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    Electrolytic composition with polymer base for electrochemical generator
    1.
    发明授权
    Electrolytic composition with polymer base for electrochemical generator 失效
    电化学发生器用电解质组合物

    公开(公告)号：US06806002B2

    公开(公告)日：2004-10-19

    申请号：US09878356

    申请日：2001-06-12

    申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    IPC分类号： H01M462

    CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

    摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

    摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料的粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂。 电解质组合物包括由聚醚和至少第二聚合物基质组成的宏观分离的第一聚合物基质，以及至少一种碱性盐以及极性非质子溶剂。聚合物基质能够被至少一种 的极性非质子溶剂。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。

    Electrolytic composition with polymer base for electrochemical generator
    2.
    发明授权
    Electrolytic composition with polymer base for electrochemical generator 有权
    电化学发生器用电解质组合物

    公开(公告)号：US06280882B1

    公开(公告)日：2001-08-28

    申请号：US09142055

    申请日：1998-12-14

    申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    IPC分类号： H01M614

    CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

    摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

    摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂电解组合物包括由聚醚 和至少第二聚合物基质，宏观上分离的，以及至少一种碱性盐以及极性非质子传递溶剂。聚合物基质能够被至少一种极性非质子传递溶剂溶胀。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。

    Alloyed and dense anode sheet with local stress relaxation
    9.
    发明授权
    Alloyed and dense anode sheet with local stress relaxation 失效
    具有局部应力松弛的合金和致密阳极片

    公开(公告)号：US06265099B1

    公开(公告)日：2001-07-24

    申请号：US09058895

    申请日：1998-04-13

    申请人： Michel Gauthier ,  Michel Armand ,  Karim Zaghib ,  Sylvain Poirier ,  Roger Bellemare

    发明人： Michel Gauthier ,  Michel Armand ,  Karim Zaghib ,  Sylvain Poirier ,  Roger Bellemare

    IPC分类号： H01M612

    CPC分类号： H01M4/587 ,  H01M4/13 ,  H01M4/38 ,  H01M4/42 ,  H01M4/46 ,  H01M4/742

    摘要： An electrochemical generator comprising thin films including a positive electrode and its collector, and a sheet of a host metal intended to later on constitute a negative electrode, as well as an electrolyte which is conductive towards alkaline ions and also a source of alkali ions. The sheet of the host metal has voids whose quantity and arrangement are capable of locally absorbing any lateral expansion of the sheet of host metal and thereby substantially preventing all cumulative change in the plane of the sheet of host metal when there is an initial formation of alloy in the sheet between the host metal and an alkali metal which is brought about by the alkaline ions. A method of manufacturing such a generator is also described.

    摘要翻译： 一种电化学发生器，其包括包括正极及其集电体的薄膜和旨在稍后构成负极的主体金属片以及对碱性离子和碱离子源导电的电解质。 主体金属片具有空隙，其数量和布置能够局部地吸收主体金属片的任何横向膨胀，从而基本上防止当初始形成合金时主体金属片的平面的所有累积变化 在主体金属和由碱性离子引起的碱金属之间的片材中。 还描述了制造这种发生器的方法。