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    Process for the production of xylenes and light olefins
    1.
    发明授权
    Process for the production of xylenes and light olefins 有权
    生产二甲苯和轻质烯烃的方法

    公开(公告)号：US09181146B2

    公开(公告)日：2015-11-10

    申请号：US13465721

    申请日：2012-05-07

    申请人： Larry L. Iaccino ,  James R. Lattner ,  Glenn C. Wood ,  Surbhi Jain ,  Stephen M. Davis

    发明人： Larry L. Iaccino ,  James R. Lattner ,  Glenn C. Wood ,  Surbhi Jain ,  Stephen M. Davis

    IPC分类号： C07C1/24 ,  C07C2/86 ,  C10G29/20 ,  C10G35/00 ,  C10G57/00 ,  C10G9/00 ,  C10G9/36 ,  C10G11/00

    CPC分类号： C07C2/864 ,  C10G9/005 ,  C10G9/36 ,  C10G11/00 ,  C10G29/205 ,  C10G35/00 ,  C10G57/005 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/30 ,  C07C15/08

    摘要： In a hydrocarbon upgrading process, a hydrocarbon feed is treated in at least one of a steam cracker, catalytic cracker, coker, hydrocracker, and reformer under suitable conditions to produce a first stream comprising olefinic and aromatic hydrocarbons. A second stream composed mainly of C4 to C12 olefinic and aromatic hydrocarbons is recovered from the first stream and at least part of the second stream is contacted with a catalyst in the absence of added hydrogen under reaction conditions including a temperature of about 450° C. to about 70° C. effective to dealkylate, transalkylate, crack and aromatize components of the second stream to produce a third stream having an increased benzene and/or toluene content compared with the second stream and a C3− olefin by-product. The C3− olefin by-product and a fourth stream comprising toluene are then recovered from the third stream.

    摘要翻译： 在烃改质方法中，在合适条件下，在蒸汽裂化器，催化裂化器，焦化器，加氢裂化器和重整器中的至少一种中处理烃进料以产生包含烯烃和芳族烃的第一流。 在第一料流中回收主要由C4至C12烯属和芳烃组成的第二料流，并且在包括约450℃的温度的反应条件下，至少部分第二料流在不加入氢气的情况下与催化剂接触。 至约70℃有效地使第二物流的烷基化，烷基转移，裂解和芳构化成分，以产生与第二物流和C3-烯烃副产物相比具有增加的苯和/或甲苯含量的第三物流。 然后从第三流中回收C3-烯烃副产物和包含甲苯的第四料流。

    Process for the Production of Xylenes and Light Olefins
    2.
    发明申请
    Process for the Production of Xylenes and Light Olefins 有权
    生产二甲苯和轻烯烃的方法

    公开(公告)号：US20130296623A1

    公开(公告)日：2013-11-07

    申请号：US13465750

    申请日：2012-05-07

    申请人： Larry L. Iaccino ,  Stephen M. Davis ,  Steven E. Silverberg

    发明人： Larry L. Iaccino ,  Stephen M. Davis ,  Steven E. Silverberg

    IPC分类号： C07C2/64

    CPC分类号： C07C2/64 ,  C07C2/864 ,  C10G9/005 ,  C10G9/36 ,  C10G11/00 ,  C10G29/205 ,  C10G35/00 ,  C10G57/005 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/30 ,  C07C15/08

    摘要： In a hydrocarbon upgrading process, a hydrocarbon feed is treated in at least one of a steam cracker, catalytic cracker, coker, hydrocracker, and reformer under suitable conditions to produce a first stream comprising olefinic and aromatic hydrocarbons. A second stream composed mainly of C4 to C12+ olefinic and aromatic hydrocarbons is recovered from the first stream and blended said second stream with a residual fraction from a steam cracker or an atmospheric or vacuum distillation unit to produce a third stream. The third stream is then catalytically pyrolyzed in a reactor under conditions effective to produce a fourth stream having an increased benzene and/or toluene content compared with said second stream and a C3-olefin by-product. The C3-olefin by-product is recovered and benzene and/or toluene are recovered from the fourth stream.

    摘要翻译： 在烃改质方法中，在合适条件下，在蒸汽裂化器，催化裂化器，焦化器，加氢裂化器和重整器中的至少一种中处理烃进料以产生包含烯烃和芳族烃的第一流。 从第一流回收主要由C4至C12 +烯烃和芳烃组成的第二料流，并将所述第二料流与来自蒸汽裂化器或大气压或真空蒸馏装置的残余馏分混合以产生第三料流。 然后在有效产生与所述第二料流和C3-烯烃副产物相比具有增加的苯和/或甲苯含量的第四料流的条件下，在反应器中催化热解。 回收C3-烯烃副产物，从第四料流回收苯和/或甲苯。

    Integrated catalytic cracking and olefin producing process using staged backflow regeneration
    6.
    发明授权
    Integrated catalytic cracking and olefin producing process using staged backflow regeneration 失效
    综合催化裂化和烯烃生产过程使用分级回流再生

    公开(公告)号：US5447622A

    公开(公告)日：1995-09-05

    申请号：US154828

    申请日：1993-11-19

    申请人： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

    发明人： Michael C. Kerby ,  Roby Bearden, Jr. ,  Stephen M. Davis

    IPC分类号： C10G11/18 ,  C10G57/00 ,  C10G51/06 ,  C07C1/00

    CPC分类号： C10G57/00 ,  C10G11/18

    摘要： Disclosed is a method which combines catalytic cracking and olefin production using a coked catalytic cracking catalyst as a dehydrogenation catalyst to dehydrogenate an alkane feed stream and form an olefin rich product stream. The method uses a staged backmixed regeneration system to form the dehydrogenation catalyst and to fully reactivate deactivated cracking catalyst for reuse in the cracking reaction. The catalyst preferably comprises a crystalline tetrahedral framework oxide component.

    摘要翻译： 公开了一种使用焦化催化裂化催化剂作为脱氢催化剂将催化裂化和烯烃生产组合以使烷烃进料流脱氢并形成富烯烃产物流的方法。 该方法使用分级回混再生系统形成脱氢催化剂，并在破裂反应中完全还原失活的裂化催化剂以供再利用。 催化剂优选包含结晶四面体骨架氧化物组分。

    Integrated fluid coking paraffin dehydrogenation process
    7.
    发明授权
    Integrated fluid coking paraffin dehydrogenation process 失效
    综合流体焦化石蜡脱氢工艺

    公开(公告)号：US5435905A

    公开(公告)日：1995-07-25

    申请号：US144984

    申请日：1993-10-27

    申请人： Stephen M. Davis ,  Michael C. Kerby ,  Roby Bearden, Jr.

    发明人： Stephen M. Davis ,  Michael C. Kerby ,  Roby Bearden, Jr.

    IPC分类号： C07C5/333 ,  C10G51/02 ,  C10G57/00 ,  C07C5/00

    CPC分类号： C10G57/00 ,  C07C5/3335 ,  C10G51/023

    摘要： An integrated fluid coking/paraffin dehydrogenation process. The fluid coking unit is comprised of a fluid coker reactor, a heater, and a gasifier. Solids from the fluidized beds are recycled between the coking zone and the heater and between the heater and the gasifier. A separate stream of hot solids from the gasifier is passed to the scrubbing zone after first being reduced in temperature by introduction of an effective amount of diluent, such as steam. A light paraffin stream is introduced into this stream of hot solids between the point where the diluent is added and the scrubbing zone. The hot particles act to catalyze the dehydrogenation of paraffins to olefins.

    摘要翻译： 综合流体焦化/石蜡脱氢工艺。 流体焦化装置由流体焦化反应器，加热器和气化器组成。 来自流化床的固体在焦化区和加热器之间以及加热器和气化器之间循环。 在通过引入有效量的稀释剂如蒸汽首先降低温度后，来自气化器的单独的热固体物流被传送到洗涤区。 在添加稀释剂的点和洗涤区之间，将轻质石蜡流引入该热固体物流中。 热颗粒起催化链烷烃脱氢成烯烃作用。

    High surface purity heat transfer solids for high temperature fluidized bed reactions
    8.
    发明授权
    High surface purity heat transfer solids for high temperature fluidized bed reactions 失效
    高表面纯度的传热固体用于高温流化床反应

    公开(公告)号：US5360778A

    公开(公告)日：1994-11-01

    申请号：US60378

    申请日：1993-05-11

    申请人： Stephen M. Davis ,  LeRoy R. Clavenna ,  Geoffrey R. Say ,  Rocco A. Fiato

    发明人： Stephen M. Davis ,  LeRoy R. Clavenna ,  Geoffrey R. Say ,  Rocco A. Fiato

    IPC分类号： B01J8/00 ,  C01B3/44 ,  C01B13/14 ,  C01F7/02 ,  C01F7/46 ,  B01J20/02 ,  B01J20/30 ,  B01J21/02

    CPC分类号： C01B3/44 ,  B01J8/008 ,  C01B13/145 ,  C01F7/02 ,  C01F7/46 ,  C01P2002/85 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2006/80 ,  Y02P20/52

    摘要： High surface purity heat transfer solids are formed, suitably by washing and treating particulate refractory inorganic solids, notably alumina, which contains as impurities up to about 0.5 wt. % silicon and/or up to about 500 wppm boron, with an acid, or dilute acid solution sufficient to reduce the concentration of silicon and boron in the outer peripheral surface layer of the particles, e.g., as measured inwardly toward the center of a particle to a depth of about 50 .ANG. using X-ray photoelectron spectroscopy, to no greater than about 5 atom percent silicon and boron, preferably about 2 atom percent silicon and boron, based on the total number of cations within said outer peripheral surface layer, thereby reducing the tendency of said particles to sinter and agglomerate in the conversion of said hydrocarbon to hydrogen and carbon monoxide in a fluidized bed synthesis gas operation vis-a-vis particles otherwise similar except that the particles are not treated with the acid. The tendency of the particles to sinter and agglomerate is further reduced by the additional removal of sodium, iron, calcium, and titanium impurities from the outer peripheral surface layer of the particles. Preferably the latter named impurities, or impurities other than silicon and boron, are reduced to a concentration below about 20 atom %, more preferably to a concentration below about 15 atom %, in the outer surface layer of the particles.

    摘要翻译： 适当地通过洗涤和处理颗粒耐火无机固体，特别是氧化铝来形成高表面纯度的热传递固体，其含有高达约0.5wt。 ％硅和/或高达约500wppm的硼，与酸或稀酸溶液相比足以降低颗粒外周表面层中硅和硼的浓度，例如向内朝向颗粒中心测量 基于所述外周表面层中的阳离子总数，使用X射线光电子能谱测量至约50AHZ的深度，不大于约5原子％的硅和硼，优选约2原子％的硅和硼，由此 降低了所述颗粒在流化床合成气操作中将所述烃转化为氢气和一氧化碳的过程中所述颗粒烧结和附聚的倾向，除了颗粒不用酸处理之外，颗粒否则相似。 通过从颗粒的外周表面层另外去除钠，铁，钙和钛杂质，进一步降低了颗粒烧结和附聚的倾向。 优选地，后者称为杂质或除了硅和硼之外的杂质，在颗粒的外表面层中被还原成低于约20原子％，更优选低于约15原子％的浓度。

    Process for the reactivation of nickel-alumina catalysts
    9.
    发明授权
    Process for the reactivation of nickel-alumina catalysts 失效
    镍 - 氧化铝催化剂再活化方法

    公开(公告)号：US5356845A

    公开(公告)日：1994-10-18

    申请号：US60333

    申请日：1993-05-11

    申请人： LeRoy R. Clavenna ,  Stephen M. Davis ,  Brent E. Beasley

    发明人： LeRoy R. Clavenna ,  Stephen M. Davis ,  Brent E. Beasley

    IPC分类号： B01J23/94 ,  B01J38/06 ,  C01B3/40 ,  C01B3/44 ,  B01J38/72 ,  B01J21/20 ,  C10J3/46

    CPC分类号： B01J23/94 ,  B01J38/06 ,  C01B3/40 ,  C01B3/44 ,  C01B2203/1052 ,  Y02P20/52 ,  Y02P20/584 ,  Y10S502/516

    摘要： A process for the reactivation, or rejuvenation of a nickel-alumina catalyst employed in the production of a gas comprised of an admixture of hydrogen and carbon monoxide, or synthesis gas, by the conversion, in a reactor, or reaction zone, of light hydrocarbons in a fluidized bed of the catalyst at elevated temperature, in the presence of steam and oxygen. Catalyst reactivation is accomplished by withdrawing a portion of the catalyst from the fluidized bed of the reactor and treating the catalyst in an oxidation zone at temperature sufficient to oxidize and convert the nickel component of the catalyst to nickel aluminate and disperse said nickel aluminate within the alumina support, and then recycling the treated catalyst to the reactor, or reaction zone, to reactivate and increase the activity of the catalyst. The catalyst, on reduction in the reactor, or reaction zone, is provided an additional boost in activity by washing, treating or contacting the catalyst from the elevated temperature oxidation zone with an acid sufficient to remove trace impurities without removing any substantial amount of the nickel aluminate, and without forming a residue on the catalyst surface. The normal tendency of the catalyst to agglomerate at reaction conditions is also reduced by the acid treatment.

    摘要翻译： 一种用于生产由氢和一氧化碳的混合气体组成的气体或通过在反应器或反应区中转化的轻烃的合成气的镍 - 氧化铝催化剂的再活化或再生的方法 在催化剂的流化床中，在升高的温度下，在蒸汽和氧气的存在下。 催化剂再活化是通过从反应器的流化床中取出一部分催化剂并在氧化区中处理催化剂，该温度足以氧化并将催化剂的镍组分转化为铝酸镍，并将所述铝酸镍分散在氧化铝 支撑物，然后将经处理的催化剂再循环到反应器或反应区，以重新活化并增加催化剂的活性。 催化剂在还原反应器或反应区中的活性通过从高温氧化区洗涤，处理或接触催化剂而提供额外的活性提高，该酸足以除去痕量杂质而不除去任何相当大量的镍 铝酸盐，并且不在催化剂表面上形成残余物。 催化剂在反应条件下凝聚的正常趋势也通过酸处理降低。

    FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds
    10.
    发明授权
    FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds 失效
    FCC用于从高氢和低氮和芳香的饲料生产低排放燃料

    公开(公告)号：US5318693A

    公开(公告)日：1994-06-07

    申请号：US982931

    申请日：1992-11-30

    申请人： Stephen M. Davis ,  William E. Winter

    发明人： Stephen M. Davis ,  William E. Winter

    IPC分类号： C10G11/05 ,  C01G11/05 ,  C01G11/18

    CPC分类号： C10G11/05

    摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is relatively low in nitrogen and aromatics and high in hydrogen content and the catalyst is an amorphous silica-alumina containing a separate surface silica phase. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.

    摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮和芳族化合物相对较低，氢含量高，催化剂是含有单独的表面二氧化硅相的无定形二氧化硅 - 氧化铝。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2+环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。