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公开(公告)号：US4360607A
公开(公告)日：1982-11-23
申请号：US72396
申请日：1979-09-04
IPC分类号： C08K3/00 , C08J3/28 , C08K3/34 , C08K5/00 , C08K5/05 , C08K5/06 , C08K5/17 , C08K13/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L53/00 , C08L53/02 , C08L71/00 , C08L71/02 , C08L77/00 , C08L101/00 , C08L25/10
CPC分类号： C08K13/02 , C08J3/28 , C08L101/00 , C08L53/02
摘要： A composition of matter suitable for sensitizing thermoplastic compositions to the heating effects of microwave energy in which the components of the composition are (1) an alcohol amine or derivative thereof; (2) a simple or polymeric alkylene glycol or derivative thereof; (3) silica; and (4) optionally, a plastomer that is a normally solid linear or radial teleblock copolymer derived from butadiene and styrene. A method for preparing this composition as a dry, free-flowing powder by preparing a liquid mixture of the polymeric alkylene glycol or derivative and the alcohol amine or derivative which mixture is then charged into a premixed combination of granulated plastomer, if used, and silica. A method for preparing flow molding compounds by admixing a non-polar thermoplastic with a sufficient amount of the sensitizer composition to provide microwave energy sensitivity. Subjecting the flow molding composition, in a mold, to microwave energy thereby producing a flow molded composition.
摘要翻译： 适用于使热塑性组合物对微波能量的加热效果敏感的物质组合物，其中组合物的组分为（1）醇胺或其衍生物; （2）简单或聚合的亚烷基二醇或其衍生物; （3）二氧化硅; 和（4）任选地，塑性体，其是衍生自丁二烯和苯乙烯的通常为固体的线性或径向远嵌段共聚物。 通过制备聚合的亚烷基二醇或衍生物和醇胺或衍生物的液体混合物将该组合物制备成干燥的自由流动的粉末的方法，然后将该混合物加入到颗粒状塑性体（如果使用的话）和二氧化硅 。 通过将非极性热塑性塑料与足量的敏化剂组合物混合来制备流动模塑化合物以提供微波能量敏感性的方法。 将流动模塑组合物在模具中施用于微波能量，从而产生流动模制组合物。
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公开(公告)号：US4400483A
公开(公告)日：1983-08-23
申请号：US248372
申请日：1981-03-27
CPC分类号： C08L53/02 , B29C35/08 , B29C43/003 , B29D30/0005 , C08J3/28 , C08L53/025 , B29C2035/0855 , B29K2009/00 , B29K2809/00
摘要： Compositions comprising a thermoplastic elastomer, e.g., radial block butadiene/styrene copolymer, solid resinous polymer, e.g., vinyl-substituted aromatics, and one or more specific polar compounds. The specific polar compounds are chosen from among simple and polymeric alkaline glycols, their mono and dialkyl ethers; ethanolamines, isopropanolamines, and their hydrocarbylsubstituted derivatives; liquid acrylonitrile/butadiene polymers; acrylonitrile/butadiene blends with homopolymers of polyvinyl chloride and styrene/acrylonitrile copolymers; and mixtures thereof. A method using these compositions for producing molded objects at a molding pressure of up to about 200 psig. Molded objects produced from these compositions and molded objects produced by this method of molding.
摘要翻译： 包含热塑性弹性体的组合物，例如径向嵌段丁二烯/苯乙烯共聚物，固体树脂聚合物，例如乙烯基取代的芳族化合物和一种或多种特定的极性化合物。 特定的极性化合物选自简单和聚合的碱性二醇，它们的单和二烷基醚; 乙醇胺，异丙醇胺及其烃基取代的衍生物; 液态丙烯腈/丁二烯聚合物; 丙烯腈/丁二烯共混物与聚氯乙烯和苯乙烯/丙烯腈共聚物的均聚物; 及其混合物。 使用这些组合物在高达约200psig的成型压力下制造成型物体的方法。 由这些组合物制成的成型体和通过该成型方法制造的成型体。
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公开(公告)号：US4288399A
公开(公告)日：1981-09-08
申请号：US825175
申请日：1977-08-17
CPC分类号： C08L53/02 , B29C35/08 , B29C43/003 , B29D30/0005 , C08J3/28 , C08L53/025 , B29C2035/0855 , B29K2009/00 , B29K2809/00 , Y10S525/901
摘要： Compositions comprising a thermoplastic elastomer, e.g., radial block butadiene/styrene copolymer, solid resinous polymer, e.g., vinyl-substituted aromatics, and one or more specific polar compounds. The specific polar compounds are chosen from among simple and polymeric alkaline glycols, their mono and dialkyl ethers; ethanolamines, isopropanolamines, and their hydrocarbyl-substituted derivatives; liquid acrylonitrile/butadiene polymers; acrylonitrile/butadiene blends with homopolymers of polyvinyl chloride and styrene/acrylonitrile copolymers; and mixtures thereof. A method using these compositions for producing molded objects at a molding pressure of up to about 200 psig. Molded objects produced from these compositions and molded objects produced by this method of molding.
摘要翻译： 包含热塑性弹性体的组合物，例如径向嵌段丁二烯/苯乙烯共聚物，固体树脂聚合物，例如乙烯基取代的芳族化合物和一种或多种特定的极性化合物。 特定的极性化合物选自简单和聚合的碱性二醇，它们的单和二烷基醚; 乙醇胺，异丙醇胺及其烃基取代的衍生物; 液态丙烯腈/丁二烯聚合物; 丙烯腈/丁二烯共混物与聚氯乙烯和苯乙烯/丙烯腈共聚物的均聚物; 及其混合物。 使用这些组合物在高达约200psig的成型压力下制造成型物体的方法。 由这些组合物制成的成型体和通过该成型方法制造的成型体。
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4.发明授权
公开(公告)号：US4234636A
公开(公告)日：1980-11-18
申请号：US973978
申请日：1978-12-28
CPC分类号： C08K3/0033 , C08L25/08 , C08L53/02 , Y10T428/23979 , Y10T442/2885
摘要： An unvulcanized, moldable composition comprising 100 parts by weight of a thermoplastic elastomer, at least about 10 parts by weight of an extender oil per 100 parts by weight of the thermoplastic elastomer and at least about 20 parts by weight of a solid, hygroscopic filler, having greater than 1 percent by weight of absorbed water and capable of retaining a substantial portion of such water at temperatures of at least 100.degree. C., per 100 parts by weight of the thermoplastic elastomer, the ratio of the oil to the hygroscopic filler being from about 0.3 to about 3. A method of flow molding by exposure to microwave energy while applying pressures below about 200 psi and a molded article of manufacture are also described.
摘要翻译： 一种未硫化的可模塑组合物，其包含100重量份的热塑性弹性体，每100重量份的热塑性弹性体至少约10重量份的增量油和至少约20重量份的固体吸湿填料， 具有大于1重量％的吸收的水，并且能够在至少100℃的温度下将相当大部分的水保留在每100重量份的热塑性弹性体中，油与吸湿填料的比例为 约0.3至约3.通过暴露于微波能量同时施加低于约200psi的压力的流动模制的方法和模制制品也被描述。
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公开(公告)号：US4370189A
公开(公告)日：1983-01-25
申请号：US217069
申请日：1980-12-16
CPC分类号： B32B37/00 , B29C35/08 , B32B37/06 , C08J5/121 , B29C2035/0855 , B29K2021/00 , B29K2023/00 , Y10T428/31833 , Y10T428/31909 , Y10T428/31917
摘要： In accordance with the present invention, at least two sheets of a thermoplastic polyalkene are bonded to one another to form a bonded product and at least one surface of a polyalkene is formed on at least a part of a synthetic nonhydrogenated, unvulcanized elastomeric product to form a bonded product by disposing the sheets of polyalkene or at least one sheet of polyalkene on the synthetic elastomeric product, as the case may be, in a mold, closing the mold and subjecting the assembly to microwave energy at a power level, for a time and while applying a pressure sufficient to bond the two polyalkene sheets or the polyalkene sheet to the synthetic elastomeric material, as the case may be.
摘要翻译： 根据本发明，至少两片热塑性聚烯烃彼此结合形成粘结产品，至少一部分合成非氢化的未硫化弹性体产品形成聚烯烃的至少一个表面以形成 粘合产品通过将聚烯烃或至少一片聚烯烃的片材放置在合成弹性体产品上（视情况而定）在模具中，封闭模具并使组件以功率水平对微波能量进行一段时间 并且在施加足以将两个聚烯烃片材或聚烯烃片材粘合到合成弹性体材料上的压力的情况下，视情况而定。
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6.发明授权Molded sponge-like thermoplastic elastomer articles having thin, dense skins and a process for their production 失效模制海绵状热塑性弹性体制品具有薄的，致密的皮肤及其生产方法
公开(公告)号：US4352854A
公开(公告)日：1982-10-05
申请号：US236344
申请日：1981-02-20
CPC分类号： B29C44/00 , C08J9/0061 , C08J9/10 , C08J9/34 , B29K2105/043 , C08J2353/02 , C08J2425/00 , Y10S264/05 , Y10T428/249989
摘要： A molded object having a sponge-like interior surrounded by a skin, molding composition from which it is produced, and the method for producing the article. Copolymers of vinyl-substituted aromatic compounds containing from 8-18 carbon atoms copolymerized with conjugated diene having from 4-12 carbon atoms and polymer chosen from among solid resinous polymers of vinyl-substituted aromatic compounds present in amounts ranging from about 10 to about 75 parts by weight per 100 parts by weight of the copolymer and solid resinous copolymers of ethylene present in an amount of about 5 to about 50 parts by weight per 100 parts by weight of the copolymer are blended with a sufficient amount of polarizing agent to achieve rapid heating through response to microwave treatment, blowing agent in an amount sufficient to provide a sponge-like, rubbery porosity to an article molded therefrom, and, optionally, cellular control agent. Composition is melted at a temperature that activates the blowing agent, molded, and removed from the mold as an article having a sponge-like interior surrounded by polymeric skin.
摘要翻译： 具有由皮肤包围的海绵状内部的成型体，其制造的成型组合物及其制造方法。 含有8-18个碳原子的乙烯基取代的芳族化合物与具有4-12个碳原子的共轭二烯共聚的共聚物和选自乙烯基取代的芳族化合物的固体树脂聚合物的聚合物，其量为约10至约75份 相对于100重量份共聚物，每100重量份共聚物和以每100重量份共聚物约5至约50重量份存在的乙烯的固体树脂共聚物与足量的偏振剂混合以实现快速加热 通过对微波处理的响应，发泡剂的量足以对由其模制的制品和任选的细胞控制剂提供海绵状橡胶状孔隙。 组合物在激活发泡剂的温度下熔融，模塑并作为具有由聚合物皮肤包围的海绵状内部的制品从模具中除去。
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7.发明授权Molding compounds, sponge articles produced therefrom and process of production 失效成型化合物，由其制造的海绵制品和生产方法
公开(公告)号：US4456706A
公开(公告)日：1984-06-26
申请号：US399532
申请日：1982-07-19
CPC分类号： B29C44/00 , C08J9/0061 , C08J9/10 , C08J9/34 , C08J2353/02 , C08J2425/00 , Y10S264/05 , Y10S521/915 , Y10S525/901
摘要： A molded object having a sponge-like interior surrounded by a skin, molding composition from which it is produced, and the method for producing the article. Copolymers of vinyl-substituted aromatic compounds containing from 8-18 carbon atoms copolymerized with conjugated diene having from 4-12 carbon atoms and polymer chosen from among solid resinous polymers of vinyl-substituted aromatic compounds present in amounts ranging from about 10 to about 75 parts by weight per 100 parts by weight of the copolymer and solid resinous copolymers of ethylene present in an amount of about 5 to about 50 parts by weight per 100 parts by weight of the copolymer are blended with a sufficient amount of polarizing agent to achieve rapid heating through response to microwave treatment, blowing agent in an amount sufficient to provide a sponge-like, rubbery porosity to an article molded therefrom, and, optionally, cellular control agent. Composition is melted at a temperature that activates the blowing agent, molded, and removed from the mold as an article having a sponge-like interior surrounded by polymeric skin.
摘要翻译： 具有由皮肤包围的海绵状内部的成型体，其制造的成型组合物及其制造方法。 含有8-18个碳原子的乙烯基取代的芳族化合物与具有4-12个碳原子的共轭二烯共聚的共聚物和选自乙烯基取代的芳族化合物的固体树脂聚合物的聚合物，其量为约10至约75份 相对于100重量份共聚物，每100重量份共聚物和以每100重量份共聚物约5至约50重量份存在的乙烯的固体树脂共聚物与足量的偏振剂混合以实现快速加热 通过对微波处理的响应，发泡剂的量足以对由其模制的制品和任选的细胞控制剂提供海绵状橡胶状孔隙。 组合物在激活发泡剂的温度下熔融，模塑并作为具有由聚合物皮肤包围的海绵状内部的制品从模具中除去。
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8.发明授权Fabric-backed teleblock copolymer composition with dulled surface useful in footwear uppers 失效织物背衬的teleblock共聚物组合物，具有用于鞋面鞋面的钝化表面
公开(公告)号：US4168341A
公开(公告)日：1979-09-18
申请号：US879568
申请日：1978-02-21
IPC分类号： B32B25/10 , C09J153/02 , D06N3/10 , C08L9/00
CPC分类号： B32B25/10 , C09J153/02 , D06N3/10 , Y10S525/901 , Y10T428/3175 , Y10T428/31786 , Y10T428/31855 , Y10T442/387
摘要： A laminate in which a fabric backing is adhered to a composition containing a radial teleblock copolymer having blocks of poly(conjugated diene) and poly(monovinylaromatic) and sufficient surface dulling agent to provide a suede-like surface. A laminate as described having high air permeability and suede-like surface is used as material for uppers of shoes.
摘要翻译： 其中织物背衬粘附到包含具有聚（共轭二烯）和聚（单乙烯基芳族化合物）嵌段的径向远端嵌段共聚物和足够的表面钝化剂的组合物以提供麂皮状表面的层压体。 如上所述的具有高透气性和绒面状表面的层压材料用作鞋的鞋面材料。
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9.发明授权Unvulcanized expanded high green strength synthetic rubber product and method of manufacture 失效未硫化膨胀高强度合成橡胶制品及其制造方法
公开(公告)号：US3959545A
公开(公告)日：1976-05-25
申请号：US440168
申请日：1974-02-06
申请人： Roy W. Siedenstrang
发明人： Roy W. Siedenstrang
CPC分类号： C08J9/06 , C08J2321/00 , C08J2353/02 , Y10S264/05 , Y10T428/24355 , Y10T428/2457
摘要： An expanded rubber, e.g., a foam or sponge-type material is obtained by admixing with a high green strength rubber an expanding or blowing agent, causing the agent to function and then quenching the expanding product to cool and set the same for example with cold water. Various applications of the process include cushioning material, rug underlay, shoe insole, slipper-type footwearing apparel, etc.
摘要翻译： 膨胀橡胶，例如泡沫或海绵型材料通过与高生坯强度橡胶，膨胀或发泡剂混合而获得，使得试剂起作用，然后使膨胀产物冷却并将其固化，例如用冷 水。 该工艺的各种应用包括缓冲材料，地毯底垫，鞋垫，拖鞋式鞋类服装等。
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