公开(公告)号：US09355826B2

公开(公告)日：2016-05-31

申请号：US14379228

申请日：2013-02-13

申请人： A SCHOOL CORPORATION KANSAI UNIVERSITY ,  NISSAN CHEMICAL INDUSTRIES, LTD.

发明人： Ryuichi Arakawa ,  Hideya Kawasaki ,  Tomoyuki Ozawa

IPC分类号： H01J49/26 ,  H01J49/00 ,  B82Y30/00 ,  A01N25/00 ,  A01N47/40 ,  G01N1/28 ,  B82Y40/00

CPC分类号： H01J49/0004 ,  A01N25/00 ,  A01N47/40 ,  B82Y30/00 ,  B82Y40/00 ,  G01N1/28 ,  G01N1/2853 ,  H01J49/26 ,  A01N47/34

摘要： The present invention provides an improved method for imaging mass spectrometry using an ionization-assisting matrix of a test sample, wherein the ionization efficiency is high, migration and visual information reduction are inhibited, no interference peaks originating from the matrix occur, and the analysis can be performed at high spatial resolution.Specifically, the present invention provides a method for imaging mass spectrometry using a sample prepared by physical vapor depositing platinum nanoparticles on the surface of a test sample to be subjected to imaging mass spectrometry.

摘要翻译： 本发明提供了使用测试样品的电离辅助基质进行成像质谱的改进方法，其中电离效率高，抑制迁移和视觉信息降低，不发生源自基质的干扰峰，并且分析可以 以高空间分辨率进行。 具体地说，本发明提供使用通过物理气相沉积铂纳米颗粒制备的样品进行成像质谱法的方法，所述样品通过成像质谱法测试的样品的表面上。

公开(公告)号：US20150021470A1

公开(公告)日：2015-01-22

申请号：US14379228

申请日：2013-02-13

申请人： A SCHOOL CORPORATION KANSAI UNIVERSITY ,  NISSAN CHEMICAL INDUSTRIES, LTD

发明人： Ryuichi Arakawa ,  Hideya Kawasaki ,  Tomoyuki Ozawa

IPC分类号： H01J49/00 ,  G01N1/28 ,  H01J49/26

CPC分类号： H01J49/0004 ,  A01N25/00 ,  A01N47/40 ,  B82Y30/00 ,  B82Y40/00 ,  G01N1/28 ,  G01N1/2853 ,  H01J49/26 ,  A01N47/34

摘要： The present invention provides an improved method for imaging mass spectrometry using an ionization-assisting matrix of a test sample, wherein the ionization efficiency is high, migration and visual information reduction are inhibited, no interference peaks originating from the matrix occur, and the analysis can be performed at high spatial resolution.Specifically, the present invention provides a method for imaging mass spectrometry using a sample prepared by physical vapor depositing platinum nanoparticles on the surface of a test sample to be subjected to imaging mass spectrometry.

摘要翻译： 本发明提供了使用测试样品的电离辅助基质进行成像质谱的改进方法，其中电离效率高，抑制迁移和视觉信息降低，不发生源自基质的干扰峰，并且分析可以 以高空间分辨率进行。 具体地说，本发明提供使用通过物理气相沉积铂纳米颗粒制备的样品进行成像质谱法的方法，所述样品通过成像质谱法测试的样品的表面上。

公开(公告)号：US09287099B2

公开(公告)日：2016-03-15

申请号：US13973305

申请日：2013-08-22

申请人： A SCHOOL CORPORATION KANSAI UNIVERSITY ,  CANON KABUSHIKI KAISHA

发明人： Yoichi Otsuka ,  Ryuichi Arakawa

IPC分类号： H01J49/10 ,  H01J49/00 ,  G01N30/72 ,  H01J49/04 ,  H01J49/16 ,  B01D59/44 ,  H01J27/08

CPC分类号： H01J49/0027 ,  B01D59/44 ,  G01N30/7266 ,  H01J27/08 ,  H01J49/0454 ,  H01J49/168

摘要： To achieve soft ionization more easily when a slight amount of substance is ionized under an atmosphere pressure. An ionization method for a substance contained in a liquid, including: supplying the liquid to a substrate from a probe and forming a liquid bridge made of the liquid containing the substance dissolved therein, between the probe and the substrate; oscillating the probe; and generating an electric field between an electrically conductive portion of the probe in contact with the liquid and an ion extraction electrode.

摘要翻译： 当在大气压下离子化少量物质时，更容易实现软电离。 一种包含在液体中的物质的电离方法，包括：在探针和基底之间，将来自探针的液体供给到基底并形成由其中溶解有物质的液体制成的液体桥; 振荡探头; 以及在与液体接触的探针的导电部分和离子提取电极之间产生电场。

公开(公告)号：US20130341279A1

公开(公告)日：2013-12-26

申请号：US13973305

申请日：2013-08-22

申请人： CANON KABUSHIKI KAISHA ,  A SCHOOL CORPORATION KANSAI UNIVERSITY

发明人： Yoichi Otsuka ,  Ryuichi Arakawa

IPC分类号： H01J49/00 ,  B01D59/44 ,  H01J27/08

CPC分类号： H01J49/0027 ,  B01D59/44 ,  G01N30/7266 ,  H01J27/08 ,  H01J49/0454 ,  H01J49/168

摘要： To achieve soft ionization more easily when a slight amount of substance is ionized under an atmosphere pressure. An ionization method for a substance contained in a liquid, including: supplying the liquid to a substrate from a probe and forming a liquid bridge made of the liquid containing the substance dissolved therein, between the probe and the substrate; oscillating the probe; and generating an electric field between an electrically conductive portion of the probe in contact with the liquid and an ion extraction electrode.

公开(公告)号：US20170073538A1

公开(公告)日：2017-03-16

申请号：US15120978

申请日：2015-02-12

申请人： A SCHOOL CORPORATION KANSAI UNIVERSITY

发明人： Hideya Kawasaki ,  Ryuichi Arakawa ,  Yuki Hokita

IPC分类号： C09D11/52 ,  C09D17/00 ,  B82Y30/00 ,  B22F1/00 ,  B22F9/24 ,  C09C1/62 ,  C09D11/00

CPC分类号： C09D11/52 ,  B22F1/0018 ,  B22F1/0062 ,  B22F1/0074 ,  B22F9/24 ,  B32B5/16 ,  B32B27/14 ,  B82Y30/00 ,  B82Y40/00 ,  C09C1/627 ,  C09D11/00 ,  C09D17/006

摘要： An object of the present invention is to provide copper nanoparticles that suppress the oxidation of copper, have an average particle diameter of 10 nm or less and therefore undergo a remarkable reduction in the melting point, are highly dispersible, can be sintered at a low temperature, allow the removal of the protective layer during low-temperature sintering at 150° C. or less, and can be suitably used as a conductive copper nanoink material; and to also provide a method for preserving copper nanoparticles, whereby the copper nanoparticles can be stably preserved at room temperature for a long period of time, and can be transported.The present invention provides copper nanoparticles each having a central portion comprising a copper single crystal, and a protective layer surrounding the central portion; (1) the copper nanoparticles having an average particle diameter of 10 nm or less; (2) the protective layer containing at least one member selected from the group consisting of C3-6 primary alcohols, C3-6 secondary alcohols, and derivatives thereof; and (3) the protective layer having a boiling point or thermal decomposition point of 150° C. or less.

摘要翻译： 本发明的主要目的是提供使铜的氧化最小化的铜纳米颗粒; 由于平均粒径为10nm以下，熔点显着降低，而且在低温下高度分散，可烧结; 在150℃以下的低温烧结时可以除去保护层; 适用于导电铜纳米材料; 以及铜纳米颗粒保存方法，其中铜纳米颗粒可以在室温下长时间稳定地保存并运输。 本发明提供了由包括铜单晶和其周围的保护层的中心部分形成的铜纳米颗粒，其中铜纳米粒子的特征在于：（1）铜纳米颗粒的平均粒径为10nm以下， （2）保护层包含至少一种选自C3-6伯醇，C3-6仲醇及其衍生物的化合物，（3）保护层的沸点或热分解点为150℃以下 。

公开(公告)号：US20130334030A1

公开(公告)日：2013-12-19

申请号：US13972063

申请日：2013-08-21

申请人： CANON KABUSHIKI KAISHA ,  A SCHOOL CORPORATION KANSAI UNIVERSITY

发明人： Yoichi Otsuka ,  Ryuichi Arakawa

IPC分类号： B01J19/08

CPC分类号： H01J49/165 ,  H01J49/0454

摘要： The present invention has an object to achieve soft ionization more easily when a slight amount of substance is ionized under an atmosphere pressure. The present invention provides an ionization method for a substance contained in a liquid, including: supplying the liquid to a substrate from a probe and forming a liquid bridge made of the liquid containing the substance dissolved therein, between the probe and the substrate; oscillating the substrate; and generating an electric field between an electrically conductive portion of the probe in contact with the liquid and an ion extraction electrode.

摘要翻译： 本发明的目的是在大气压下将少量物质电离时，更容易实现软电离。 本发明提供一种液体中所含物质的离子化方法，包括：从探针供应液体至基底，并形成由溶解于其中的物质形成的液体桥;探针与基底之间; 振荡基板; 以及在与液体接触的探针的导电部分和离子提取电极之间产生电场。

公开(公告)号：US10214656B2

公开(公告)日：2019-02-26

申请号：US15120978

申请日：2015-02-12

申请人： A SCHOOL CORPORATION KANSAI UNIVERSITY

发明人： Hideya Kawasaki ,  Ryuichi Arakawa ,  Yuki Hokita

IPC分类号： B32B5/16 ,  C09D11/52 ,  B32B27/14 ,  B22F9/24 ,  B82Y30/00 ,  B22F1/00 ,  C09C1/62 ,  C09D11/00 ,  C09D17/00 ,  B82Y40/00

摘要： An object of the present invention is to provide copper nanoparticles that suppress the oxidation of copper, have an average particle diameter of 10 nm or less and therefore undergo a remarkable reduction in the melting point, are highly dispersible, can be sintered at a low temperature, allow the removal of the protective layer during low-temperature sintering at 150° C. or less, and can be suitably used as a conductive copper nanoink material; and to also provide a method for preserving copper nanoparticles, whereby the copper nanoparticles can be stably preserved at room temperature for a long period of time, and can be transported.The present invention provides copper nanoparticles each having a central portion comprising a copper single crystal, and a protective layer surrounding the central portion; (1) the copper nanoparticles having an average particle diameter of 10 nm or less; (2) the protective layer containing at least one member selected from the group consisting of C3-6 primary alcohols, C3-6 secondary alcohols, and derivatives thereof; and (3) the protective layer having a boiling point or thermal decomposition point of 150° C. or less.

公开(公告)号：US09190257B2

公开(公告)日：2015-11-17

申请号：US13972063

申请日：2013-08-21

申请人： A SCHOOL CORPORATION KANSAI UNIVERSITY ,  CANON KABUSHIKI KAISHA

发明人： Yoichi Otsuka ,  Ryuichi Arakawa

IPC分类号： H01J49/10 ,  H01J49/16 ,  H01J49/04

CPC分类号： H01J49/165 ,  H01J49/0454

摘要： The present invention has an object to achieve soft ionization more easily when a slight amount of substance is ionized under an atmosphere pressure. The present invention provides an ionization method for a substance contained in a liquid, including: supplying the liquid to a substrate from a probe and forming a liquid bridge made of the liquid containing the substance dissolved therein, between the probe and the substrate; oscillating the substrate; and generating an electric field between an electrically conductive portion of the probe in contact with the liquid and an ion extraction electrode.

摘要翻译： 本发明的目的是在大气压下将少量物质电离时，更容易实现软电离。 本发明提供一种液体中所含物质的离子化方法，包括：从探针供应液体至基底，并形成由溶解于其中的物质形成的液体桥;探针与基底之间; 振荡基板; 以及在与液体接触的探针的导电部分和离子提取电极之间产生电场。