摘要:
A binder for an electrode of a fuel cell is a basic polymer including a nitrogen-containing functional group and a proton conductive polymer having a phosphoric acid impregnation capacity of 200 wt % or less. An electrode for a fuel cell includes the binder and a catalyst, and a fuel cell includes the electrode. The electrode is manufactured by mixing the binder, a catalyst, and a solvent; and coating the mixture on a carbon support and heat-treating the coated mixture. The binder has excellent proton conductivity by having a phosphoric acid impregnation capacity of 200 wt % or less, and has improved durability without membrane damage and micro-structural changes due to swelling, which occurs when PBI is used as a binder. Accordingly, an electrode including the binder has improved phosphoric acid retention capacity, and increased wetting velocity. Thus, a fuel cell having improved efficiency can be manufactured due to the improved proton conductivity and durability of the electrode.
摘要:
A method for preparing a metal catalyst includes a proton conductive material coating layer formed on the surface of a conductive material. Also, an electrode may be prepared using the metal catalyst. The method for preparing the metal catalyst comprises mixing the conductive catalyst material, the proton conductive material, and a first solvent, casting the mixture onto a supporting layer and drying the mixture to form a conductive catalyst containing film. The method further comprises separating the conductive catalyst containing film from the supporting layer and pulverizing the conductive catalyst containing film to obtain the metal catalyst. The method for preparing the electrode comprises mixing the metal catalyst with a hydrophobic binder and a second solvent, coating the mixture on an electrode support, and drying it.
摘要:
Provided are an additive to an electrode for a fuel cell that is a proton conductive compound having at least one phosphate group, an electrode for a fuel cell including the same, a method of manufacturing the electrode for a fuel cell, and a fuel cell using the electrode. The additive to an electrode for a fuel cell improves the durability of a fuel cell and reduces the amount of phosphoric acid discharged during operation of the fuel cell by fixing the phosphoric acid. Accordingly, a fuel cell having improved efficiency may be prepared using the additive because of improved proton conductivity and durability.
摘要:
A method for preparing a metal catalyst includes a proton conductive material coating layer formed on the surface of a conductive material. Also, an electrode may be prepared using the metal catalyst. The method for preparing the metal catalyst comprises mixing the conductive catalyst material, the proton conductive material, and a first solvent, casting the mixture onto a supporting layer and drying the mixture to form a conductive catalyst containing film. The method further comprises separating the conductive catalyst containing film from the supporting layer and pulverizing the conductive catalyst containing film to obtain the metal catalyst. The method for preparing the electrode comprises mixing the metal catalyst with a hydrophobic binder and a second solvent, coating the mixture on an electrode support, and drying it.
摘要:
A catalyst composition including a proton conductive metal oxide, and a fuel cell employing an electrode using the same. The proton conductivity of an electrode catalyst layer and distribution of a phosphoric acid electrolyte are enhanced, and thus the performance of the fuel cell is enhanced.
摘要:
A metal catalyst including a conductive catalyst material and a coating layer formed of a water repellent material on the conductive catalyst material, an electrode including the metal catalyst, and a fuel cell employing the electrode. By forming the coating layer, having a water repellent material, on the conductive catalyst material, the metal catalyst does not sink in the liquid electrolyte, the distribution and movement of the liquid electrolyte around the metal catalyst can be controlled, and the thickness of the interface between the metal catalyst and the liquid electrolyte can be regulated. Accordingly, an ideal electrode structure having triple phase boundary for electrochemical reaction can be formed. A fuel cell employing an electrode including the metal catalyst has excellent efficiency and overall performance.
摘要:
A solid proton conductor for a fuel cell and a fuel cell employing the solid proton conductor, the solid proton conductor including a sulfonated polymer, and a hydrophilic polymer having an acid group, constituting a polymer solvent, providing a proton mobile path.
摘要:
A method for preparing a metal catalyst includes a proton conductive material coating layer formed on the surface of a conductive material. Also, an electrode may be prepared using the metal catalyst. The method for preparing the metal catalyst comprises mixing the conductive catalyst material, the proton conductive material, and a first solvent, casting the mixture onto a supporting layer and drying the mixture to form a conductive catalyst containing film. The method further comprises separating the conductive catalyst containing film from the supporting layer and pulverizing the conductive catalyst containing film to obtain the metal catalyst. The method for preparing the electrode comprises mixing the metal catalyst with a hydrophobic binder and a second solvent, coating the mixture on an electrode support, and drying it.
摘要:
A proton conductor for a fuel cell, an electrode for a fuel cell that includes the proton conductor, and a fuel cell including the electrode of which the proton conductor includes a phosphoric acid-based material, and a C1-C20 ammonium perfluoroalkylsulfonate dissolved in the phosphoric acid-based material.
摘要:
Provided are an additive to an electrode for a fuel cell that is a proton conductive compound having at least one phosphate group, an electrode for a fuel cell including the same, a method of manufacturing the electrode for a fuel cell, and a fuel cell using the electrode. The additive to an electrode for a fuel cell improves the durability of a fuel cell and reduces the amount of phosphoric acid discharged during operation of the fuel cell by fixing the phosphoric acid. Accordingly, a fuel cell having improved efficiency may be prepared using the additive because of improved proton conductivity and durability.