸盐溶液的方法。 首先，将二氧化碳引入氨基酸盐溶液中，结果碳酸盐或碳酸盐被沉淀，这些被滤出。 然后将剩余的滤液冷却，将氨基酸或氨基酸盐结晶出来并同样被滤出。 然后氨基酸或氨基酸盐再次溶解，结果是回收经处理的氨基酸盐溶液。
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10.发明申请Method and device for separating carbon dioxide from a waste gas of a fossil fueloperated power plant 有权从化石发电厂的废气中分离二氧化碳的方法和装置公开(公告)号：US20110139003A1
公开(公告)日：2011-06-16
申请号：US13003805
申请日：2009-05-14
申请人： Ralph Joh , Rüdiger Schneider , Henning Schramm
发明人： Ralph Joh , Rüdiger Schneider , Henning Schramm
CPC分类号： F23J15/04 , B01D53/1425 , B01D53/1475 , B01D2257/504 , F22B37/008 , F23J15/006 , F23J2215/20 , F23J2215/50 , F23J2219/40 , Y02A50/2342 , Y02C10/04 , Y02C10/06 , Y02E20/326
摘要： A method for separating carbon dioxide from a flue gas of a fossil fuel-operated power plant is provided. In the method, a fossil fuel is initially burned in a combustion process, wherein a hot waste gas containing carbon dioxide is produced. In a next process step, waste gas containing carbon dioxide is brought into contact with an absorption medium in an absorption process, wherein carbon dioxide is absorbed by the absorption medium, thus forming a charged absorption medium. Next, gaseous carbon dioxide is thermally expelled from the charged absorption medium in a desorption process. For this purpose, a vapor is supplied to the desorption process, the vapor is injected into the charged absorption medium, wherein the condensation heat released by the condensation of the vapor is transferred to the charged absorption medium, and the partial pressure of the carbon dioxide is simultaneously reduced in the desorption unit.
摘要翻译： 提供了一种从化石燃料操作的发电厂的烟道气中分离二氧化碳的方法。 在该方法中，化石燃料最初在燃烧过程中燃烧，其中产生含有二氧化碳的热废气。 在下一个工艺步骤中，在吸收过程中，含有二氧化碳的废气与吸收介质接触，其中二氧化碳被吸收介质吸收，从而形成带电的吸收介质。 接下来，气态二氧化碳在解吸过程中从带电吸收介质中热排出。 为此，将蒸气供给到解吸过程中，将蒸汽注入带电的吸收介质中，其中通过蒸气冷凝释放的冷凝热被转移到带电的吸收介质中，并且二氧化碳的分压 在解吸单元中同时减少。
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