公开(公告)号：US08697598B2

公开(公告)日：2014-04-15

申请号：US11918851

申请日：2006-04-20

Applicant: Xiangyun Long ,  Xuefen Liu ,  Hong Nie ,  Kui Wang ,  Jing Xin ,  Qinghe Liu ,  Xiaodong Gao ,  Zhihai Hu ,  Yahua Shi ,  Dadong Li

Inventor： Xiangyun Long ,  Xuefen Liu ,  Hong Nie ,  Kui Wang ,  Jing Xin ,  Qinghe Liu ,  Xiaodong Gao ,  Zhihai Hu ,  Yahua Shi ,  Dadong Li

IPC: B01J21/04 ,  B01J21/12 ,  B01J29/46 ,  B01J23/883 ,  B01J23/888 ,  C10G45/08 ,  C10G45/38

CPC classification number: B01J23/8885 ,  B01J23/002 ,  B01J27/128 ,  B01J27/132 ,  B01J27/19 ,  B01J27/199 ,  B01J29/005 ,  B01J29/076 ,  B01J29/166 ,  B01J29/26 ,  B01J29/48 ,  B01J29/7815 ,  B01J29/80 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/024 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  C10G49/04 ,  C10G49/08 ,  C10G2300/1022 ,  C10G2300/1033 ,  C10G2300/4018 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. In another embodiment, the present invention provides a hydrogenation catalyst, containing a carrier and metal components of nickel, molybdenum and tungsten supported thereon, wherein said carrier contains a molecular sieve. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.

Abstract translation: 本发明提供了一种氢化催化剂，其含有载体，负载有镍，钼和钨的金属组分，以及选自氟和磷及其组合的助剂组分。 在另一个实施方案中，本发明提供一种氢化催化剂，其含有负载在其上的载体和镍，钼和钨的金属组分，其中所述载体含有分子筛。 本发明提供所述催化剂在烃油氢化方法中的进一步的应用。 与根据现有技术的氢化催化剂相比，根据本发明的催化剂具有高得多的活性。

公开(公告)号：US20090139898A1

公开(公告)日：2009-06-04

申请号：US11918851

申请日：2006-04-20

Applicant: Xiangyun Long ,  Xuefen Liu ,  Hong Nie ,  Kui Wang ,  Jing Xin ,  Qinghe Liu ,  Xiaodong Gao ,  Zhihai Hu ,  Yahua Shi ,  Dadong Li

Inventor： Xiangyun Long ,  Xuefen Liu ,  Hong Nie ,  Kui Wang ,  Jing Xin ,  Qinghe Liu ,  Xiaodong Gao ,  Zhihai Hu ,  Yahua Shi ,  Dadong Li

IPC: B01J29/06 ,  B01J27/132 ,  B01J27/19 ,  B01J31/02 ,  C07C5/03 ,  B01J27/138 ,  B01J27/135

CPC classification number: B01J23/8885 ,  B01J23/002 ,  B01J27/128 ,  B01J27/132 ,  B01J27/19 ,  B01J27/199 ,  B01J29/005 ,  B01J29/076 ,  B01J29/166 ,  B01J29/26 ,  B01J29/48 ,  B01J29/7815 ,  B01J29/80 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/024 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  C10G49/04 ,  C10G49/08 ,  C10G2300/1022 ,  C10G2300/1033 ,  C10G2300/4018 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. In another embodiment, the present invention provides a hydrogenation catalyst, containing a carrier and metal components of nickel, molybdenum and tungsten supported thereon, wherein said carrier contains a molecular sieve. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.

Abstract translation: 本发明提供了一种氢化催化剂，其含有载体，负载有镍，钼和钨的金属组分，以及选自氟和磷及其组合的助剂组分。 在另一个实施方案中，本发明提供一种氢化催化剂，其含有负载在其上的载体和镍，钼和钨的金属组分，其中所述载体含有分子筛。 本发明提供所述催化剂在烃油氢化方法中的进一步的应用。 与根据现有技术的氢化催化剂相比，根据本发明的催化剂具有高得多的活性。

公开(公告)号：US5914290A

公开(公告)日：1999-06-22

申请号：US884814

申请日：1997-06-30

Applicant: Yahua Shi ,  Dadong Li ,  Xuefen Liu ,  Hong Nie ,  Xiaodong Gao ,  Yibing Ying

Inventor： Yahua Shi ,  Dadong Li ,  Xuefen Liu ,  Hong Nie ,  Xiaodong Gao ,  Yibing Ying

IPC: B01J23/888 ,  B01J27/132 ,  C10G45/08 ,  B01J23/30 ,  B01J23/755 ,  B01J27/12

CPC classification number: C10G45/08 ,  B01J23/888 ,  B01J27/132

Abstract: The present invention discloses a hydrofining catalyst. The catalyst has the following composition based on the total weight of the entire catalyst composition: 1-5%(wt.) nickel oxide, 12-35% (wt.) tungsten oxide, 1-9% (wt.) fluorine, and the balancing amount of composite alumina. Said composite alumina is composed of one or several kinds of micropore alumina and one or several kinds of macropore alumina, wherein the weight ratio of micropore alumina to macropore alumina is 75:25 to 50:50. The term "micropore alumina" in the context means the alumina in which the volume of the proe of diameter less than 80 angstrom occupies more than 95% of its total pore volume, while the term "macropore alumina" in the contest means the alumina in which the volume of the pore of diameter 60-600 angstrom occupies more than 70% of its total pore volume. The pore distribution mentioned above is determined by BET method of nitrogen adsorption at low temperature. This catalyst is especially suitable for the hydrofining of inferior distillates with high sulfur content and boiling range of 80-550.degree. C.

Abstract translation: 本发明公开了一种加氢精制催化剂。 催化剂具有以下催化剂组合物总重量的组成：1-5％（重量）氧化镍，12-35％（重量）氧化钨，1-9％（重量）氟，和 复合氧化铝的平衡量。 所述复合氧化铝由一种或几种微孔氧化铝和一种或几种大孔氧化铝组成，其中微孔氧化铝与大孔氧化铝的重量比为75:25至50:50。 在本文中，术语“微孔氧化铝”是指直径小于80埃的原型体积占其总孔体积的95％以上的氧化铝，而比较中的术语“大孔氧化铝”是指氧化铝 其直径为60-600埃的孔的体积占其总孔体积的70％以上。 上述孔分布由低温氮吸附的BET法测定。 该催化剂特别适用于高硫含量和沸程为80-550℃的劣质馏分的加氢精制。

公开(公告)号：US06518219B1

公开(公告)日：2003-02-11

申请号：US09687564

申请日：2000-10-13

Applicant: Qinghe Yang ,  Bin Liu ,  Hong Nie ,  Xuefen Liu ,  Dadong Li ,  Yahua Shi ,  Fucheng Zhuang

Inventor： Qinghe Yang ,  Bin Liu ,  Hong Nie ,  Xuefen Liu ,  Dadong Li ,  Yahua Shi ,  Fucheng Zhuang

IPC: B01J2300

CPC classification number: B01J23/85 ,  B01J21/04 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/033 ,  C10G45/08

Abstract: A catalyst for hydrofining fraction oils, comprises an alumina carrier and at least one metal and/or thereof oxide of Group VIB and at least one metal and/or thereof oxide of Group VIII supported on said alumina carrier. The pore volume of said alumina carrier is not less than 0.35 ml/g, in which the pore volume of the pores having a diameter of 40-100 angstrom accounts for more than 80% of the total pore volume, the alumina carrier is prepared by a special process. The catalyst possesses relatively high hydrogenation activity.

Abstract translation: 用于加氢精馏部分油的催化剂包含氧化铝载体和至少一种VIB族的金属和/或氧化物和至少一种负载在所述氧化铝载体上的第VIII族金属和/或氧化物。 所述氧化铝载体的孔体积不小于0.35ml / g，其中直径为40-100埃的孔的孔体积占总孔体积的大于80％，氧化铝载体由 一个特殊的过程。 催化剂具有较高的氢化活性。