公开(公告)号：US20120301389A1

公开(公告)日：2012-11-29

申请号：US13574641

申请日：2011-02-06

申请人： Aharon Eyal ,  Asher Vitner ,  Revital Mali ,  Carmi Raz

发明人： Aharon Eyal ,  Asher Vitner ,  Revital Mali ,  Carmi Raz

IPC分类号： C01B17/90 ,  C09K3/00

CPC分类号： C01B25/234 ,  C01B17/903 ,  C01B21/46

摘要： The present invention provides an organic phase composition comprising (a) a first solvent (S1) characterized by water solubility of less than 10% and by at least one of (a1) having a polarity related component of Hoy's cohesion parameter (delta-P) between 5 and 10 MPa1/2 and (b1) having a Hydrogen bonding related component of Hoy's cohesion parameter (delta-H) between 5 and 20 MPa1/2; (b) a second solvent (S2) characterized by a water solubility of at least 30% and by at least one of (a2) having delta-P greater than 8 MPa1/2 and (b2) having delta-H greater than 12 MPa1/2; (c) water; (d) a non-volatile strong acid; and (e) a salt thereof.

摘要翻译： 本发明提供一种有机相组合物，其包含（a）第一溶剂（S1），其特征在于水溶性小于10％，和至少一种具有Hoy的内聚参数（Δ-P）的极性相关成分的（a1） 5〜10MPa1 / 2，（b1）具有5〜20MPa·1/2的Hoy粘结参数（δ-H）的氢键相关成分; （b）第二溶剂（S2），其特征在于水溶解度为至少30％，并且至少一种具有δ-P大于8MPa1 / 2的（a2）和（b2）具有大于12MPa1的Δ-H / 2; （c）水; （d）不挥发性强酸; 和（e）其盐。

公开(公告)号：US20140190470A1

公开(公告)日：2014-07-10

申请号：US13807479

申请日：2011-06-28

申请人： Aharon Eyal ,  Robert Jansen ,  Asher Vitner ,  Revital Mali

发明人： Aharon Eyal ,  Robert Jansen ,  Asher Vitner ,  Revital Mali

IPC分类号： C13K11/00 ,  C13K1/02

CPC分类号： C13K11/00 ,  C13B5/04 ,  C13B10/02 ,  C13K1/02 ,  C13K13/00 ,  C13K13/002

摘要： A method comprising: (a) providing a partially processed sucrose crop product containing at least 2% optionally at least 5% of the sucrose content of said crop at harvest on a dry solids basis, cellulose and lignin; (b) hydrolyzing said partially processed crop product with HCl to produce an acid hydrolyzate stream and a lignin stream; and (c) de-acidifying said hydrolyzate stream to produce a de-acidified sugar solution and an HCl recovery stream. Additional, methods, systems and sugar mixtures are also disclosed.

摘要翻译： 一种方法，包括：（a）提供部分加工的蔗糖作物产品，其在干固体收获时提供含有至少2％任选至少5％的所述作物蔗糖含量的纤维素和木质素; （b）用HCl水解所述部分加工的作物产物以产生酸水解产物流和木质素流; 和（c）使所述水解产物流脱酸以产生脱酸糖溶液和HCl回收流。 还公开了方法，系统和糖混合物。

公开(公告)号：US20130028832A1

公开(公告)日：2013-01-31

申请号：US13577213

申请日：2011-02-06

申请人： Aharon Eyal ,  Asher Vitner ,  Revital Mali

发明人： Aharon Eyal ,  Asher Vitner ,  Revital Mali

IPC分类号： C01B7/01 ,  C09K3/00

CPC分类号： C01B7/0731 ,  C01B7/0737 ,  C13K1/02 ,  Y02E50/16

摘要： The present invention provides an organic phase composition comprising: (a) a first solvent (S1) characterized by a water solubility of less than 10% and by at least one of (a1) having a polarity related component of Hoy's cohesion parameter (delta-P) between 5 and 10 MPa1/2 and (b1) having a Hydrogen bonding related component of Hoy's cohesion parameter (delta-H) between 5 and 20 MPa1/2; (b) a second solvent (S2) characterized by a water solubility of at least 30% and by at least one of (a2) having a delta-P greater than 8 MPa1/2 and (b2) having a delta-H greater than 12 MPa1/2; (c) water; (d) HCl; and (e) a carbohydrate.

摘要翻译： 本发明提供一种有机相组合物，其包含：（a）第一溶剂（S1），其特征在于水溶解度小于10％，和至少一种（a1）具有Hoy的内聚参数（δ- P）为5〜10MPa1 / 2，（b1）具有5〜20MPa1 / 2的Hoy粘附参数（δ-H）的氢键相关成分; （b）第二溶剂（S2），其特征在于水溶解度为至少30％，并且至少一种（a2）具有大于8MPa1 / 2的δ-P和（b2），其中δ-H大于 12 MPa1 / 2; （c）水; （d）HCl; 和（e）碳水化合物。

公开(公告)号：US20090158895A1

公开(公告)日：2009-06-25

申请号：US12083362

申请日：2006-10-15

申请人： Asher Vitner ,  Aharon Eyal ,  Revital Mali

发明人： Asher Vitner ,  Aharon Eyal ,  Revital Mali

IPC分类号： C01B17/96 ,  C01G23/04 ,  C01G25/06 ,  C22B34/12

CPC分类号： C01G23/002 ,  B82Y30/00 ,  C01G23/008 ,  C01G23/04 ,  C01G23/0532 ,  C01G49/009 ,  C01G49/14 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/80

摘要： The invention provides a method for the Industrial purification of a titanium feed stream of purity P1, by the formation of a titanium-double-salt precipitate of purity P2 and a titanium solution with purity P3, wherein P2>P1>P3, the method comprising the steps of: i. forming, from the feed, a medium comprising water, titanium ion, a cation selected from the group consisting of ammonium, cations of alkali metals, protons and a combination thereof, and an anion selected from the group consisting of OH, SO4, HSO4, halides and a combination thereof, which formed medium is further characterized by the presence of (a) a double-salt precipitate comprising titanium ion, at least one of the cations and at least one of the anions; and (b) a titanium solution; and wherein the concentration of the anion in the titanium solution is higher than 15% and the ratio between the concentrations of the cation and the anion in the titanium solution is higher than 0.2 and lower than 1.6; and ii. separating at least a portion of the precipitate from the solution.

摘要翻译： 本发明提供了通过形成纯度为P2的钛 - 双盐沉淀物和纯度为P3的钛溶液（其中P2> P1> P3），纯化P1纯钛进料流的工业纯化方法，该方法包括 步骤：i。 从进料形成包含水，钛离子，选自铵，碱金属阳离子，质子及其组合的阳离子和选自OH，SO 4，HSO 4， 形成介质的卤化物及其组合的特征还在于存在（a）包含钛离子，至少一种阳离子和至少一种阴离子的双盐沉淀物; 和（b）钛溶液; 并且其中钛溶液中阴离子的浓度高于15％，并且钛溶液中阳离子和阴离子的浓度之比高于0.2且低于1.6; 和ii。 从溶液中分离出至少一部分沉淀物。

公开(公告)号：US09476106B2

公开(公告)日：2016-10-25

申请号：US13807479

申请日：2011-06-28

申请人： Aharon Eyal ,  Robert Jansen ,  Asher Vitner ,  Revital Mali

发明人： Aharon Eyal ,  Robert Jansen ,  Asher Vitner ,  Revital Mali

IPC分类号： C13K11/00 ,  C13K1/02 ,  C13K13/00 ,  C13B10/02 ,  C13B5/04

CPC分类号： C13K11/00 ,  C13B5/04 ,  C13B10/02 ,  C13K1/02 ,  C13K13/00 ,  C13K13/002

摘要： A method comprising: (a) providing a partially processed sucrose crop product containing at least 2% optionally at least 5% of the sucrose content of said crop at harvest on a dry solids basis, cellulose and lignin; (b) hydrolyzing said partially processed crop product with HCl to produce an acid hydrolyzate stream and a lignin stream; and (c) de-acidifying said hydrolyzate stream to produce a de-acidified sugar solution and an HCl recovery stream. Additional, methods, systems and sugar mixtures are also disclosed.

摘要翻译： 一种方法，包括：（a）提供部分加工的蔗糖作物产品，其在干固体收获时提供含有至少2％任选至少5％的所述作物蔗糖含量的纤维素和木质素; （b）用HCl水解所述部分加工的作物产物以产生酸水解产物流和木质素流; 和（c）使所述水解产物流脱酸以产生脱酸糖溶液和HCl回收流。 还公开了方法，系统和糖混合物。

公开(公告)号：US20130028833A1

公开(公告)日：2013-01-31

申请号：US13577215

申请日：2011-02-06

申请人： Aharon Eyal ,  Asher Vitner ,  Revital Mali

发明人： Aharon Eyal ,  Asher Vitner ,  Revital Mali

IPC分类号： C01B7/01 ,  C09K3/00

CPC分类号： C01B7/0737

摘要： The present invention provides an organic phase composition comprising (f) a first solvent (S1) characterized by water solubility of less than 10% and by at least one of (a1) having a polarity related component of Hoy's cohesion parameter (delta-P) between 5 and 10 mPa1/2 and (b1) having a Hydrogen bonding related component of Hoy's cohesion parameter (delta-H) between 5 and 20 MPa1/2; (g) a second solvent (S2) characterized by water solubility of at least 30% and by at least one of (a2) having a delta-P greater than 8 MPa1/2 and (b2) having a delta-H greater than 12 MPa1/2; (h) water (i) HCl, and (j) a chloride salt.

摘要翻译： 本发明提供一种有机相组合物，其包含（f）第一溶剂（S1），其特征在于水溶解度小于10％，和至少一种（a1）具有Hoy的内聚参数（Δ-P）的极性相关成分， 5和10mPa1 / 2之间，（b1）具有5至20MPa1 / 2的Hoy粘附参数（δ-H）的氢键相关组分; （g）第二溶剂（S2），其特征在于水溶解度为至少30％，并且至少一种具有δ-P大于8MPa1 / 2的（a2）和（b2）具有大于12的Δ-H MPa1 / 2; （h）水（i）HCl，和（j）氯化物盐。

公开(公告)号：US07700057B2

公开(公告)日：2010-04-20

申请号：US12083362

申请日：2006-10-15

申请人： Asher Vitner ,  Aharon Eyal ,  Revital Mali

发明人： Asher Vitner ,  Aharon Eyal ,  Revital Mali

IPC分类号： C01G23/00 ,  C01G23/047 ,  C01G23/053

CPC分类号： C01G23/002 ,  B82Y30/00 ,  C01G23/008 ,  C01G23/04 ,  C01G23/0532 ,  C01G49/009 ,  C01G49/14 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/80

摘要： The invention provides a method for the Industrial purification of a titanium feed stream of purity P1, by the formation of a titanium-double-salt precipitate of purity P2 and a titanium solution with purity P3, wherein P2>P1>P3, the method comprising the steps of: i. forming, from the feed, a medium comprising water, titanium ion, a cation selected from the group consisting of ammonium, cations of alkali metals, protons and a combination thereof, and an anion selected from the group consisting of OH, SO4, HSO4, halides and a combination thereof, which formed medium is further characterized by the presence of (a) a double-salt precipitate comprising titanium ion, at least one of the cations and at least one of the anions; and (b) a titanium solution; and wherein the concentration of the anion in the titanium solution is higher than 15% and the ratio between the concentrations of the cation and the anion in the titanium solution is higher than 0.2 and lower than 1.6; and ii. separating at least a portion of the precipitate from the solution.

摘要翻译： 本发明提供了通过形成纯度为P2的钛 - 双盐沉淀物和纯度为P3的钛溶液（其中P2> P1> P3），纯化P1纯钛进料流的工业纯化方法，该方法包括 步骤：i。 从进料形成包含水，钛离子，选自铵，碱金属阳离子，质子及其组合的阳离子和选自OH，SO 4，HSO 4， 形成介质的卤化物及其组合的特征还在于存在（a）包含钛离子，至少一种阳离子和至少一种阴离子的双盐沉淀物; 和（b）钛溶液; 并且其中钛溶液中阴离子的浓度高于15％，并且钛溶液中阳离子和阴离子的浓度之比高于0.2且低于1.6; 和ii。 从溶液中分离出至少一部分沉淀物。

公开(公告)号：US09410216B2

公开(公告)日：2016-08-09

申请号：US13378657

申请日：2011-06-26

申请人： Aharon Meir Eyal ,  Robert P. Jansen ,  Revital Mali ,  Asher Vitner

发明人： Aharon Meir Eyal ,  Robert P. Jansen ,  Revital Mali ,  Asher Vitner

IPC分类号： C13K1/02 ,  C12P7/10 ,  C12P19/02 ,  C12P19/14

CPC分类号： C12N1/22 ,  A23V2002/00 ,  C12P7/10 ,  C12P19/02 ,  C12P19/14 ,  C12P2203/00 ,  C13K1/02 ,  C13K7/00 ,  C13K13/00 ,  Y02E50/13 ,  Y02E50/16 ,  Y02E50/17 ,  A23V2250/60

摘要： A sugar mixture comprising: monosaccharides; oligosaccharides in a ratio ≧0.06 to total saccharides; disaccharides in a ratio to total saccharides ≧0.05; pentose in a ratio to total saccharides ≧0.05; at least one alpha-bonded di-glucose; and at least one beta-bonded di-glucose. Also disclosed are methods to make and/or use such mixtures.

摘要翻译： 一种糖混合物，其包含：单糖; 比例≥0.06的寡糖总糖; 二糖与总糖的比例≥0.05; 戊糖与总糖的比例≥0.05; 至少一种α-键合的二葡萄糖; 和至少一种β-键合的二葡萄糖。 还公开了制备和/或使用这种混合物的方法。

公开(公告)号：US20120264873A1

公开(公告)日：2012-10-18

申请号：US13378657

申请日：2011-06-26

申请人： Aharon Meir Eyal ,  Robert P. Jansen ,  Revital Mali ,  Asher Vitner

发明人： Aharon Meir Eyal ,  Robert P. Jansen ,  Revital Mali ,  Asher Vitner

IPC分类号： C13B50/00 ,  C12P7/02 ,  C12P7/40 ,  C12P13/04 ,  C12P7/06 ,  C12P7/16 ,  C12P7/64 ,  C12P7/04 ,  C12P7/14 ,  C12P21/00 ,  C08F10/02 ,  C08F10/06 ,  C08G63/08 ,  C08G63/02 ,  C08F20/12 ,  C09D133/08 ,  C13K13/00

CPC分类号： C12N1/22 ,  A23V2002/00 ,  C12P7/10 ,  C12P19/02 ,  C12P19/14 ,  C12P2203/00 ,  C13K1/02 ,  C13K7/00 ,  C13K13/00 ,  Y02E50/13 ,  Y02E50/16 ,  Y02E50/17 ,  A23V2250/60

摘要： A sugar mixture comprising: monosaccharides; oligosaccharides in a ratio ≧0.06 to total saccharides; disaccharides in a ratio to total saccharides ≧0.05; pentose in a ratio to total saccharides ≧0.05; at least one alpha-bonded di-glucose; and at least one beta-bonded di-glucose. Also disclosed are methods to make and/or use such mixtures.

摘要翻译： 一种糖混合物，其包含：单糖; 比例≥0.06的寡糖总糖; 二糖与总糖的比例≥0.05; 戊糖与总糖的比例≥0.05; 至少一种α-键合的二葡萄糖; 和至少一种β-键合的二葡萄糖。 还公开了制备和/或使用这种混合物的方法。

公开(公告)号：US06344348B1

公开(公告)日：2002-02-05

申请号：US09284234

申请日：1999-11-22

申请人： Aharon Eyal ,  Robert J. Jansen ,  Asher Vitner ,  Pierre Cami ,  Emmanuel Mailly ,  Thomas Chattaway ,  Bruno Jarry ,  Joelle More

发明人： Aharon Eyal ,  Robert J. Jansen ,  Asher Vitner ,  Pierre Cami ,  Emmanuel Mailly ,  Thomas Chattaway ,  Bruno Jarry ,  Joelle More

IPC分类号： C12P1320

CPC分类号： C12P13/20 ,  C08G73/1092

摘要： The invention provides a process for the production of aspartic acid poly-condensate from a carbohydrate comprising the steps of: fermenting a carbohydrate-containing medium by means of a fumaric acid-producing microorganism, whereby a fumarate-containing fermentation liquor is formed; forming a purified ammonium fumarate solution from the fumarate-containing fermentation liquor; enzymatically converting the purified ammonium fumarate into purified ammonium aspartate; heating an aqueous solution of an aspartate salt derived from the purified ammonium aspartate whereby water is removed, an aspartic acid condensate is formed and a second product is formed, which second product is basic and contains the cation of the aspartate salt; and removing and using the basic second product as a reagent in another step of the process.

摘要翻译： 本发明提供了一种从碳水化合物制备天冬氨酸聚缩合物的方法，包括以下步骤：通过产生富马酸的微生物发酵含碳水化合物的培养基，从而形成含富马酸的发酵液; 从含富马酸的发酵液中形成纯化的富马酸铵溶液; 将纯化的富马酸铵酶促转化成纯天然天冬氨酸铵; 加热源自纯化天冬氨酸铵的天冬氨酸盐的水溶液，由此除去水，形成天冬氨酸缩合物并形成第二产物，该第二产物是碱性的，并含有天冬氨酸盐的阳离子; 以及在该方法的另一步骤中除去和使用碱性第二产物作为试剂。