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公开(公告)号：US09533922B2
公开(公告)日：2017-01-03
申请号：US14888520
申请日：2014-05-06
发明人： Munaka Christopher Maumela , Moses Mokgolela Mogorosi , Molise Stephen Mokhadinyana , Matthew James Overett , Kevin Blann , Cedric Wahl Holzapfel
CPC分类号： C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/18 , C07C2531/24 , C07C2531/34 , C07C11/107 , C07C11/02
摘要： A process for the oligomerization of ethylene to predominantly 1-hexene or 1-octene or mixtures of 1-hexene and 1-octene includes contacting ethylene with a catalyst under ethylene oligomerization conditions. The catalyst comprises a source of chromium, a diphosphine ligating compound, and optionally an activator. The diphosphine ligating compound includes at least one optionally substituted fused cyclic structure including at least two rings, the optionally substituted fused cyclic structure including a 5- to 7-membered aromatic first ring bonded to a phosphorus atom, the aromatic first ring being fused to a 4- to 8-membered heterocyclic second ring, the heterocyclic second ring including a heteroatom which is separated by two ring atoms along the shortest connecting path from the phosphorous atom that is bonded to the first aromatic ring.
摘要翻译： 将乙烯低聚至主要1-己烯或1-辛烯或1-己烯和1-辛烯的混合物的方法包括在乙烯齐聚条件下使乙烯与催化剂接触。 催化剂包含铬源，二膦连接化合物和任选的活化剂。 二膦连接化合物包括至少一个包含至少两个环的任选取代的稠合环状结构，任选取代的稠合环状结构包括与磷原子键合的5-至7-元芳族第一环，芳族第一环与 4-至8-元杂环第二环，杂环第二环包括由键合到第一芳香环上的磷原子的最短连接路径被两个环原子分开的杂原子。
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2.发明授权Method of preparing a modified support, a catalyst precursor and a catalyst, and a hydrocarbon synthesis process using the catalyst 有权制备改性载体，催化剂前体和催化剂的方法以及使用该催化剂的烃合成方法公开(公告)号：US09527782B2
公开(公告)日：2016-12-27
申请号：US14408726
申请日：2013-07-26
发明人： Rita Meyer , Jacobus Lucas Visagie
IPC分类号： C07C1/04 , B01J20/284 , B01J23/75 , B01J23/89 , B01J20/30 , B01J37/03 , B01J37/08 , B01J21/04 , B01J21/06 , B01J35/00 , C10G2/00
CPC分类号： C07C1/043 , B01J20/284 , B01J20/30 , B01J21/04 , B01J21/063 , B01J23/75 , B01J23/8913 , B01J35/0006 , B01J35/002 , B01J37/033 , B01J37/08 , C07C1/0445 , C10G2/33
摘要： A method of preparing a modified catalyst support comprises preparing a titanium-containing catalyst support material by (i) contacting a catalyst support material with an organic titanium compound, or (ii) co-hydrolyzing a hydrolysable organic titanium compound and Al(OR″)3, with the titanium-containing catalyst support material then including Al, wherein all R″ are the same or different and are each an organic group. The titanium-containing catalyst support material is calcined at a temperature above 900° C. to obtain a modified catalyst support which includes more than 1 wt % and less than 3.5 wt % Ti, based on the mass of the catalyst support material in the modified catalyst support, the Ti being present in the form of one or more titanium compounds.
摘要翻译： 制备改性催化剂载体的方法包括：（i）使催化剂载体材料与有机钛化合物接触，或（ii）将可水解的有机钛化合物和Al（OR“）的共水解，从而制备含钛催化剂载体材料; 如图3所示，含钛催化剂载体材料随后包括Al，其中所有R“相同或不同，并且各自为有机基团。 含钛催化剂载体材料在高于900℃的温度下煅烧，以获得改性的催化剂载体，其包含大于1重量％且小于3.5重量％的Ti，基于改性的催化剂载体材料的质量 催化剂载体，Ti以一种或多种钛化合物的形式存在。
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3.发明授权Process and installation for making protected catalyst bodies by means of a molten organic substance 有权通过熔融有机物质制备受保护的催化剂体的工艺和安装公开(公告)号：US09114388B2
公开(公告)日：2015-08-25
申请号：US14144330
申请日：2013-12-30
发明人： Zofia Anna Brodziak
IPC分类号： B29C39/02 , B29C39/06 , B01J33/00 , B01J35/02 , B01J37/00 , B01J37/02 , C10G2/00 , B41D3/08 , B41D3/12
CPC分类号： B01J33/00 , B01J35/026 , B01J37/0009 , B01J37/0081 , B01J37/0219 , B01J37/0221 , B01J2208/00752 , B01J2208/00814 , B41D3/08 , B41D3/12 , C10G2/332 , C10G2300/70
摘要： A process for handling an active catalyst includes introducing a mixture of active catalyst particles and a molten organic substance, which is at a temperature T1, and which sets at a lower temperature T2 so that T2
摘要翻译： 处理活性催化剂的方法包括将温度为T1的活性催化剂颗粒和熔融有机物质的混合物引入模具中，并将其设定在较低温度T2，使T2
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公开(公告)号：US09061952B2
公开(公告)日：2015-06-23
申请号：US14379482
申请日：2013-02-20
CPC分类号： C07C1/0485 , C07C1/0435 , C07C2523/75 , C10G2/32 , C10G2/331 , C10G2/332
摘要： A process (10) to produce Fischer-Tropsch products includes feeding feed synthesis gas (30) with a substantially constant target feed synthesis gas H2/CO ratio to a Fischer-Tropsch synthesis stage (16). A portion of the feed synthesis gas (30) is converted to Fischer-Tropsch products in the Fischer-Tropsch synthesis stage (16). The Fischer-Tropsch products (20) from the Fischer-Tropsch synthesis stage (16) are withdrawn. A Fischer-Tropsch synthesis stage tail gas (26) which includes unconverted H2 and CO is obtained. The operating conditions of the Fischer-Tropsch synthesis stage (16) are manipulated to achieve a substantially constant target tail gas H2/CO ratio, with the target tail gas H2/CO ratio being substantially different from the target feed synthesis gas H2/CO ratio.
摘要翻译： 制备费 - 托产品的方法（10）包括将基本上恒定的目标原料合成气H 2 / CO比的进料合成气（30）进料到费 - 托合成阶段（16）。 一部分原料合成气（30）在费 - 托合成阶段（16）中转化成费 - 托产物。 取出费 - 托合成阶段（16）的费 - 托产物（20）。 得到包含未转化的H 2和CO的费 - 托合成段尾气（26）。 操作费 - 托合成阶段（16）的操作条件以实现基本上恒定的目标尾气H 2 / CO比，目标尾气H 2 / CO比率与目标原料合成气H 2 / CO比率基本上不同 。
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公开(公告)号：US20030225224A1
公开(公告)日：2003-12-04
申请号：US10156686
申请日：2002-05-28
发明人： Ioan Tincul , Dawid Johannes Joubert , Udo Maximilian Wahner , Sarel Petrus Jacobus Smith , Pieter Willem Van Zyl
IPC分类号： C08F002/00
CPC分类号： C08F210/00 , C08F4/65912 , C08F210/06 , C08F4/65925 , C08F4/655 , C08F4/6555 , C08F2/14 , C08F2/06 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F210/16 , C08F210/08
摘要： A polymer includes at least propylene as a first monomeric component, 1-pentene as a second monomeric component, and, as a third monomeric component, a third olefin. The third olefin has fewer than 5 carbon atoms, is linear and is not propylene, or has 5 carbon atoms and is branched, or has more than 5 carbon atoms and is linear or branched.
摘要翻译： 聚合物至少包括作为第一单体组分的丙烯，作为第二单体组分的1-戊烯，和作为第三单体组分的第三烯烃。 第三烯烃具有少于5个碳原子，是线性的并且不是丙烯，或具有5个碳原子并且是支链的或具有多于5个碳原子并且是直链或支链的。
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公开(公告)号：US20030125201A1
公开(公告)日：2003-07-03
申请号：US10159970
申请日：2002-05-31
IPC分类号： B01J023/75
CPC分类号： C10G2/332 , B01J23/75 , B01J23/8913 , B01J37/08 , B01J37/082
摘要： A cobalt catalyst precursor includes a catalyst support impregnated with cobalt. All reducible cobalt is present in the support as supported cobalt oxide of formula-unit CoOaHb, where anull1,7 and bnull0. A process for preparing a cobalt catalyst precursor, and a process for preparing a cobalt catalyst are also provided.
摘要翻译： 钴催化剂前体包括浸渍有钴的催化剂载体。 所有可还原钴在载体中作为式 - 单元CoOaHb的负载型钴氧化物存在，其中a> = 1,7和b> = 0。 还提供了制备钴催化剂前体的方法和制备钴催化剂的方法。
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公开(公告)号：US20010025091A1
公开(公告)日：2001-09-27
申请号：US09761633
申请日：2001-03-12
IPC分类号： C08F004/44
CPC分类号： C08F210/16 , C08F2/14 , C08F210/14 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F210/06
摘要： The invention provides a polymer of ethylene as a first component or monomer, with a branched olefin as a second component or monomer, and at least one different olefin as a third component or monomer. The olefins can be obtained from a Fischer-Tropsch process.
摘要翻译： 本发明提供了乙烯作为第一组分或单体的聚合物，其中支链烯烃作为第二组分或单体，以及至少一种不同的烯烃作为第三组分或单体。 烯烃可以从费 - 托方法获得。
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公开(公告)号：US20200283685A1
公开(公告)日：2020-09-10
申请号：US15932374
申请日：2016-08-10
摘要： A method for starting a slurry bubble column reactor that includes a reactor vessel holding a settled or slumped bed of particles and a liquid phase from which the particles have settled includes introducing a flow of a re-suspension liquid into the settled or slumped bed to loosen the settled or slumped bed. The introduction of the re-suspension liquid takes place before the introduction of any gas into the settled or slumped bed, or together with feeding of gas into the settled or slumped bed, provided that, if gas is fed together with the re-suspension liquid into the settled or slumped bed before the settled or slumped bed has been loosened, the gas has a superficial gas velocity in the reactor below 10 cm/s. Once the settled or slumped bed has been loosened by at least the re-suspension liquid, gas is passed at a superficial gas velocity above 10 cm/s through the liquid phase.
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公开(公告)号：US10322393B2
公开(公告)日：2019-06-18
申请号：US15855860
申请日：2017-12-27
发明人： André Peter Steynberg , Evert Phillippus Kleynhans , Marshall Stephen Lee , Hermanus Gerhardus Nel , Jako Louw
摘要： A method of operating a slurry phase apparatus includes feeding one or more gaseous reactants into a slurry body of solid particulate material suspended in a suspension liquid contained inside a vessel. The one or more gaseous reactants are fed into the slurry body through a gas distributor having downward facing gas outlets and are fed towards a fluid impermeable partition spanning across the vessel below the gas distributor. The partition divides the vessel into a slurry volume above the partition and a bottom volume below the partition. A differential pressure is maintained over the partition between predefined limits by manipulating or allowing changes in the pressure in the bottom volume by employing a pressure transfer passage establishing flow or pressure communication between the bottom volume and a head space above the slurry body.
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公开(公告)号：US10233789B2
公开(公告)日：2019-03-19
申请号：US15034097
申请日：2014-10-31
发明人： Franco Gasparini , Rian Wessels , Corné Welgemoed
摘要： A method of operating a combined heat and power plant (10) (CHP plant) includes generating hot flue gas and cooling the hot flue gas in a sequence of cooling steps to recover heat and to generate steam in a heat recovery steam generator (16) (HRSG). The HRSG (16) includes an LP steam evaporator (36) designed to generate steam at least over a pressure range of from 2 bar(g) to 18 bar(g) so that either LP steam or MP steam can selectively be generated by the LP steam generator (36), thereby to cool the hot flue gas, and an MP steam superheater (24) upstream of the LP steam evaporator (36) to superheat MP steam in heat exchange with the hot flue gas thereby to cool the hot flue gas. The method further includes, when no or insufficient MP steam is being imported to the MP steam superheater (24) to ensure safe operation of the MP steam superheater, and/or when a demand exists for exporting MP steam which cannot be satisfied by imported MP steam superheated in the MP steam superheater (24), and/or when a demand exists for MP steam in the CHP plant which cannot be satisfied by imported MP steam, operating the LP steam evaporator (36) at an operating pressure in the range of between 8 bar(g) and 18 bar(g) to generate MP steam to wet the MP steam superheater (24) and/or to satisfy at least to some extent said demand for MP steam, and thereafter, when sufficient MP steam is being imported to the MP steam superheater (24) from external of the CHP plant (10) to ensure safe operation of the MP steam superheater (24), and/or when any demand for exported MP steam is satisfied by imported MP steam which is superheated in the MP steam superheater (24) and then exported, and/or when there is no more demand for exporting of MP steam, and/or when the demand for MP steam in the CHP plant (10) is being satisfied at least to some extent by imported MP steam, reducing the operating pressure of the LP steam evaporator (36) to a pressure in the range of between 2 bar(g) and 8 bar(g) thereby to generate LP steam.
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