Silane/filler preparations, process for their production and their use
    4.
    发明授权
    Silane/filler preparations, process for their production and their use 失效
    硅烷/填料制剂,其生产和使用过程

    公开(公告)号:US4297145A

    公开(公告)日:1981-10-27

    申请号:US178159

    申请日:1980-08-14

    CPC分类号: C08K9/06 C04B20/1051

    摘要: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formulaX.sub.p --C.sub.m H.sub.2m+1-p SiR.sub.n.sup.1 (OR).sub.3-n, Iin whichX=a halogen atom, preferably chlorine or bromine,p=1 or 2,m=1 to 5,R.sup.1 =a C.sub.1 -C.sub.5 alkyl group, C.sub.5 -C.sub.8 -cycloalkyl group or a phenyl group,R=a C.sub.1 -C.sub.5 -alkyl group, a C.sub.5 -C.sub.8 -cycloalkyl group, a phenyl group, a benzyl group or a C.sub.1 -C.sub.5 -alkoxy-C.sub.1 -C.sub.5 -alkyl group, andn=0, 1 or 2,and--respectively balanced to 100%--from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.

    摘要翻译: 本发明涉及一种硅烷/填料制剂,其基本上由5至70重量%的至少一种对应于下式的硅烷Xp-CmH2m + 1-pSiRn1(OR)3-n,其中X = a 卤素原子,优选氯或溴,p = 1或2,m = 1至5,R1 = C1-C5烷基,C5-C8-环烷基或苯基,R = C1-C5-烷基, C 5 -C 8 - 环烷基,苯基,苄基或C 1 -C 5 - 烷氧基-C 1 -C 5 - 烷基,n = 0,1或2,分别平衡至100〜95〜 30重量%的无机填料,优选炭黑和硅酸盐填料,例如二氧化硅。 还公开了制备硅烷/填料制剂的方法及其在任选可交联的聚合物模塑组合物或可硫化或可交联的橡胶模塑组合物中的用途,例如基于天然橡胶和/或合成的硫可硫化模塑组合物 橡胶。

    Nitrogen containing alkoxysilane and process for its production
    5.
    发明授权
    Nitrogen containing alkoxysilane and process for its production 失效
    含氮烷氧基硅烷及其生产方法

    公开(公告)号:US4337205A

    公开(公告)日:1982-06-29

    申请号:US182313

    申请日:1980-08-28

    CPC分类号: C07F7/182

    摘要: There are prepared nitrogen containing alkoxysilanes of the formula (RO).sub.3-n (CH.sub.3).sub.n Si(CH.sub.2).sub.m NHCON.sub.3 in which R is an alkyl group having 1 to 3 carbon atoms, n is 0, 1 or 2 and m is 1, 2 or 3 by a process comprising dissolving in an inert solvent an isocyanate group containing silane of the formula (RO).sub.3-n (CH.sub.3).sub.n Si(CH.sub.2).sub.m N.dbd.C.dbd.O in which R, n and m are as defined above and reacting the silane with a water free hydrogen nitride or with hydrogen halide and an alkali metal-alkaline earth metal-, or ammonium azide at a temperature between 0.degree. C. and the boiling point of the inert solvent. The compounds are useful in making phosphinimines.

    摘要翻译: 制备式(RO)3-n(CH3)nSi(CH2)mNHCON3的含氮烷氧基硅烷,其中R是具有1至3个碳原子的烷基,n是0,1或2,m是1,2 或通过包括在惰性溶剂中溶解含有式(RO)3-n(CH 3)n Si(CH 2)m N = C = O的硅烷的异氰酸酯基团的方法,其中R,n和m如上所定义,并使 该硅烷与无水氮化氢或与卤化氢和碱金属 - 碱土金属或叠氮化铵在0℃至惰性溶剂的沸点之间的温度下进行。 该化合物可用于制备次膦酰亚胺。

    Vulcanizable halorubber mixtures
    9.
    发明授权
    Vulcanizable halorubber mixtures 失效
    硫化橡胶混合物

    公开(公告)号:US4222915A

    公开(公告)日:1980-09-16

    申请号:US35234

    申请日:1979-05-02

    CPC分类号: C08K5/5406 C08K5/54

    摘要: There are prepared vulcanizable rubber containing mixtures comprising at least one halogen rubber, at least one silicate filler in an amount of 1 to 250 parts by weight, magnesium oxide, zinc oxide or lead oxide in an amount of 0.1 to 15 parts by weight, sulfur in an amount of 0 to 15 parts by weight, stearic acid or other higher fatty acid, benzoic acid or salicylic acid in an amount of 0 to 10 parts by weight, at least one vulcanization accelerator in an amount of 0 to 10 parts by weight, at least one plasticizer in an amount of 0 to 100 parts by weight, at least one stabilizer from the group consisting of antiagers, fatigue inhibitors, antioxidants, light protecting agents and ozone protecting agents in an amount of 0 to 10 parts by weight, carbon black in an amount of 0 to 150 parts by weight and at least one organosilane having the formulaX--C.sub.m H.sub.2m --SiR.sub.n.sup.1 (OR).sub.3-n,while X is chlorine, bromine or iodine, m is a number from 1 to 5, R.sup.1 is a C.sub.1 to C.sub.5 -alkyl group, a C.sub.5 --C.sub.8 -cycloalkyl group or the phenyl group, R is a C.sub.1 to C.sub.8 alkyl group, a C.sub.5 to C.sub.8 -cycloalkyl group, the methoxyethyl group, the phenyl group or the benzyl group and n is 0, 1 or 2, in an amount of 0.1 to 20 parts by weight, all amounts being based on 100 parts by weight of the halogen rubber.

    摘要翻译: 制备含有至少一种卤素橡胶,至少一种量为1至250重量份的硅酸盐填料,0.1至15重量份的氧化镁,氧化锌或氧化铅的混合物的可硫化橡胶,硫 0至15重量份的硬脂酸或其它高级脂肪酸,苯甲酸或水杨酸,其量为0至10重量份,至少一种硫化促进剂的量为0至10重量份 ,0〜100重量份的至少1种增塑剂,0〜10重量份的抗衰老剂,疲劳抑制剂,抗氧化剂,防光剂和臭氧保护剂中的至少1种稳定剂, 0〜150重量份的炭黑和至少1个具有式X-CmH2m-SiRn1(OR)3-n的有机硅烷,X为氯,溴或碘,m为1〜5的数, R1是C1-C5-烷基,C5-C8-环烷基 或苯基,R为C1〜C8烷基,C5〜C8-环烷基,甲氧基乙基,苯基或苄基,n为0,1或2,为0.1〜20份 ,所有量均为100重量份的卤素橡胶。

    Vulcanizable EPDM containing rubber composition
    10.
    发明授权
    Vulcanizable EPDM containing rubber composition 失效
    可硫化的含EPDM的橡胶组合物

    公开(公告)号:US06521713B2

    公开(公告)日:2003-02-18

    申请号:US08417858

    申请日:1995-04-07

    IPC分类号: C08F834

    摘要: A rubber composition is disclosed containing an ethylene-propylene-nonconjugated diene copolymer rubber (or a blend of an ethylene-propylene-nonconjugated diene copolymer rubber and a diene rubber), a specific alkoxysilane compound, and amorphous silica powder having a specific surface area of 50 to 100 m2/g (BET adsorption). The vulcanized rubber is prepared by vulcanizing such a rubber composition. The rubber composition is excellent in dynamic characteristics and also in mechanical characteristics, dynamic fatigue resistance and thermal aging resistance. It also can provide a vulcanized rubber having the above-mentioned effects.

    摘要翻译: 公开了一种橡胶组合物,其含有乙烯 - 丙烯 - 非共轭二烯共聚物橡胶(或乙烯 - 丙烯 - 非共轭二烯共聚物橡胶和二烯橡胶的共混物),特定的烷氧基硅烷化合物和比表面积为 50〜100m2 / g(BET吸附)。 通过硫化这种橡胶组合物制备硫化橡胶。 橡胶组合物的动态特性以及机械特性,动态耐疲劳性和耐热老化性都优异。 也可以提供具有上述效果的硫化橡胶。