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19 条记录 (耗时 0.013 秒)

    Process for the production of 11,11,12,12-tetracyano-9,10-anthraquinodimehane _or its derivatives
    3.
    发明授权
    Process for the production of 11,11,12,12-tetracyano-9,10-anthraquinodimehane _or its derivatives 失效
    制备11,11,12,12-四氰基-9,10-蒽醌二甲烷或其衍生物的方法

    公开(公告)号：US4478753A

    公开(公告)日：1984-10-23

    申请号：US426069

    申请日：1982-09-28

    申请人： Shu Hotta ,  Tomiharu Hosaka ,  Nobuo Sonoda ,  Wataru Shimotsuma

    发明人： Shu Hotta ,  Tomiharu Hosaka ,  Nobuo Sonoda ,  Wataru Shimotsuma

    IPC分类号： C07C255/34 ,  C07C17/18 ,  C07C17/32 ,  C07C67/00 ,  C07C253/00 ,  C07C255/36 ,  C07C255/42 ,  C07C121/64

    CPC分类号： C07C17/18 ,  C07C17/32 ,  C07C2103/24

    摘要： A process for producing 11,11,12,12-tetracyano-9,10-anthraquinodimethane or its derivatives of the general formula ##STR1## in which Z.sub.1, Z.sub.4, Z.sub.5, and Z.sub.8 independently represent hydrogen, chlorine, hydroxy or amino group and Z.sub.2, Z.sub.3, Z.sub.6 and Z.sub.7 independently represent hydrogen, halogen, alkyl which has 1 to 8 carbon atoms, phenyl, alkylphenyl whose alkyl group has 1 to 2 carbon atoms, hyroxyalkly which has 1 to 8 carbon atoms, carboxyalkyl whose alkyl group has 1 to 8 carbon atoms, hydroxy amino, or carboxyl group, the process comprising introduction of dicyanomethyl groups into an anthracene compound of the following general formula at 9 and 10 positions ##STR2## in which Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, Z.sub.5, Z.sub.6, Z.sub.7 and Z.sub.8 have the same meanings as defined above, and dehydrogenation of the dicyanomethyl groups.

    摘要翻译： 制备11,11,12,12-四氰基-9,10-蒽醌二甲烷或其通式“IMAGE”的衍生物的方法，其中Z1，Z4，Z5和Z8独立地表示氢，氯，羟基或氨基， Z2，Z3，Z6和Z7独立地表示氢，卤素，具有1-8个碳原子的烷基，苯基，其烷基具有1至2个碳原子的烷基苯基，具有1至8个碳原子的羟基链烷基，其烷基具有1个 8个碳原子，羟基氨基或羧基的方法，该方法包括将二氰基甲基引入下述通式的蒽化合物中，其中Z1和Z2，Z3，Z4，Z5，Z6， Z7和Z8具有与上述相同的含义，并且二氰基甲基的脱氢。

    Process for producing polyacetylene
    4.
    发明授权
    Process for producing polyacetylene 失效
    生产聚乙炔的方法

    公开(公告)号：US4983696A

    公开(公告)日：1991-01-08

    申请号：US465421

    申请日：1990-01-16

    申请人： Mamoru Soga ,  Shu Hotta ,  Nobuo Sonoda

    发明人： Mamoru Soga ,  Shu Hotta ,  Nobuo Sonoda

    IPC分类号： C08F38/02

    CPC分类号： C08F38/02

    摘要： A polyacetylene with excellent stretchability can be obtained by a process which comprises polymerizing acetylene with a Ziegler-Natta catalyst consisting of a tetraalkyl titanate and a trialkylaluminum, wherein in the Ziegler-Natta catalyst at least one of the tetraalkyl titanate and the trialkylaluminum has a long chain alkyl group and the molar ratio of al to Ti is 1.5-10.

    摘要翻译： 具有优异的拉伸性的聚乙炔可以通过包括使乙炔与由四烷基钛酸酯和三烷基铝组成的齐格勒 - 纳塔催化剂聚合的方法获得，其中在齐格勒 - 纳塔催化剂中，至少一种钛酸四烷基酯和三烷基铝具有长 链烷基，Al与Ti的摩尔比为1.5-10。

    Anion-doped polymers of five-membered oxygen family heterocyclic compounds and method for producing same
    5.
    发明授权
    Anion-doped polymers of five-membered oxygen family heterocyclic compounds and method for producing same 失效
    五元氧族杂环化合物的阴离子掺杂聚合物及其制备方法

    公开(公告)号：US4501686A

    公开(公告)日：1985-02-26

    申请号：US488598

    申请日：1983-04-25

    申请人： Shu Hotta ,  Tomiharu Hosaka ,  Nobuo Sonoda ,  Wataru Shimotsuma

    发明人： Shu Hotta ,  Tomiharu Hosaka ,  Nobuo Sonoda ,  Wataru Shimotsuma

    IPC分类号： C08G61/12 ,  H01B1/12 ,  H01M4/60 ,  H01B1/06

    CPC分类号： H01M4/60 ,  C08G61/123 ,  H01B1/127

    摘要： Polymeric materials consisting essentially of a polymer of recurring units of a five-membered oxygen family heterocyclic ring which are selected from furan, thiophene, selenophene, tellurophene and derivatives thereof. The polymer is doped with anions of the specific type. A method for producing the polymeric materials is also described which comprises electrochemically polymerizing a five-membered oxygen family heterocyclic compound in coexistence with an acceptor with or without use of a supporting electrolyte in such a way that anions of the specific type are taken in the polymerized heterocyclic compound. The polymeric material is obtained in the form of a dense tenacious film.

    摘要翻译： 基本上由选自呋喃，噻吩，硒吩，特兰普兰及其衍生物的五元氧族杂环的重复单元的聚合物组成的聚合材料。 聚合物掺杂了特定类型的阴离子。 还描述了一种生产聚合物材料的方法，其中包括在使用或不使用支持电解质的情况下，使五元氧族杂环化合物与受体共存于电化学聚合，使得特定类型的阴离子被吸收在聚合物 杂环化合物。 聚合物材料以致密的韧性膜的形式获得。

    Tetracyanoanthraquinodimethane compounds
    6.
    发明授权
    Tetracyanoanthraquinodimethane compounds 失效
    四氰基蒽醌二甲烷化合物

    公开(公告)号：US4500459A

    公开(公告)日：1985-02-19

    申请号：US357664

    申请日：1982-03-12

    申请人： Shu Hotta ,  Tomiharu Hosaka ,  Wataru Shimotsuma

    发明人： Shu Hotta ,  Tomiharu Hosaka ,  Wataru Shimotsuma

    IPC分类号： C07C67/00 ,  C07C253/00 ,  C07C255/34 ,  C08G61/10 ,  C08G65/34 ,  C08K5/29 ,  C09B1/00 ,  H01B1/12 ,  H01L51/30 ,  C07C50/20

    CPC分类号： H01B1/121 ,  C07C255/00 ,  C08G61/10 ,  C08G65/34 ,  C08K5/29 ,  C09B1/00 ,  H01L51/0051 ,  Y02E10/549

    摘要： A 11,11,12,12,-tetracyano-9,10-antraquinondimethane compound of the general formula ##STR1## wherein Z.sub.2, Z.sub.3, Z.sub.6 and Z.sub.7 each is H, halogen, alkyl, phenyl, alkylphenyl, hydroxyalkyl, carboxyalkyl, hydroxy, amino or carboxy and Z.sub.1, Z.sub.4, Z.sub.5 and Z.sub.8 each is H, Cl, hydroxy or amino; said halogen being F, Cl, Br or I and said alkyl, alkylphenyl, hydroxyalkyl and carboxyalkyl each containing up to 8 carbon atoms.The compounds within the scope of the above general formula are of value as organic conductors or organic semiconductors and can be used broadly as electronic materials.

    摘要翻译： 其中Z2，Z3，Z6和Z7各自为H，卤素，烷基，苯基，烷基苯基，羟基烷基，羧基烷基，羟基的烷基，11,11,12,12-四氰基-9,10-蒽醌二甲烷化合物 ，氨基或羧基，Z 1，Z 4，Z 5和Z 8各自为H，Cl，羟基或氨基; 所述卤素是F，Cl，Br或I，并且所述烷基，烷基苯基，羟基烷基和羧基烷基各自含有至多8个碳原子。 上述通式范围内的化合物作为有机导体或有机半导体具有价值，可广泛用作电子材料。

    Process for producing polyacetylene
    8.
    发明授权
    Process for producing polyacetylene 失效
    生产聚乙炔的方法

    公开(公告)号：US5216102A

    公开(公告)日：1993-06-01

    申请号：US767580

    申请日：1991-09-30

    申请人： Mamoru Soga ,  Shu Hotta ,  Nobuo Sonoda ,  Hideki Shirakawa ,  Kazuo Akagi

    发明人： Mamoru Soga ,  Shu Hotta ,  Nobuo Sonoda ,  Hideki Shirakawa ,  Kazuo Akagi

    IPC分类号： C08F38/02 ,  C08F138/02 ,  C08J5/18

    CPC分类号： C08J5/18 ,  C08F138/02 ,  C08F38/02 ,  C08J2349/00 ,  Y10S526/901

    摘要： The present invention provides a process for producing a polyacetylene.In the present process for producing a polyacetylene, acetylene is polymerized with a Ziegler-Natta catalyst consisting of a trialkylaluminum and an alkyl titanate, wherein there is used, as the trialkylaluminum, a trialkylaluminum having an alkyl group of 6 or more carbon atoms, or, as the alkyl titanate, an alkyl titanate having an alkyl group of 6 or more carbon atoms.The polyacetylene obtained according to the present invention is superior in mechanical properties, particularly stretchability.

    摘要翻译： 本发明提供聚乙炔的制造方法。 在本发明的聚乙炔的制备方法中，乙炔与由三烷基铝和钛酸烷基酯组成的齐格勒 - 纳塔催化剂聚合，其中作为三烷基铝使用具有6个或更多个碳原子的烷基的三烷基铝，或 作为钛酸烷基酯，具有6个以上碳原子的烷基的钛酸烷基酯。 根据本发明获得的聚乙炔的机械性能，特别是拉伸性优异。

    Recording media and recording methods
    9.
    发明授权
    Recording media and recording methods 失效
    录制媒体和录制方式

    公开(公告)号：US4735879A

    公开(公告)日：1988-04-05

    申请号：US726387

    申请日：1985-04-23

    申请人： Shu Hotta ,  Mamoru Soga ,  Wataru Shimotsuma

    发明人： Shu Hotta ,  Mamoru Soga ,  Wataru Shimotsuma

    IPC分类号： G11B7/244 ,  B41M5/26 ,  G11B7/00 ,  G11B7/003 ,  G11B7/0045 ,  G11B7/24 ,  G11B7/245 ,  G11C13/04 ,  G03C11/00 ,  G01D15/10

    CPC分类号： G11B7/245 ,  Y10S430/146

    摘要： The present invention provides a recording medium employing conductive polymers and a recording method employing the recording medium. The recording medium of the present invention is comprised of a substrate and a conductive polymer layer including a dopant therein and layered on the substrate. In addition, the recording method according to the present invention is effected on the basis of selective change in the amount of the dopant contained in the conductive polymers. The recording medium according to the present invention is utilizable ion the field of recording, memory and electronic devices, while displaying remarkably advantageous recording characteristics and environmental stability.

    摘要翻译： 本发明提供采用导电聚合物的记录介质和采用记录介质的记录方法。 本发明的记录介质由衬底和包括其中的掺杂剂的导电聚合物层组成，并且在衬底上层叠。 此外，根据本发明的记录方法是基于导电聚合物中包含的掺杂剂的量的选择性变化来实现的。 根据本发明的记录介质在记录，存储和电子设备的领域是可利用的，同时显示出非常有利的记录特性和环境稳定性。

    Anion-doped polymers of five-membered oxygen family heterocyclic compounds and method for producing same
    10.
    发明授权
    Anion-doped polymers of five-membered oxygen family heterocyclic compounds and method for producing same 失效
    五元氧族杂环化合物的阴离子掺杂聚合物及其制备方法

    公开(公告)号：US4582587A

    公开(公告)日：1986-04-15

    申请号：US675644

    申请日：1984-11-28

    申请人： Shu Hotta ,  Tomiharu Hosaka ,  Nobuo Sonoda ,  Wataru Shimotsuma

    发明人： Shu Hotta ,  Tomiharu Hosaka ,  Nobuo Sonoda ,  Wataru Shimotsuma

    IPC分类号： C08G61/12 ,  H01B1/12 ,  H01M4/60 ,  C22B11/04 ,  H01B1/00 ,  H01B1/06

    CPC分类号： H01M4/60 ,  C08G61/123 ,  H01B1/127

    摘要： Polymeric materials consisting essentially of a polymer of recurring units of a five-membered oxygen family heterocyclic ring which is selected from furan, thiophene, selenophene, tellurophene and derivatives thereof. The polymer is doped with anions of the specific type. A method for producing the polymeric materials is also described which comprises electrochemically polymerizing a five-membered oxygen family heterocyclic compound in coexistence with an acceptor with or without use of a supporting electrolyte in such a way that anions of the specific type is taken in the polymerized heterocyclic compound. The polymeric material is obtained in the form of a dense tenacious film.

    摘要翻译： 基本上由选自呋喃，噻吩，硒吩，特氟丙烯及其衍生物的五元氧族杂环的重复单元的聚合物组成的聚合材料。 聚合物掺杂了特定类型的阴离子。 还描述了生产聚合物材料的方法，该方法包括在有或没有使用支持电解质的情况下使五元氧族杂环化合物与受体共存于电化学聚合，使得特定类型的阴离子被吸收在聚合物 杂环化合物。 聚合物材料以致密的韧性膜的形式获得。