Process for operating a gas generator
    2.
    发明授权
    Process for operating a gas generator 失效
    用于操作气体发生器的过程

    公开(公告)号:US4676805A

    公开(公告)日:1987-06-30

    申请号:US707719

    申请日:1985-03-04

    Abstract: A method is provided for turning down from design conditions or below the output of raw product gas from a free-flow partial oxidation gas generator, or when operating below design conditions the output of raw product gas from the gas generator may be turned up while maintaining substantially constant the efficiency of the gas generation, or conversion of the fuel to gas, and the quality of the gas produced. The flow rates of the feedstreams to the burner are adjusted down or up a predetermined amount for each of the feedstreams to the burner to obtain a specified output of raw product gas while maintaining substantially constant in the reaction zone the levels of O/C atomic ratio and the H.sub.2 O/fuel weight ratio. Further, a pressure adjustment in the system is made which produces a corresponding adjustment to the pressure in the gas generator. The adjusted pressure is a direct function of the adjusted flow rate for the adjusted fuel or oxidant feedstream.

    Abstract translation: 提供了一种用于从设计条件或低于原料气体从自由流动部分氧化气体发生器输出的方法,或者当在设计条件下操作时,来自气体发生器的原料气体的输出可以在保持 气体产生的效率基本上恒定,或燃料转化为气体,以及产生的气体的质量。 将进入燃烧器的进料流的流量向着燃烧器的每个进料流向下或向上调节预定量,以获得原始产物气体的特定输出,同时在反应区域保持基本上恒定的O / C原子比 和H2O /燃料重量比。 此外,进行系统中的压力调节,其对气体发生器中的压力进行相应的调整。 调节压力是调整后的燃料或氧化剂进料流的调节流量的直接函数。

    Production of clean synthesis or fuel gas
    4.
    发明授权
    Production of clean synthesis or fuel gas 失效
    生产清洁合成或燃气

    公开(公告)号:US4007017A

    公开(公告)日:1977-02-08

    申请号:US643069

    申请日:1975-12-22

    Abstract: An improved continuous partial oxidation process for producing clean synthesis or fuel gas from a hydrocarbonaceous fuel feed is disclosed wherein the effluent gas stream from the reaction zone of the gas generator is simultaneously cooled and cleaned by first discharging the gas stream directly into a relatively large body of hot liquid hydrocarbon immersion fluid contained in an immersion vessel, and second by scrubbing with by-product water obtained subsequently in the process in a nozzle scrubber. The process gas stream is optionally cooled and passed into a gas-liquid separator where any condensed by-product noxious water and any C.sub.5 -C.sub.10 liquid hydrocarbons are separated from each other and from the clean product gas stream. By-product noxious water is disposed of without polluting the environment by recycling a portion of it to the gas generator as the temperature moderator. For example, the immersion fluid may be a dispersion of liquid hydrocarbonaceous fuel such as petroleum oil and particulate carbon which is contained in a separate immersion vessel. A portion of the hot immersion fluid is continuously removed from the immersion vessel and is cooled in an external gas cooler to a temperature in the range of about 300.degree. to 850.degree. F but above the dew point of the water in the process gas stream. Portions of the cooled immersion fluid are recycled to the immersion vessel, and optionally to the gas generator as at least a portion of the hydrocarbonaceous fuel feed. In another embodiment, a portion of the immersion fluid removed from the immersion vessel may be introduced into the gas generator as at least a portion of the feed without first being passed through a cooler. The clean product gas comprises H.sub.2, CO, CO.sub.2, H.sub.2 O and, optionally at least one material from the group H.sub.2 S, COS, N.sub.2, A, and C.sub.1 -C.sub.4 hydrocarbons.

    Abstract translation: 公开了一种用于从烃类燃料进料中产生清洁合成或燃料气体的改进的连续部分氧化方法,其中来自气体发生器的反应区的流出气体流同时被冷却和清洁,首先将气流直接排放到相对大的体内 包含在浸没容器中的热液体烃浸液,其次通过在喷嘴洗涤器中随后在该方法中获得的副产物水进行洗涤。 任选地将工艺气流冷却并进入气液分离器,其中任何冷凝的副产物有害水和任何C5-C10液体烃彼此分离,并且与清洁产物气流分离。 通过将副产物的一部分再循环到作为温度调节剂的气体发生器中,副产物有害水被处理而不污染环境。 例如,浸渍流体可以是液体烃类燃料如石油和分散在容器中的颗粒状碳的分散体。 热浸液体的一部分从浸没容器中连续地取出,并在外部气体冷却器中冷却至约300-850°F,但高于工艺气体流中的水的露点。 冷却的浸没流体的一部分被再循环到浸没容器中,并且任选地再循环到作为含烃燃料进料的至少一部分的气体发生器。 在另一个实施例中,从浸没容器移除的浸渍流体的一部分可以作为进料的至少一部分被引入到气体发生器中,而不首先通过冷却器。 清洁产品气体包括H 2,CO,CO 2,H 2 O和任选的至少一种来自H 2 S,COS,N 2,A和C 1 -C 4烃的材料。

    Production of clean synthesis or fuel gas
    8.
    发明授权
    Production of clean synthesis or fuel gas 失效
    生产清洁合成或燃气

    公开(公告)号:US4007019A

    公开(公告)日:1977-02-08

    申请号:US643561

    申请日:1975-12-22

    Abstract: An improved continuous partial oxidation process for producing clean synthesis or fuel gas and by-product steam from a hydrocarbonaceous fuel feed is disclosed wherein hot gases from the process are simultaneously cooled and cleaned by direct contact with hydrocarbon oil. Thus, the effluent gas stream from the reaction zone of the gas generator is cooled and cleaned by discharging the gas stream directly into a relatively large body of hot liquid hydrocarbon immersion fluid. For example, the immersion fluid may be a dispersion of liquid hydrocarbonaceous fuel such as petroleum oil and particulate carbon which is contained in a separate immersion vessel. A portion of the hot immersion fluid is continuously removed from the immersion vessel and cooled to a temperature in the range of about 300.degree. to 850.degree. F. but above the dew point of the water in the process gas stream in an external heat exchanger, such as a steam generator. High pressure by-product steam may be produced thereby. A portion of the cooled immersion fluid, optionally in admixture with a hydrocarbonaceous scrubbing fluid of a similar composition obtained subsequently in the process may be recycled to the immersion vessel and optionally to the gas generator as at least a portion of the hydrocarbonaceous fuel feed.

    Abstract translation: 公开了一种改进的连续部分氧化工艺,用于从烃类燃料进料中产生清洁合成或燃料气体和副产物蒸汽,其中来自该方法的热气体同时被冷却并通过与烃油直接接触来清洁。 因此,来自气体发生器的反应区的废气流通过将气流直接排放到较大体积的热液体烃浸液中来进行冷却和清洗。 例如,浸渍流体可以是液体烃类燃料如石油和分散在容器中的颗粒状碳的分散体。 热浸液体的一部分从浸没容器中连续地取出并冷却到约300-850°F的范围内,但高于外部热交换器中工艺气流中的水的露点, 例如蒸汽发生器。 因此可能产生高压副产物蒸汽。 冷却的浸没流体的一部分,任选地与随后在该方法中获得的类似组合物的烃类洗涤流体混合可以再循环到浸没容器中,并任选地再循环到作为至少一部分烃类燃料进料的气体发生器。

    Production of clean synthesis or fuel gas
    9.
    发明授权
    Production of clean synthesis or fuel gas 失效
    生产清洁合成或燃气

    公开(公告)号:US4007018A

    公开(公告)日:1977-02-08

    申请号:US643458

    申请日:1975-12-22

    Abstract: An improved continuous partial oxidation process for producing clean synthesis or fuel gas from a hydrocarbonaceous fuel feed is disclosed wherein hot gases from the process are simultaneously cooled and cleaned by direct contact with hydrocarbon oil. Thus, the effluent gas stream from the reaction zone of the gas generator is cooled and cleaned by discharging the gas stream directly into a relatively large body of hot liquid hydrocarbon immersion fluid. For example, the immersion fluid may be a dispserion of liquid hydrocarbonaceous fuel such as petroleum oil and particulate carbon which is contained in a separate immersion vessel. A portion of the immersion fluid is continuously removed from the immersion vessel and is cooled in an external cooler to a temperature in the range of about 300 to 850.degree. F but above the dew point of the water in the process gas stream. Portions of the cooled immersion fluid optionally in admixture with scrubbing fluid obtained subsequently in the process are recycled to the immersion vessel, and optionally to the gas generator as at least a portion of the hydrocarbonaceous fuel feed. In another emnbodiment, a portion of the immersion fluid removed from the immersion vessel may be introduced into the gas generator as at least a portion of the feed without first being passed through a cooler. The effluent gas stream leaving said immersion zone may be subjected to additional cleaning by being scrubbed with said scrubbing fluid comprising make-up hydrocarbonaceous fuel and particulate carbon in a separate scrubbing zone. The clean product gas comprises H.sub.2, CO, CO.sub.2, H.sub.2 O and, optionally at least one material from the group H.sub.2 S, COS, N.sub.2, A, and C.sub.1 - C.sub.10 hydrocarbons.

    Abstract translation: 公开了一种用于从烃类燃料进料生产清洁合成或燃料气体的改进的连续部分氧化方法,其中来自该方法的热气体通过与烃油直接接触同时冷却和清洁。 因此,来自气体发生器的反应区的废气流通过将气流直接排放到较大体积的热液体烃浸液中来进行冷却和清洗。 例如,浸没流体可以是包含在单独的浸没容器中的液体烃类燃料如石油和颗粒状碳的分配。 浸没流体的一部分从浸没容器中连续地移出,并在外部冷却器中冷却至约300至850°F但高于工艺气体流中的水的露点的温度。 冷却的浸没流体的部分任选地与随后在该方法中获得的洗涤流体混合,被再循环到浸没容器中,并且任选地作为至少一部分烃类燃料进料再循环到气体发生器。 在另一个实施例中,从浸没容器移除的浸渍流体的一部分可以作为进料的至少一部分被引入到气体发生器中,而不首先通过冷却器。 离开所述浸入区的废气流可以通过在分离的洗涤区中用包含补充含烃燃料和颗粒碳的所述洗涤流体进行洗涤来进行附加清洁。 清洁产物气体包括H 2,CO,CO 2,H 2 O和任选地至少一种来自H 2 S,COS,N 2,A和C 1 -C 10烃的材料。

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