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公开(公告)号：US06482524B1
公开(公告)日：2002-11-19
申请号：US09036927
申请日：1998-03-09
IPC分类号： B32B1706
CPC分类号： C04B41/009 , B05D1/185 , B05D3/10 , B05D5/083 , C03C17/34 , C03C17/3405 , C03C17/42 , C03C2217/76 , C04B41/52 , C04B41/89 , C04B2111/20 , C04B2111/27 , C09K3/18 , C23C26/00 , C23C30/00 , Y10T428/24355 , Y10T428/24364 , Y10T428/31612 , Y10T428/31667 , C04B41/4933 , C04B41/524 , C04B41/4961 , C04B41/522 , C04B41/455 , C04B33/00 , C04B35/00
摘要： For obtaining a substrate on the surface of which a water repellent film is firmly bonded through an undercoating film, and which shows a low critical inclination angle, superior durability, and high density, a water repellent and/or oil repellent film layer is formed by using a liquid for undercoating treatment. The liquid for undercoating treatment is obtained by dissolving and reacting a material having chlorosilyl radicle radicle in molecular form therein and is dissolved into an alcohol group solvent, so that a surface roughness (Ra) of less than 0.5 nm is obtained, thereby achieving high durability and a low critical inclination angle.
摘要翻译： 为了获得其表面上的基材，通过底涂膜牢固地粘合防水膜，并且显示出低临界倾斜角，优异的耐久性和高密度，通过以下方式形成防水和/或防油膜层： 使用液体进行底涂处理。 用于底涂处理的液体是通过将具有分子形式的具有氯甲硅烷基辐射体的材料溶解并反应并溶解在醇基溶剂中而获得的，从而获得小于0.5nm的表面粗糙度（Ra），从而获得高耐久性 和低临界倾角。
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公开(公告)号：US6001485A
公开(公告)日：1999-12-14
申请号：US970671
申请日：1997-11-14
CPC分类号： C03C17/42 , C03C2217/76
摘要： This invention provides a water repellant glass plate for vehicles or buildings, which shows a long-term durability. The water repellant glass plate includes a primer layer on a glass substrate, consisting essentially of silicon oxide in which oxygen atoms are partially substituted by hydroxyl groups, at a thickness between 10 nm and 100 nm, and a second layer on the first layer consisting of an organic silicon compound including a fluoroalkyl group at a thickness between about 0.2 nm and about 40 nm.
摘要翻译： 本发明提供一种车辆或建筑物的防水玻璃板，其具有长期的耐久性。 防水玻璃板包括在玻璃基板上的底漆层，其基本上由其中氧原子被羟基部分取代的氧化硅组成，厚度为10nm至100nm，第一层上的第二层由 包含厚度在约0.2nm至约40nm之间的氟代烷基的有机硅化合物。
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公开(公告)号：US5318931A
公开(公告)日：1994-06-07
申请号：US832582
申请日：1992-02-07
CPC分类号： C03C4/085 , C03C3/095 , Y10S501/904 , Y10S501/905
摘要： Glass for vehicles comprising from 65 to 80% by weight of SiO.sub.2, from 0 to 5% by weight of Al.sub.2 O.sub.3, from 0 to 5% by weight B.sub.2 O.sub.3, from 0 to 10% by weight of MgO, from 5 to 15% by weight of CaO, from 10 to 18% by weight of Na.sub.2 O, from 0 to 5% by weight of K.sub.2 O, from 5 to 15% by weight in total of MgO and CaO, from 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, from 0.1 to 1% by weight of cerium oxide in terms of CeO.sub.2, from 0.2 to 0.6% by weight of iron oxide in terms of Fe.sub.2 O.sub.3, from 0 to 0.005% by weight of CoO, from 0 to 0.01% by weight of NiO, and from 0.0005 to 0.005% by weight of Se, and glass for vehicles comprising from 65 to 80% by weight of SiO.sub.2, from 0 to 5% by weight of Al.sub.2 O.sub.3, from 0 to 5% by weight of B.sub.2 O.sub.3, from to 10% by weight of MgO, from 5 to 15% by weight of CaO, from 10 to 18% by weight of Na.sub.2 O, from 0 to 5% by weight of K.sub.2 O, from 5 to 15% by weight in total of MgO and CaO, from 10 to 18% by weight in total of Na.sub.2 O and K.sub.2 O, from 0.1 to 1% by weight of cerium oxide in terms of CeO.sub.2, from 0 to 1% by weight of TiO.sub.2, from 0.2 to 0.6% by weight of iron oxide in terms of Fe.sub.2 O.sub.3, from 0 to 0.005% by weight of CoO, from 0 to 0.01% by weight of NiO, and from 0.0005 to 0.005% by weight of Se. The glass is gray-tinted while exhibiting excellent ultraviolet and heat absorption.
摘要翻译： 用于车辆的玻璃包含65至80重量％的SiO 2，0至5重量％的Al 2 O 3，0至5重量％的B 2 O 3，0至10重量％的MgO，5至15重量％ 的CaO，10〜18重量％的Na 2 O，0〜5重量％的K 2 O，5〜15重量％的MgO和CaO，10〜20重量％的Na 2 O和K 2 O ，以CeO 2为0.1〜1重量％的氧化铈，以Fe 2 O 3换算为0.2〜0.6重量％的氧化铁，0〜0.005重量％的CoO，0〜0.01重量％的NiO 和0.0005〜0.005重量％的Se，车辆用玻璃包含65〜80重量％的SiO 2，0〜5重量％的Al 2 O 3，0〜5重量％的B 2 O 3，10重量％ 5重量％的MgO，5〜15重量％的CaO，10〜18重量％的Na 2 O，0〜5重量％的K 2 O，5〜15重量％的MgO和CaO， 总计为10至18重量％的Na 2 O和K 2 O，0.1至1重量％的氧化铈，以C计 eO 2，0至1重量％的TiO 2，0.2至0.6重量％的以Fe 2 O 3计的氧化铁，0至0.005重量％的CoO，0至0.01重量％的NiO和0.0005 至0.005重量％的Se。 玻璃是灰色的，同时具有优异的紫外线和吸热性。
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4.发明授权Sulfur-modified chloroprene rubber, molded article, and method for producing sulfur-modified chloroprene rubber 有权硫改性氯丁橡胶，成型品和硫改性氯丁橡胶的制造方法公开(公告)号：US09080019B2
公开(公告)日：2015-07-14
申请号：US14004478
申请日：2012-05-16
申请人： Takashi Sunada , Naoki Kobayashi , Yasushi Abe
发明人： Takashi Sunada , Naoki Kobayashi , Yasushi Abe
摘要： This invention provides a means to produce improved sulfur-modified chloroprene rubber for use in making products with improved heat resistance. The products of the invention require sulfurization of the chloroprene followed by plasticization. A preferred plasticizer is tetraethylthiuram.
摘要翻译： 本发明提供一种生产改进的硫改性氯丁二烯橡胶的方法，用于制造具有改进的耐热性的产品。 本发明的产品需要氯丁二烯的硫化，然后进行增塑。 优选的增塑剂是四乙基秋兰姆。
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5.发明授权公开(公告)号：US06511753B1
公开(公告)日：2003-01-28
申请号：US09701752
申请日：2000-12-01
IPC分类号： B32B904
CPC分类号： C09K3/18 , C09D4/00 , Y02P20/582 , Y10T428/31612 , Y10T428/31663 , C08G77/24 , C08G77/04
摘要： In a process for producing a product coated with a water repellent film which comprises applying on a base substrate a coating liquid containing a silicon alkoxide, a fluoroalkyl group-containing silane compound and an acid dissolved in a solvent and drying; the process for producing a product coated with a water repellent film being characterized in that said coating liquid contains: said silicon alkoxide or a hydrolysate thereof is present at a concentration equivalent to 0.01 to 2% by weight of silica formed by hydrolysis of the silicon alkoxide, said fluoroalkyl group-containing silane compound is present at a concentration equivalent to 0.00001 to 0.15% by weight of silica formed by hydrolysis of the fluoroalkyl group-containing silane compound, 0.003-3 normality of said acid, and 0-20% by weight of water. The invention further provides water repellent products having a good rolling properly of water drops, a high scratching resistance and a high weatherability prepared by the process of the invention.
摘要翻译： 一种涂布防水膜的制品的制造方法，其特征在于，在基材上涂布含有硅醇盐，含氟烷基的硅烷化合物和溶解在溶剂中的酸的涂布液，并干燥; 制造涂覆有防水膜的产品的方法的特征在于所述涂布液含有：所述硅醇盐或其水解产物的存在浓度相当于通过硅醇盐的水解形成的二氧化硅的0.01至2重量％ 所述含氟代烷基的硅烷化合物的存在浓度相当于通过含氟烷基的硅烷化合物的水解形成的二氧化硅的0.00001〜0.15重量％，所述酸的平均值为0.003〜3，0〜20重量％ 的水。 本发明还提供了具有良好的水滴轧制性，耐刮擦性和通过本发明的方法制备的高耐候性的防水产品。
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公开(公告)号：US6156409A
公开(公告)日：2000-12-05
申请号：US117541
申请日：1998-08-06
CPC分类号： B32B27/14 , C03C17/007 , C03C17/23 , C03C17/25 , C03C17/42 , C09K3/18 , C03C2217/45 , C03C2217/475 , C03C2217/77 , Y10T428/24355 , Y10T428/24372 , Y10T428/24421 , Y10T428/256 , Y10T428/259
摘要： The present invention is to provide an anti-fogging article which is excellent in durability, wear resistance, anti-fogging property and anti-fogging substainability property, wherein the same is an anti-fogging article in which a film having a metal oxide fine particles having a grain size from 4 through 300 nm and having metal oxides used as its matrix is coated on a substrate and dents and projections having an arithmetical mean roughness (Ra) from 1.5 to 80 nm and their mean interval (Sm) from 4 to 300 nm are formed on the abovementioned film surface, as necessary, the corresponding film contains a surface-active agent and a phosphate compound, and further as necessary, organosilane or its hydrolyzed substance containing in the molecule at least a functional group which is selected from a group consisting of polyalkylene oxide group, alkyl group, alkenyl group, and aryl group is covered on the corresponding dents and projections, and further as necessary, a surface-active agent layer is secured thereon or on the corresponding dents and projections.
摘要翻译： PCT No.PCT / JP97 / 04494 Sec。 371日期1998年8月6日 102（e）1998年8月6日PCT PCT 1997年12月8日PCT公布。 公开号WO98 / 25761 日期：1998年6月18日本发明提供耐久性，耐磨性，防雾性和防雾性能特性优异的防雾制品，其中，防雾制品中具有 将具有4〜300nm的粒径为金属氧化物作为基体的金属氧化物微粒子涂布在基板上，并将具有1.5〜80nm的算术平均粗糙度（Ra）的平均间隔（Sm） ）在上述膜表面上形成，根据需要，相应的膜含有表面活性剂和磷酸盐化合物，并且还根据需要，在分子中至少含有官能团的有机硅烷或其水解物质 选自聚环氧烷基，烷基，烯基和芳基的基团，在相应的凹部和突起上被覆盖，进一步根据需要覆盖表面 e活性剂层固定在其上或相应的凹陷和突起上。
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7.发明授权
公开(公告)号：US6033738A
公开(公告)日：2000-03-07
申请号：US103543
申请日：1998-06-24
CPC分类号： C03C17/30 , C09K3/18 , Y10T428/31663
摘要： Water-repellent articles having an excellent water repellency, particularly water-repellent articles having a great contact angle with respect to waterdrop, an excellent waterdrop rollability, a high scuff resistance and a high weathering resistance, a method for producing the water-repellent articles, and a solution for forming a water-repellent film are dsiclosed. A novel method for producing water-repellent articles is provided, which comprises dissolving a chlorosilyl group-containing compound and a fluoroalkyl group-containing silane compound in a solvent containing an alcohol and/or water content to obtain a solution having the chloro group in said chlorosilyl group-containing compound substituted by an alkoxyl group or hydroxyl group, applying said solution to the surface of a substrate, and then drying the coated material to form a water-repellent film.
摘要翻译： 具有优异的防水性的防水制品，特别是相对于水滴具有大的接触角的防水制品，优异的水滴滚动性，高耐擦伤性和高耐候性，用于制造防水制品的方法， 并且用于形成防水膜的溶液被分离。 提供一种生产防水制品的新方法，其包括将含有氯甲硅烷基的化合物和含氟代烷基的硅烷化合物溶解在含有醇和/或水含量的溶剂中，以获得在所述溶剂中具有氯基团的溶液 被烷氧基或羟基取代的含氯甲硅烷基的化合物，将所述溶液施加到基材的表面，然后干燥涂覆的材料以形成拒水膜。
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公开(公告)号：US5264400A
公开(公告)日：1993-11-23
申请号：US959796
申请日：1992-10-13
CPC分类号： C03C3/095 , C03C4/085 , Y10S501/904 , Y10S501/905 , Y10T428/266
摘要： Glass for vehicles comprising from 65 to 80% by weight of SiO.sub.2, from 0 to 5% by weight of Al.sub.2 O.sub.3, from 0 to 5% by weight of B.sub.2 O.sub.3, from 0 to 10% by weight of MgO, from 5 to 15% by weight of CaO, from 10 to 18% by weight of Na.sub.2 O, from 0 to 5% by weight of K.sub.2 O, from 5 to 15% by weight in total of MgO and CaO, from 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, from 0.1 to 1% by weight of cerium oxide in terms of CeO.sub.2, from 0.2 to 0.6% by weight of iron oxide in terms of Fe.sub.2 O.sub.3, from 0 to 0.005% by weight of CoO, from 0 to 0.01% by weight of NiO, from 0.2 to 3% by weight of Er.sub.2 O.sub.3, and from 0.0003 to 0.005% by weight of Se. The glass assumes bronze while exhibiting excellent ultraviolet and heat absorption.
摘要翻译： 用于车辆的玻璃包含65至80重量％的SiO 2，0至5重量％的Al 2 O 3，0至5重量％的B 2 O 3，0至10重量％的MgO，5至15重量％ CaO的重量，10〜18重量％的Na 2 O，0〜5重量％的K 2 O，5〜15重量％的MgO和CaO，10〜20重量％的Na 2 O和 K 2 O，0.1至1重量％的氧化铈，以CeO 2计，0.2至0.6重量％的氧化铁，换算成Fe 2 O 3，0至0.005重量％的CoO，0至0.01重量％ NiO，0.2〜3重量％的Er2O3，0.0003〜0.005重量％的Se。 玻璃呈青铜色，同时具有优异的紫外线和吸热性。
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公开(公告)号：US5241558A
公开(公告)日：1993-08-31
申请号：US849584
申请日：1992-03-11
申请人： Yukihito Nagashima , Kouichi Sakaguchi , Shigeki Nakagaki , Seiichiro Manabe , Yoshiyuki Inaka , Takashi Sunada , Hiroyuki Tanaka
发明人： Yukihito Nagashima , Kouichi Sakaguchi , Shigeki Nakagaki , Seiichiro Manabe , Yoshiyuki Inaka , Takashi Sunada , Hiroyuki Tanaka
CPC分类号： C03B5/0336 , C03B5/1875
摘要： A vertical glass melting furnace of the type having an inlet for raw materials at the top thereof, an outlet for molten glass at the bottom thereof, and a tabular electric resistance heating element for melting which is immersed at some level in molten glass, has at least one opening, and covers almost entirely the cross-section of the furnace at that level, the vertical glass melting furnace comprising a stirrer which extends from above the furnace and passes through the batch layer and the tabular heating element so that the stirrer brings about forced circulation for homogenization of the molten glass which has passed through the tabular heating element and stays in the region below the tabular heating element.
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10.发明申请SULFUR-MODIFIED CHLOROPRENE RUBBER, MOLDED ARTICLE, AND METHOD FOR PRODUCING SULFUR-MODIFIED CHLOROPRENE RUBBER 有权硫改性氯仿橡胶，成型制品和用于生产硫改性氯仿橡胶的方法公开(公告)号：US20140005354A1
公开(公告)日：2014-01-02
申请号：US14004478
申请日：2012-05-16
申请人： Takashi Sunada , Naoki Kobayashi , Yasushi Abe
发明人： Takashi Sunada , Naoki Kobayashi , Yasushi Abe
IPC分类号： C08G75/14
摘要： Provided are a sulfur-modified chloroprene rubber improved in heat resistance, a molded article prepared by using the sulfur-modified chloroprene rubber and a method for producing the sulfur-modified chloroprene rubber.A sulfur-modified chloroprene rubber comprising, as the principal component, a sulfur-modified chloroprene polymer having sulfur atoms in the molecule which is obtained by emulsion polymerization of chloroprene alone or a mixture of chloroprene and one or more other monomers in the presence of sulfur, wherein the content of the sulfur that is bound to the sulfur-modified chloroprene polymer is 0.2 to 0.6 mass % with respect to the total amount of the rubber and the ratio of the amount of the bound sulfur (mass %) to the total amount of the sulfur contained in the entire rubber (mass %) (bound sulfur content/total sulfur content) is 0.28 to 0.5. The sulfur-modified chloroprene rubber according to the present invention can be used favorably for molded articles such as transmission belts and conveyer belts for use in industries in general, antivibration rubbers, air springs for automobiles, hoses and sponges.
摘要翻译： 提供了耐热性提高的硫改性氯丁橡胶，使用硫改性氯丁二烯橡胶制备的成型体和硫改性氯丁二烯橡胶的制造方法。 一种硫改性氯丁二烯橡胶，其包含在分子中具有硫原子的硫改性氯丁二烯聚合物作为主要组分，其通过在硫存在下单独氯丁橡胶或氯丁二烯与一种或多种其它单体的混合物的乳液聚合而获得 其中与硫改性氯丁二烯聚合物结合的硫的含量相对于橡胶的总量为0.2〜0.6质量％，并且结合的硫的量（质量％）与总量的比例 的全部橡胶中所含的硫（质量％）（结合硫含量/总硫含量）为0.28〜0.5。 根据本发明的硫改性氯丁二烯橡胶可以有利地用于诸如用于一般工业中的传动带和传送带的模塑制品，防振橡胶，用于汽车的空气弹簧，软管和海绵。
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