公开(公告)号：US06806002B2

公开(公告)日：2004-10-19

申请号：US09878356

申请日：2001-06-12

申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

IPC分类号： H01M462

CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料的粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂。 电解质组合物包括由聚醚和至少第二聚合物基质组成的宏观分离的第一聚合物基质，以及至少一种碱性盐以及极性非质子溶剂。聚合物基质能够被至少一种 的极性非质子溶剂。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。

公开(公告)号：US06280882B1

公开(公告)日：2001-08-28

申请号：US09142055

申请日：1998-12-14

申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

IPC分类号： H01M614

CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂电解组合物包括由聚醚 和至少第二聚合物基质，宏观上分离的，以及至少一种碱性盐以及极性非质子传递溶剂。聚合物基质能够被至少一种极性非质子传递溶剂溶胀。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。

公开(公告)号：US20070243467A1

公开(公告)日：2007-10-18

申请号：US11808353

申请日：2007-06-08

申请人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

IPC分类号： H01M4/48 ,  C01G23/04 ,  H01G9/04

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, preferably having a spinel structure, wherein β is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), a representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.

摘要翻译： Li 4 N 5 O 12的新颗粒的合成方法，Li（S-4-α）Z _{5 5 β优选具有尖晶石结构，其中β大于0且小于或等于0.5（优选具有尖晶石结构），表示大于零的数 并且小于或等于0.33，Z代表至少一种金属的源，优选选自由Mg，Nb，Al，Zr，Ni，Co组成的组。涂覆有碳层的这些颗粒特别表现出电化学性质 这在电化学发生器中作为阳极和/或阴极的组分是特别有意义的。}

公开(公告)号：US06265099B1

公开(公告)日：2001-07-24

申请号：US09058895

申请日：1998-04-13

申请人： Michel Gauthier ,  Michel Armand ,  Karim Zaghib ,  Sylvain Poirier ,  Roger Bellemare

发明人： Michel Gauthier ,  Michel Armand ,  Karim Zaghib ,  Sylvain Poirier ,  Roger Bellemare

IPC分类号： H01M612

CPC分类号： H01M4/587 ,  H01M4/13 ,  H01M4/38 ,  H01M4/42 ,  H01M4/46 ,  H01M4/742

摘要： An electrochemical generator comprising thin films including a positive electrode and its collector, and a sheet of a host metal intended to later on constitute a negative electrode, as well as an electrolyte which is conductive towards alkaline ions and also a source of alkali ions. The sheet of the host metal has voids whose quantity and arrangement are capable of locally absorbing any lateral expansion of the sheet of host metal and thereby substantially preventing all cumulative change in the plane of the sheet of host metal when there is an initial formation of alloy in the sheet between the host metal and an alkali metal which is brought about by the alkaline ions. A method of manufacturing such a generator is also described.

摘要翻译： 一种电化学发生器，其包括包括正极及其集电体的薄膜和旨在稍后构成负极的主体金属片以及对碱性离子和碱离子源导电的电解质。 主体金属片具有空隙，其数量和布置能够局部地吸收主体金属片的任何横向膨胀，从而基本上防止当初始形成合金时主体金属片的平面的所有累积变化 在主体金属和由碱性离子引起的碱金属之间的片材中。 还描述了制造这种发生器的方法。

公开(公告)号：US09077031B2

公开(公告)日：2015-07-07

申请号：US13360173

申请日：2012-01-27

申请人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

IPC分类号： B05D5/12 ,  H01M4/485 ,  B82Y30/00 ,  C01G23/00 ,  H01G9/00 ,  H01M4/04 ,  H01M4/131 ,  H01M4/136 ,  H01M4/36 ,  H01M4/58 ,  H01M4/62 ,  H01M4/74 ,  H01M10/0525 ,  H01M4/02 ,  H01M4/505 ,  H01M4/525 ,  H01M4/66 ,  H01M10/0562 ,  H01M10/0565

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, wherein β is >0 and ≦0.5, α is a number >0 and ≦0.33, Z is a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators. The process may involve the steps of a) preparing a dispersion of a mixture of TiOx—LizY-carbon, wherein x is a number between 1 and 2, z is 1 or 2, and Y is a radical chosen among CO3, OH, O and TiO3 or a mixture thereof; and 2) heating of the dispersion, preferably to a temperature of between about 400° C. and about 1000° C.

摘要翻译： Li4Ti5O12，Li（4-α）ZαTi5O12或Li4Z＆bgr; Ti（5-＆bgr）O12的新颗粒的合成工艺，其中＆bgr; 是> 0和＆nlE; 0.5，α是数> 0和＆nlE; 0.33，Z是至少一种金属的源，优选选自由Mg，Nb，Al，Zr，Ni，Co组成的组。 涂覆有碳层的颗粒特别表现出电化学特性，其特别令人感兴趣的是作为电化学发生器中阳极和/或阴极的组分。 该方法可以包括以下步骤：a）制备TiOx-LizY-碳的混合物的分散体，其中x是1和2之间的数，z是1或2，Y是选自CO 3，OH，O 和TiO 3或其混合物; 和2）分散体的加热，优选至约400℃至约1000℃的温度

公开(公告)号：US20070194158A1

公开(公告)日：2007-08-23

申请号：US11790020

申请日：2007-04-23

申请人： Karim Zaghib ,  Michel Gauthier ,  Gabrielle Nadeau ,  Abdelbast Guerfi ,  Monique Masse ,  Fernand Brochu ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Gabrielle Nadeau ,  Abdelbast Guerfi ,  Monique Masse ,  Fernand Brochu ,  Michel Armand

IPC分类号： B02C19/00 ,  C01B31/04

CPC分类号： H01M4/583 ,  C01B32/215 ,  H01M4/133 ,  H01M10/0525

摘要： The present invention relates to the physical or chemical specific purification of natural mineral graphite. This purification is preferably applied to the surface of natural graphite in order to allow the formation of a passivation film during the first electrical discharge or the insertion of lithium in the graphite when the latter is used in a lithium-ion cell. The grinding to a small size before purification allows the optimization of the distribution of the particles, resulting in a more uniform electrode. This grinding is carried out in the presence of the natural impurities of the graphite that play the role of a micro-abrasive and result in a hardness of the graphite that increases its mechanical properties.

摘要翻译： 本发明涉及天然矿物石墨的物理或化学特异性纯化。 优选将该纯化施加到天然石墨的表面，以便在锂离子电池中使用时，在石墨中的第一次放电或锂的插入期间允许形成钝化膜。 在纯化之前研磨至小尺寸允许优化颗粒的分布，导致更均匀的电极。 这种研磨是在发生微磨料作用的石墨的天然杂质的存在下进行的，并导致石墨的硬度增加其机械性能。

公开(公告)号：US20120135311A1

公开(公告)日：2012-05-31

申请号：US13360173

申请日：2012-01-27

申请人： Karim ZAGHIB ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Massé ,  Michel Armand

发明人： Karim ZAGHIB ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Massé ,  Michel Armand

IPC分类号： H01M4/131 ,  H01G9/155 ,  C01D15/02 ,  H01B1/08 ,  B82Y40/00 ,  B82Y30/00

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, preferably having a spinel structure, wherein β is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), α representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.

摘要翻译： Li4Ti5O12，Li（4-α）ZαTi5O12或Li4Z＆bgr; Ti（5-＆bgr））O12的新颗粒的合成方法，优选具有尖晶石结构，其中＆bgr; 大于0且小于或等于0.5（优选具有尖晶石结构），α表示大于零且小于或等于0.33的数，Z表示至少一种金属的来源，优选选自所制成的组 Mg，Nb，Al，Zr，Ni，Co这些颗粒被涂覆了一层碳，特别表现出电化学特性，作为电化学发生器中阳极和/或阴极的组分是特别有意义的。

公开(公告)号：US08114469B2

公开(公告)日：2012-02-14

申请号：US12149535

申请日：2008-05-02

申请人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

IPC分类号： B05D5/12

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： A process for synthesizing particles of an oxide corresponding to a formula selected from: Li4Ti5O12; Li(4-α)ZβTi5O12; and Li4ZαTi(5-β)O12, said process including the steps of: a) preparing an intimately dispersed ternary mixture of TiOx—LiZY-carbon, wherein x is a number between 1 and 2, z is 1 or 2, Y is a radical chosen from the group consisting of CO3, OH, O and TiO3 or a mixture thereof, and the carbon is a carbon powder selected from the group consisting of natural or artificial graphite, carbon black, Shawinigan black, Ketjen black and cokes; b) heating the dispersion at a temperature of between 400 and 1,000° C.; and c) if appropriate, adding a source of at least one metal Z to the ternary mixture, wherein the operating conditions are chosen in such a way as to yield a conversion of the initial products respectively into Li4Ti5O12, Li(4-α)ZαTi5O12, Li4ZβTi(5-β)O12.

摘要翻译： 一种合成相应于下式的氧化物颗粒的方法：Li 4 Ti 5 O 12; Li（4-α）Z＆bgr; Ti5O12; 所述方法包括以下步骤：a）制备紧密分散的TiOx-LiZY-碳的三元混合物，其中x是1和2之间的数，z是1或2，Y是 选自CO 3，OH，O和TiO 3或其混合物的基团，碳是选自天然或人造石墨，炭黑，Shawinigan黑，Ketjen黑和焦炭的碳粉末; b）在400-1000℃的温度下加热分散体; 并且c）如果合适，向三元混合物中加入至少一种金属Z的源，其中选择操作条件以分别将初始产物分别转化为Li 4 Ti 5 O 12，Li（4-α）ZαTi5 O 12 ，Li4Z＆bgr; Ti（5-＆bgr））O12。

公开(公告)号：US07993621B2

公开(公告)日：2011-08-09

申请号：US11790020

申请日：2007-04-23

申请人： Karim Zaghib ,  Michel Gauthier ,  Gabrielle Nadeau ,  Abdelbast Guerfi ,  Monique Massé ,  Fernand Brochu ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Gabrielle Nadeau ,  Abdelbast Guerfi ,  Monique Massé ,  Fernand Brochu ,  Michel Armand

IPC分类号： C01B31/04

CPC分类号： H01M4/583 ,  C01B32/215 ,  H01M4/133 ,  H01M10/0525

摘要： The present invention relates to the physical or chemical specific purification of natural mineral graphite. This purification is preferably applied to the surface of natural graphite in order to allow the formation of a passivation film during the first electrical discharge or the insertion of lithium in the graphite when the latter is used in a lithium-ion cell. The grinding to a small size before purification allows the optimization of the distribution of the particles, resulting in a more uniform electrode. This grinding is carried out in the presence of the natural impurities of the graphite that play the role of a micro-abrasive and result in a hardness of the graphite that increases its mechanical properties.

摘要翻译： 本发明涉及天然矿物石墨的物理或化学特异性纯化。 优选将该纯化施加到天然石墨的表面，以便在锂离子电池中使用时，在石墨中的第一次放电或锂的插入期间允许形成钝化膜。 在纯化之前研磨至小尺寸允许优化颗粒的分布，导致更均匀的电极。 这种研磨是在发生微磨料作用的石墨的天然杂质的存在下进行的，并导致石墨的硬度增加其机械性能。

公开(公告)号：US20080285211A1

公开(公告)日：2008-11-20

申请号：US12149535

申请日：2008-05-02

申请人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

IPC分类号： H01M4/48 ,  H01G9/155 ,  H01G9/04 ,  C01G23/04

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, preferably having a spinel structure, wherein β is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), α representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.

摘要翻译： Li 4 N 5 O 12的新颗粒的合成方法，Li（4-α）Z _{5 5 β优选具有尖晶石结构，其中β大于0且小于或等于0.5（优选具有尖晶石结构），α表示大于零的数 并且小于或等于0.33，Z代表至少一种金属的源，优选选自由Mg，Nb，Al，Zr，Ni，Co组成的组。涂覆有碳层的这些颗粒特别表现出电化学性质 这在电化学发生器中作为阳极和/或阴极的组分是特别有意义的。}