公开(公告)号：US20110009650A1

公开(公告)日：2011-01-13

申请号：US12920877

申请日：2009-03-12

Applicant: Benjamin List ,  Corinna Reisinger ,  Xingwang Wang

Inventor： Benjamin List ,  Corinna Reisinger ,  Xingwang Wang

IPC: C07D301/03

CPC classification number: C07D301/12

Abstract: A process is claimed for the enantioselective epoxidation of α,β-unsaturated ketones, in which a compound of the general formula I, is reacted with an oxidizing agent to form α,β-epoxy ketones of the general formula II, in which R1, R2, R3 are as defined above. The α,β-epoxy ketones of the general formula II can be obtained in good yields and outstanding enantioselectivities from α,β-unsaturated ketones of the general formula I by epoxidation with hydrogen peroxide in the presence of a chiral catalyst, such as amino compounds and their acid addition salts.

Abstract translation: 要求对α，bgr-不饱和酮的对映选择性环氧化方法，其中将通式I的化合物与氧化剂反应以形成通式II的α和b-环氧酮，其中 R1，R2，R3如上所定义。 通式II的α和bgr-环氧酮可以通过在手性催化剂存在下用过氧化氢进行环氧化，得到通式Ⅰ的α，bgr-不饱和酮的良好收率和优异的对映体选择性，例如 氨基化合物及其酸加成盐。

公开(公告)号：US08471046B2

公开(公告)日：2013-06-25

申请号：US12920877

申请日：2009-03-12

Applicant: Benjamin List ,  Corinna Reisinger ,  Xingwang Wang

Inventor： Benjamin List ,  Corinna Reisinger ,  Xingwang Wang

IPC: C07D301/12

CPC classification number: C07D301/12

Abstract: A process is claimed for the enantioselective epoxidation of α,β-unsaturated ketones, in which a compound of the general formula I, is reacted with an oxidizing agent to form α,β-epoxy ketones of the general formula II, in which R1, R2, R3 are as defined above. The α,β-epoxy ketones of the general formula II can be obtained in good yields and outstanding enantioselectivities from α,β-unsaturated ketones of the general formula I by epoxidation with hydrogen peroxide in the presence of a chiral catalyst, such as amino compounds and their acid addition salts.

Abstract translation: 要求对α，β-不饱和酮进行对映选择性环氧化的方法，其中通式I的化合物与氧化剂反应形成通式II的α，β-环氧酮，其中R1， R2，R3如上所定义。 通式II的α，β-环氧酮可以通过在手性催化剂如氨基化合物的存在下用过氧化氢进行环氧化，以良好的收率和通式I的α，β-不饱和酮的优异的对映选择性获得。 和它们的酸加成盐。

公开(公告)号：US20090030216A1

公开(公告)日：2009-01-29

申请号：US12280821

申请日：2007-02-27

Applicant: Benjamin List ,  Sonja Mayer ,  Nolwenn Martin ,  Xingwang Wang

Inventor： Benjamin List ,  Sonja Mayer ,  Nolwenn Martin ,  Xingwang Wang

IPC: C07D301/00

CPC classification number: C07C201/12 ,  B01J31/0225 ,  B01J31/0239 ,  B01J31/0258 ,  B01J2231/645 ,  B01J2231/72 ,  B01J2531/0266 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/88 ,  C07C45/511 ,  C07C45/62 ,  C07C45/69 ,  C07C45/72 ,  C07C49/86 ,  C07C67/08 ,  C07C253/30 ,  C07C2601/08 ,  C07C2601/14 ,  C07C2601/18 ,  C07D301/14 ,  C07C47/23 ,  C07C49/213 ,  C07C49/413 ,  C07C47/21 ,  C07C47/24 ,  C07C47/228 ,  C07C47/02 ,  C07C49/395 ,  C07C49/657 ,  C07C49/403 ,  C07C47/445 ,  C07C69/007 ,  C07C255/56 ,  C07C69/157 ,  C07C205/44 ,  C07C33/22

Abstract: The invention relates to a method for producing chiral organic compounds by asymmetric catalysis, using ionic catalysts comprising a chiral catalyst anion. The claimed method is suitable for reactions which are carried out over cationic intermediate stages, such as iminium ions or acyl pyridinium ions. The invention enables the production of chiral compounds with high ee values, that until now could only be obtained by means of costly purification methods.

Abstract translation: 本发明涉及使用包含手性催化剂阴离子的离子催化剂通过不对称催化制备手性有机化合物的方法。 所要求的方法适用于在阳离子中间阶段例如亚铵离子或酰基吡啶鎓离子进行的反应。 本发明能够生产具有高ee值的手性化合物，到目前为止只能通过昂贵的纯化方法获得。

公开(公告)号：US20080161438A1

公开(公告)日：2008-07-03

申请号：US11647069

申请日：2006-12-28

Applicant: Xingwang Wang ,  Ruo Fei Zhao ,  Kye Hyun Kim

Inventor： Xingwang Wang ,  Ruo Fei Zhao ,  Kye Hyun Kim

IPC: C08L75/04 ,  C08L53/00 ,  C08L33/04 ,  C08L77/00 ,  C08F8/00

CPC classification number: C08J9/0061 ,  C08J2201/024 ,  C08J2203/04 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2400/14 ,  C08J2423/00 ,  C08J2453/00 ,  C08J2467/00 ,  C08J2475/00 ,  C08J2477/00 ,  C08L23/0853 ,  C08L23/0869 ,  C08L53/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02

Abstract: Disclosed is a composition comprising, consisting essentially of, or consisting of an ethylene polymer, a thermoplastic elastomer, a crosslinking agent, and optionally a foaming agent wherein the ethylene polymer includes ethylene vinyl acetate copolymer, polyethylene, ethylene acid copolymer, ionomer of the acid copolymer, ethylene alkyl(meth)acrylate copolymer, or combinations of two or more thereof; the thermoplastic elastomer can include copolyetherester, copolyetheramide, elastomeric polyolefin, styrene diene block copolymers, thermoplastic polyurethane, or combinations of two or more thereof; and the crosslinking agent includes one or more organic peroxides, irradiation, or combinations thereof. Also disclosed is a product made from the composition such as foam for shoe applications.

Abstract translation: 公开了一种组合物，其包含乙烯聚合物，热塑性弹性体，交联剂和任选的发泡剂，其中乙烯聚合物包括乙烯 - 乙酸乙烯酯共聚物，聚乙烯，乙烯酸共聚物，酸的离聚物 共聚物，（甲基）丙烯酸乙烯酯共聚物，或其两种以上的组合; 热塑性弹性体可包括共聚醚酯，共聚醚酰胺，弹性体聚烯烃，苯乙烯二烯嵌段共聚物，热塑性聚氨酯或其两种或多种的组合; 并且交联剂包括一种或多种有机过氧化物，照射或其组合。 还公开了由组合物制成的产品，例如用于鞋应用的泡沫。