公开(公告)号：US20230322576A1

公开(公告)日：2023-10-12

申请号：US18298863

申请日：2023-04-11

申请人： Purdue Research Foundation

发明人： Rakesh Agrawal ,  Apurva Ajit Pradhan ,  Jonathan William Turnley ,  Suzanne C. Bart ,  Madeleine Claire Uible

IPC分类号： C01G25/06 ,  C01G27/06

CPC分类号： C01G25/06 ,  C01G27/06 ,  C01P2002/70 ,  C01P2002/82 ,  C01P2002/34

摘要： Methods for synthesizing chalcogenide perovskites and chalcogenide perovskites synthesized thereby. Such s method includes providing a precursor solution containing a metal precursor, depositing the precursor solution onto a substrate to form a precursor film, and heating the precursor film in the presence of a chalcogen source to form a chalcogenide perovskite. The precursor solution is oxygen-free, and the steps of depositing and heating are conducted in an inert atmosphere.

公开(公告)号：US07642210B2

公开(公告)日：2010-01-05

申请号：US11188495

申请日：2005-07-25

申请人： Hiroshi Okamoto

发明人： Hiroshi Okamoto

IPC分类号： C01G23/00 ,  C01G25/00 ,  C01G27/00 ,  C01G23/02 ,  C01G25/04 ,  C01G25/06 ,  C01G27/02 ,  C22B34/10 ,  C04B35/48 ,  C04B35/49 ,  B01J21/00 ,  B01J23/02 ,  B01J23/06

CPC分类号： C04B35/486 ,  B01D53/885 ,  B01J21/066 ,  B01J23/10 ,  B01J23/63 ,  B01J23/745 ,  B01J27/053 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J37/033 ,  C01G25/02 ,  C01P2002/60 ,  C01P2006/12 ,  C01P2006/13 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C04B38/0064 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3272 ,  C04B2235/448 ,  C04B35/48 ,  C04B38/0054

摘要： A zirconia porous body with excellent stability of heat resistance is manufactured. This relates to a zirconia porous body having peaks at pore diameters of 8 to 20 nm and 30 to 100 nm in a pore distribution based on the BJH method, with a total pore volume of 0.4 cc/g or more, and to a zirconia porous body having a peak at a pore diameters of 20 to 110 nm in a pore distribution based on the BJH method, with a total pore volume of 0.4 cc/g or more.

摘要翻译： 制造具有优异的耐热稳定性的氧化锆多孔体。 本发明涉及一种氧化锆多孔体，其孔径分布为8〜20nm，孔径分布为30〜100nm，基于BJH法，总孔体积为0.4cc / g以上，氧化锆多孔体 基于BJH法在孔分布中具有孔径为20〜110nm的峰，其总孔体积为0.4cc / g以上。

公开(公告)号：US2525474A

公开(公告)日：1950-10-10

申请号：US9405749

申请日：1949-05-18

申请人： NAT LEAD CO

发明人： BLUMENTHAL WARREN B

IPC分类号： C01G25/06

CPC分类号： C01G25/06

公开(公告)号：US1586241A

公开(公告)日：1926-05-25

申请号：US72617224

申请日：1924-07-15

申请人： PHILIPS NV

发明人： DIRK COSTER ,  VON HEVESY GEORG

IPC分类号： C01G25/06

CPC分类号： C01G25/06

公开(公告)号：US20110092740A1

公开(公告)日：2011-04-21

申请号：US12741655

申请日：2008-11-07

申请人： Francois Figueras ,  Abhay Deshpande ,  Lakshmi Kantam Mannepalli ,  Jeeva Ratnam Katuri ,  Sudarshan Reddy Ragireddy ,  Subrahmanya Sekhar Nujilla

发明人： Francois Figueras ,  Abhay Deshpande ,  Lakshmi Kantam Mannepalli ,  Jeeva Ratnam Katuri ,  Sudarshan Reddy Ragireddy ,  Subrahmanya Sekhar Nujilla

IPC分类号： C07C213/00 ,  C01G25/06

CPC分类号： B01J23/40 ,  B01J27/053 ,  B01J35/0006 ,  C01G25/02 ,  C01G25/06 ,  C01G55/00 ,  C07C213/00 ,  C07C215/76

摘要： The method of using a bi-functional catalyst for the one-step preparation of para-aminophenol. The catalyst includes a mixture of a hydrogenation noble metal and a zirconium sulfate. Also, an improved single-step process for the preparation of para-aminophenol from nitrobenzene, in an aqueous medium, using the bi-functional catalyst.

摘要翻译： 使用双官能催化剂一步制备对氨基苯酚的方法。 催化剂包括氢化贵金属和硫酸锆的混合物。 而且，使用双官能催化剂，在水介质中由硝基苯制备对氨基苯酚的改进的单步方法。

公开(公告)号：US20070264178A1

公开(公告)日：2007-11-15

申请号：US11412816

申请日：2006-04-27

申请人： Harry Flynn ,  Leslie Crowder

发明人： Harry Flynn ,  Leslie Crowder

IPC分类号： C01G25/06

CPC分类号： C22B34/1222 ,  C02F2101/20 ,  C22B3/22 ,  C22B7/006 ,  C22B7/02 ,  C22B34/1259 ,  Y02P10/23 ,  Y02P10/234

摘要： A process is provided for handling waste solids produced from the chlorination of titanium-bearing ores in the presence of coke as a reducing agent, in particular waste metal chloride solids from a chloride process for making pigmentary titanium dioxide, which process comprises cooling the product stream from chlorination, separating the solids therein from the gaseous components of the product stream, combining the waste metal chloride solids and unreacted ore and coke solids with a liquid whereby waste metal chloride solids are dissolved in the liquid and unreacted ore and coke solids are slurried in the liquid, separating out unreacted ore and coke solids from the liquid including the dissolved waste metal chlorides, then after separating out unreacted ore and coke solids from the liquid, dividing the liquid including the dissolved waste metal chlorides into a recycle substream or portion and a bleed substream or portion, recycling the recycle substream or portion to comprise at least a part of the liquid which is combined with the waste metal chloride solids and unreacted ore and coke solids in the product stream, and neutralizing the bleed substream or portion to produce a filterable or directly landfillable mass of waste metal hydroxide solids.

摘要翻译： 提供了一种方法，用于处理在作为还原剂的焦炭存在下的含钛矿石的氯化产生的废物固体，特别是用于制备颜料二氧化钛的氯化物方法的废金属氯化物固体，该方法包括冷却产物流 从氯化中分离其中的固体与产物流的气体组分，将废金属氯化物固体和未反应的矿石和焦炭固体与液体混合，由此将废金属氯化物固体溶解在液体中，未反应的矿石和焦炭固体在 液体，从包括溶解的废金属氯化物的液体中分离未反应的矿石和焦炭固体，然后从液体中分离未反应的矿石和焦炭固体后，将包含溶解的废金属氯化物的液体分成循环子流或部分， 泄放子流或部分，循环再循环子流或部分以包括在lea 这是液体的一部分，其与废金属氯化物固体和产物流中的未反应的矿石和焦炭固体相结合，并且中和排放子流或部分以产生可过滤或直接可填埋的废金属氢氧化物固体块。

公开(公告)号：US3672825A

公开(公告)日：1972-06-27

申请号：US3672825D

申请日：1970-02-16

申请人： TIZON CHEM CORP

发明人： GAMBALE JAMES RICHARD ,  MCINTYRE GLENN HAZEL JR ,  RANNEY FREDRIK J

IPC分类号： C01G25/00 ,  C01G25/06 ,  C22B59/00

CPC分类号： C01G25/06 ,  C01G25/00

摘要： A PROCESS IS PROVIDED FOR PREPARING ZIRCONIUM SULFATES BY FUSING A ZIRCONIUM SILICEOUS ORE, SUCH AS ZIRCON SAND, WITH AN ALKALI METAL CARBONATE OR HYDROZIDE TO FORM AN ALKALI METAL ZIRCONYLOSILICATE, AND/OR ALKALI METAL ZIRCONATE, AND SILICATE, WHICH IS DISSOLVED IN AQUEOUS HYDROCHLORIC ACID TO FORM A CLEAR SOLUTION OF ZIRCONYL CHLORIDE AND SILICIC ACID. AN AQUEOUS SULFATE SOLUTION IS ADDED, AND THE MIXTURE HEATED TO RPECIPITATE A ZIRCONIUM SULFATE. THIS CAN BE CALCINED TO FORM ZIRCONIUM OXIDE. IF FLUORIDE IS ADDED WITH THE SULFATE SOLUTION, A SERIES OF BASIC AND ACIDIC ZIRCONIUM FLUOSULFATES CAN BE OBTAINED USEFUL AS A GLASS POLISHING ADDITIVE. THE ZIRCONIUM FLUOSULFATES CAN ALSO BE CALCINED, TO FORM A VERY PURE ZIRCONIUM OXIDE. A PROCESS ALSO IS PROVIDED FOR PREPARING A ZIRCONIUM OXIDE HAVING A VERY LOW PROPORTION OF SILICA, BY CALCINING A ZIRCONIUM COMPOUND COMPRISING SILICA IN THE PRESENCE OF FLUORINE OR A FLUORIDE.

公开(公告)号：US3419587A

公开(公告)日：1968-12-31

申请号：US45652665

申请日：1965-05-17

申请人： HARDMAN & HOLDEN LTD

发明人： EDWARD HARSON SAMUEL

IPC分类号： C01G25/00 ,  C01G25/06 ,  C07B61/00 ,  C07C51/41 ,  C07F7/00 ,  C07F7/28 ,  C07F9/02 ,  C07F13/00 ,  C07F15/04 ,  C07F15/06 ,  C08K5/00 ,  C08K5/56 ,  C22B3/26 ,  C22B3/32 ,  C22B3/40

CPC分类号： C07F15/045 ,  C01G25/003 ,  C01G25/006 ,  C01P2002/02 ,  C01P2006/60 ,  C07F7/006 ,  C07F13/005 ,  C07F15/065 ,  C08K5/0091 ,  C08K5/56 ,  C10M1/08 ,  C10M2207/022 ,  C10M2207/121 ,  C10M2207/122 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2207/16 ,  C10M2207/18 ,  C10M2207/282 ,  C10M2207/34 ,  C10M2209/103 ,  C10M2209/108 ,  C10M2211/024 ,  C10M2211/06 ,  C10M2211/08 ,  C10M2219/044 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2227/065 ,  C10N2210/00 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2210/04 ,  C10N2210/07 ,  C10N2210/08 ,  C22B3/0024 ,  C22B3/0032 ,  C22B3/0095 ,  Y02P10/234

摘要： Metal-organic compounds or complexes are prepared by heating zirconyl carbonate with at least one monocarboxylic acid and further reacting with at least one divalent metal as a metal powder, oxide, hydroxide or carbonate, and distilling off the water formed. Calcium, strontium, barium, zinc, cadmium, magnesium, manganese, iron, nickel, cobalt, lead, mercury and copper are the metals and acetic, propionic, 2-ethyl hexoic, methacrylic, naphthenic, tall oil, or synthetic branched chain C8-C10 acids are mentioned. Additional acids may be alkyl or aryl phosphoric or phosphorous acid or sulphonic acids and phenols or alkyl phenols may be added to the reaction mixture and glycol or glycol ethers added to the product. The products have good compatability with organic media and may be used as driers, in surface coating compositions and as stabilizers for polymers, e.g. polyvinyl chloride.

公开(公告)号：US1460766A

公开(公告)日：1923-07-03

申请号：US32241519

申请日：1919-09-08

申请人： RICH MALCOLM N

发明人： RICH MALCOLM N

IPC分类号： C01G25/06

CPC分类号： C01G25/06

公开(公告)号：US11066726B2

公开(公告)日：2021-07-20

申请号：US15548334

申请日：2016-02-08

申请人： ILUKA Resources Limited

发明人： Phillip James Dundas

IPC分类号： C22B34/14 ,  C22B9/10 ,  C04B35/626 ,  C04B35/48 ,  C01G49/14 ,  C01G23/00 ,  C01G25/06 ,  C01B33/20 ,  C22B3/08

摘要： A process for improving the grade and optical quality of zircon, comprising: baking a mixture of a zircon feed and concentrated sulphuric acid at a baking temperature in the range of from 200 up to 400° C., and for a time to form water leachable sulphates with impurities therein including at least iron and titanium; leaching the baked mixture to dissolve the leachable sulphates; and separating the zircon from the leachate containing the leached sulphates, which separated zircon is thereby of improved grade and optical quality.