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公开(公告)号:US5453253A
公开(公告)日:1995-09-26
申请号:US602017
申请日:1990-10-23
IPC分类号: B03B9/04 , B09B3/00 , C01B17/02 , C01B17/06 , C22B20060101 , C22B3/00 , C22B3/08 , C22B7/00 , C22B9/02 , C22B19/20 , C22B19/30 , C25C1/00 , C25C1/16
CPC分类号: C22B19/22 , Y02P10/234
摘要: For reprocessing of jarosite-containing residues to provide usable products, the jarosite-containing residues and concentrates which contain zinc sulfide are stirred in dilute sulfuric acid, which contains 40 to 100 g/l free sulfuric acid, in an autoclave under an oxygen partial pressure of at least 1,000 kPa and at a temperature from 130.degree. to 170.degree. C., the iron contents and the zinc contents of the residue and of the concentrate which contains zinc sulfide are substantially dissolved, flashing is effected and is succeeded by a separation of solution and solids, the solution is fed to the leaching circuit of a plant for the electrolytic production of zinc with precipitation of iron as hematite, the elemental sulfur is separated from the solids and the hematite residue is supplied to a further utilization.
摘要翻译: 对于含黄钾矾渣的后处理以提供可用的产品,将包含硫化锌的含黄钾铁矾的残渣和浓缩物在氧分压下在高压釜中在含有40-100g / l游离硫酸的稀硫酸中搅拌 至少1000kPa,在130℃至170℃的温度下,残留物和含有硫化锌的浓缩物的铁含量和锌含量基本上溶解,闪烁,并通过分离 溶液和固体,将溶液进料到用于电解生产锌的设备的浸出回路中,铁沉淀为赤铁矿,元素硫与固体分离,并且赤铁矿残渣被供应以进一步利用。
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2.
公开(公告)号:US4789446A
公开(公告)日:1988-12-06
申请号:US101714
申请日:1987-09-28
IPC分类号: C22B7/00 , C22B3/00 , C22B3/04 , C22B3/08 , C22B3/44 , C22B7/02 , C22B15/00 , C22B19/00 , C22B19/20 , C22B19/30 , C22B21/00 , C22B41/00 , C22B58/00 , C25C20060101 , C25C1/14 , C25C1/16 , C25D1/16
CPC分类号: C22B19/22 , Y02P10/234
摘要: In conjunction with an electrolytic production of zinc, the residues are processed so that the residue is leached with cell acid at a temperature from 50.degree. to 100.degree. C. in such a manner that a concentration of free acid from 10 to 100 g/l is obtained at the end of the leaching. The undissolved matter is separated from the suspension, the separated matter is supplied to the acid leaching step performed in the electrolytic production of zinc, and fine-grained metallic iron is added to the solution from which the undissolved matter has been removed so that copper is precipitated. The precipitated copper is separated and the liquid phase from which the precipitated copper has been separated is supplied to one of the stages which precede the precipitation of iron in the electrolytic production of zinc.
摘要翻译: 结合锌的电解生产,处理残余物,使得残余物在50℃至100℃的温度下以细胞酸浸出,使得游离酸的浓度为10至100g / l 在浸出结束时获得。 将未溶解的物质与悬浮液分离,将分离的物质供给到在电解生产锌中进行的酸浸出步骤,并且将细粒金属铁加入到其中去除未溶解物质的溶液中,使得铜为 沉淀 将析出的铜分离,将析出的铜分离出的液相供给到在电解生产锌中铁析出之前的一个阶段。
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