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公开(公告)号：US4540515A
公开(公告)日：1985-09-10
申请号：US641773
申请日：1984-08-17
IPC分类号： C08G69/14 , C08G18/80 , C08G65/32 , C08G65/333 , C08G69/00 , C08G69/18 , C08G69/20 , C08G69/40 , C07D223/10
CPC分类号： C08G18/8074 , C08G65/33327 , C08G69/18 , C08G69/20 , C08G69/40
摘要： The invention concerns an N-substituted carbamoyl-lactam compound characterized by the formula: ##STR1## where in the formula: R is a polyol radical from a polyol having the formula R--(OH).sub.xi, where .sub.xi is an integer.gtoreq.2R' is an alkyl, whether or not cyclic aralkyl, alkaryl or aryl group, .sub.yi is an integer>0,(--L) is an unopened lactam ring and(--L--) is an opened lactam block. The compoundsare highly suited for use as activators in preparing nylon block copolymers.
摘要翻译： 本发明涉及一种N-取代的氨基甲酰基 - 内酰胺化合物，其特征在于下式：其中在下式中：R是具有式R-（OH）xi的多元醇的多元醇基团，其中xi是整数> 2 R'是烷基，无论是环状芳烷基，烷芳基还是芳基，yi是> 0的整数，（-L）是未开封的内酰胺环，（-L-）是开放的内酰胺嵌段。 该化合物非常适合用作制备尼龙嵌段共聚物的活化剂。
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2.发明授权Process for the preparation of an N-substituted carbamoyl-lactam compound 失效制备N-取代氨基甲酰基 - 内酰胺化合物的方法
公开(公告)号：US4540516A
公开(公告)日：1985-09-10
申请号：US641772
申请日：1984-08-17
CPC分类号： C08G69/18 , C08G18/4825 , C08G18/8074 , C08G69/00 , C08G69/16 , C08G69/20
摘要： The invention concerns a simple, reliable and reproducable process for the preparation of an N-substituted carbamoyl lactam compound, for example of the following formula: ##STR1## where: R is a polyol originating from a polyol having the formula R-(OH).sub.xi, where.sub.xi is an integer.gtoreq.2R' is an alkyl, aralkyl, alkaryl or aryl group, whether or not cyclic,.sub.yi is an integer.gtoreq.0,(--L) is an unopened lactam ring and(--L--) is an opened lactam block.This process is characterized in that a polyol and a lactam blocked polyisocyanate are reacted in the liquid state in the presence of a metal compound catalyst.
摘要翻译： 本发明涉及用于制备N-取代的氨基甲酰基内酰胺化合物的简单，可靠和可再现的方法，例如下式：其中：R是源自具有式R-（OH） xi，其中xi是整数> / = 2 R'是烷基，芳烷基，烷芳基或芳基，无论是否是环状，yi是整数，其中（-L）是未开封的内酰胺环，（ - L-）是开放的内酰胺块。 该方法的特征在于，多元醇和内酰胺封端的多异氰酸酯在金属化合物催化剂的存在下以液态反应。
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3.发明授权Process for preparing a polymer alloy, molded product, and reaction injection molded products 失效制备聚合物合金，模制产品和反应注塑产品的方法
公开(公告)号：US4742128A
公开(公告)日：1988-05-03
申请号：US787139
申请日：1985-10-15
CPC分类号： C08L75/00 , C08G18/10 , C08G18/2855 , C08L77/02 , C08G2105/02 , C08G2120/00 , C08G2270/00 , Y10S525/903
摘要： The present invention provides a molded product composed of a polymer alloy of a polyamide polymer and at least one polyurethane polymer, polyurea polymer, and/or polyisocyanurate polymer. The polymer alloy is an interpenetrated network of different polymers, a semi-interpenetrating network of different polymers, or a polyblend of different polymers.Reactant streams containing the compounds for forming the polymers of the polymer alloy are admixed to form a reaction mixture. The liquid reaction mixture is preferably a substantially homogeneous mixture of the reactant compounds. Each reactant stream thus contains only a portion of the components required to obtain the polymer alloy product. The resulting mixture is then rapidly introduced into a mold wherein chemical reaction takes place and the polymer alloy forms. Preferably, the mold is heated. The solid polymer alloy product is then recovered from the mold.
摘要翻译： 本发明提供了由聚酰胺聚合物和至少一种聚氨酯聚合物，聚脲聚合物和/或聚异氰脲酸酯聚合物的聚合物合金构成的模塑产品。 聚合物合金是不同聚合物的互穿网络，不同聚合物的半互穿网络，或不同聚合物的聚合物。 将含有形成聚合物合金的聚合物的化合物的反应物流混合以形成反应混合物。 液体反应混合物优选为反应物化合物的基本上均匀的混合物。 因此，每个反应物流仅含有获得聚合物合金产品所需的部分组分。 然后将所得混合物快速引入模具，其中发生化学反应并形成聚合物合金。 优选地，模具被加热。 然后从模具中回收固体聚合物合金产品。
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4.发明授权
公开(公告)号：US4582879A
公开(公告)日：1986-04-15
申请号：US592081
申请日：1984-03-22
IPC分类号： B29C39/00 , B29C45/00 , C08G18/00 , C08G18/08 , C08G69/00 , C08G69/18 , C08L75/00 , C08L75/04 , C08L77/00 , C08L77/02
CPC分类号： C08L77/00 , C08G18/00 , C08L75/00 , C08G2120/00 , Y10S525/903
摘要： A reaction injection molding process is disclosed comprising:introducing a mixture of substantially stable reactant streams into a mold, said mixture, in the aggregate, containing polyamide polymer forming compounds and polyurethane polymer forming compounds, said polyamide polymer forming compounds including lactam, an anionic polymerization catalyst and a polymerization activator, said polyurethane polymer forming compounds including a polyol, a polyisocyanate, a chain extender if desired, and a polyurethane polymerization catalyst, said polyamide polymer forming compounds and said polyurethane forming compounds reacting to respectively form polyamide and polyurethane polymers in said mold to thereby yielding a reaction injection molded product composed of said polymers; andrecovering said product from said mold.
摘要翻译： 公开了一种反应注射成型方法，包括：将基本上稳定的反应物流的混合物引入模具中，所述混合物在聚集体中，含有聚酰胺聚合物形成化合物和形成聚氨酯聚合物的化合物，所述聚酰胺聚合物形成化合物包括内酰胺，阴离子聚合 催化剂和聚合活化剂，所述聚氨酯聚合物形成化合物，包括多元醇，多异氰酸酯，扩链剂，如果需要，和聚氨酯聚合催化剂，所述聚酰胺聚合物形成化合物和所述聚氨酯形成化合物在所述聚合反应中分别形成聚酰胺和聚氨酯聚合物 从而产生由所述聚合物组成的反应注塑产品; 并从所述模具中回收所述产品。
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公开(公告)号：US4340723A
公开(公告)日：1982-07-20
申请号：US218452
申请日：1980-12-19
CPC分类号： C08F6/22
摘要： An improved process for the preparation of copolymers of .alpha.-methylstyrene and other co-monomers such as acrylonitrile styrene, methyl methacrylate and the like, wherein a substantially water-immiscible softener is employed, particularly prior to coagulation of the latex formed of the copolymer, whereby an improved product of higher bulk density and easier to employ in a subsequent processing is obtained.
摘要翻译： 用于制备α-甲基苯乙烯和其它共聚单体如丙烯腈苯乙烯，甲基丙烯酸甲酯等的共聚物的改进方法，其中使用基本上与水不混溶的软化剂，特别是在由共聚物形成的胶乳凝结之前， 从而获得了在随后的处理中更高体积密度和更易于使用的改进的产品。
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6.发明授权Process for the preparation of a copolymer comprising alpha-methylstyrene and acrylonitrile 失效制备包含α-甲基苯乙烯和丙烯腈的共聚物的方法
公开(公告)号：US4536556A
公开(公告)日：1985-08-20
申请号：US548769
申请日：1983-11-04
IPC分类号： C08F212/12 , C08F212/10
CPC分类号： C08F212/12
摘要： An improved process for the preparation of heat resistant copolymers of an alpha-methylstyrene and acrylonitrile by polymerization thereof in aqueous emulsion, and in the presence of a free-radical-supplying compound and a chain-transfer agent. The polymerization reaction is insufficiently cooled to remove all of the released reaction heat, and in combination therewith the polymerization is conducted at a temperature of the aqueous emulsion maintained at a level of at most 110.degree., while further maintaining the mean rate of temperature increase per hour, v, at a value of at most 60.degree. C. per hour, wherein v is determined by the formula: ##EQU1## in which: T.sub.m =maximum temperature of the aqueous emulsion (.degree.C.),T.sub.o =temperature of the aqueous emulsion at the start of the polymerization (.degree.C.)t.sub.m =time in hours at which T.sub.m is reached, andt.sub.o =time in hours at which the polymerization is started whereby the rate of monomer conversion is maximized.
摘要翻译： 一种改进的α-甲基苯乙烯和丙烯腈的耐热共聚物的制备方法，其通过在水乳液中的聚合，以及在自由基供体化合物和链转移剂的存在下进行。 聚合反应不充分冷却以除去所有释放的反应热，并且与此相结合，聚合在水乳液的温度下保持在至多110℃的水平，同时进一步保持每平均温度升高 小时，v至多为60℃/小时，其中v由下式确定：其中：Tm =水乳液的最高温度（℃），To =温度 聚合开始时的水性乳液（℃）tm =达到Tm的时间（小时），以及=以聚合开始的时间（以小时为单位），由此单体转化率最大化。
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公开(公告)号：US4626385A
公开(公告)日：1986-12-02
申请号：US736257
申请日：1985-05-21
IPC分类号： C07D223/10 , C08G18/10 , C08G18/48 , C08G69/20 , C07D207/38 , C07D211/40
CPC分类号： C08G69/20 , C07D223/10 , C08G18/10 , C08G18/4854 , C08G2120/00
摘要： An N-substituted carbamoyl-lactam compound of the formula ##STR1## wherein R is a di-valent radical derived from polytetramethylene glycol, R' is an at least divalent radical derived from a diisocyanate, Y is a C.sub.3 -C.sub.14 ring-forming alkylene group, and a has a value of at least 1 and is a number corresponding to the mean functionality of the aforesaid polyisocyanate minus 1. A process for preparing the N-substituted carbamoyl-lactam compound is also described.
摘要翻译： 其中R是衍生自聚四亚甲基二醇的二价基团的N-取代的氨基甲酰基 - 内酰胺化合物，其中R是至少二价基团，其衍生自二异氰酸酯，Y是C 3 -C 14环成环亚烷基 并且a具有至少为1的值，并且是对应于上述多异氰酸酯的平均官能度减去1的数字。还描述了制备N-取代的氨基甲酰基 - 内酰胺化合物的方法。
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8.发明授权Polymer composition of .alpha.-methyl styrene/acrylonitrile copolymer and graft copolymer 失效α-甲基苯乙烯/丙烯腈共聚物和接枝共聚物的聚合物组成
公开(公告)号：US4404323A
公开(公告)日：1983-09-13
申请号：US276637
申请日：1981-06-23
IPC分类号： C08L55/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/00 , C08L25/16 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L55/02 , C08L101/00
摘要： The invention relates to a heat resistant polymer composition based on one or more graft copolymers of styrene and acrylonitrile on a rubber and a copolymer of .alpha.-methylstyrene and acrylonitrile.This composition comprises:A. A graft copolymer obtained by polymerizing 50-80 parts by weight of a monomer mixture consisting of20-40% by weight of acrylonitrile,50-80% by weight of styrene and0-30% by weight of one or more other monomers in the presence of 20-50 parts by weight of rubber (in respect of 100 parts by weight of graft copolymer) andB. a copolymer of .alpha.-methylstyrene and acrylonitrile obtained by polymerizing a mixture of 60-80 parts by weight of .alpha.-methylstyrene and 20-40 parts by weight of acrylonitrile, of which copolymer the spiral flow length (S) is at least 65 and the flow index (V) 45 at most, and the ratio between spiral flow length and the flow index is at least 3.0, and in which polymer composition 35 to 80% by weight of copolymer of .alpha.-methylstyrene and acrylonitrile is present.
摘要翻译： 本发明涉及一种基于一种或多种苯乙烯和丙烯腈在橡胶上的接枝共聚物和α-甲基苯乙烯与丙烯腈的共聚物的耐热聚合物组合物。 该组合物包含：A.通过聚合50-80重量份的由20-40重量％的丙烯腈，50-80重量％的苯乙烯和0-30重量％的丙烯酸酯组成的单体混合物而获得的接枝共聚物 或更多的其它单体，在20-50重量份的橡胶（相对于100重量份的接枝共聚物）的存在下，B是α-甲基苯乙烯和丙烯腈的共聚物，其通过将60-80份的混合物 α-甲基苯乙烯的重量和20-40重量份的丙烯腈，其共聚物的螺旋流动长度（S）至多为65，流动指数（V）为45以下，螺旋流动长度与流量之比 指数为3.0以上，聚合物组合物为α-甲基苯乙烯与丙烯腈共聚物的35〜80重量％。
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公开(公告)号：US4614615A
公开(公告)日：1986-09-30
申请号：US723309
申请日：1985-04-15
IPC分类号： C08G18/10 , C08G69/18 , C08G69/20 , C07D223/10 , C07D211/16 , C07D207/38
摘要： The invention relates to a process for preparing an N-substituted carbamoyl-lactam compound having the formula: ##STR1## by admixing a polyhydroxy compound having the formula R(OH).sub.n with a polyisocyanate having the formula OCH--R'--NCO, wherein saidn has a value of at least 3,R' is a di-valent hydrocarbon group having 6-25 carbon atoms, andY is a C.sub.3 -C.sub.14 alkylene group,and reacting the product thereof with a lactam. The n value may advantageously range from 3 to 10. The invention also relates to certain novel n-substituted carbamoyl-lactam compounds which can advantageously be used in the preparation of nylon 6 block copolymers, and are particularly useful in reaction injection molding nylon 6.
摘要翻译： 本发明涉及通过将具有式R（OH）n的多羟基化合物与具有式OCH-R'-NCO的多异氰酸酯混合制备具有下式的N-取代氨基甲酰基 - 内酰胺化合物的方法：其中 所述n的值至少为3，R'是具有6-25个碳原子的二价烃基，Y是C3-C14亚烷基，并使其产物与内酰胺反应。 n值可以有利地在3至10的范围内。本发明还涉及某些新颖的n-取代氨基甲酰基 - 内酰胺化合物，其可有利地用于制备尼龙6嵌段共聚物，并且特别适用于反应注射成型尼龙6。
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10.发明授权
公开(公告)号：US4200593A
公开(公告)日：1980-04-29
申请号：US925626
申请日：1978-07-17
IPC分类号： C08F2/00 , C08F2/16 , C08F2/18 , C08F212/00 , C08F212/06 , C08F212/10 , C08F220/00 , C08F220/42 , C08F279/00 , C08F279/04 , C08L9/00
CPC分类号： C08F2/18 , C08F279/04
摘要： An improved process for the preparation of copolymers by the polymerization of from about 25 to 85 parts by weight of a styrene and/or .alpha.-methylstyrene monomer together with about 15-75 parts by weight of acrylonitrile and/or methacrylonitrile monomer in an aqueous dispersion in the presence of a compound yielding free radicals is disclosed whereby the quantity of monomer remaining in the copolymer after polymerization is substantially reduced. A compound yielding water-soluble free radicals is added to the aqueous reaction medium, containing copolymer as well as non-converted monomer, in a quantity of between about 0.05 and 2.5 parts per 100 parts by weight of monomer and copolymer present in the reaction medium, at a point of time at which (a) the rate of conversion of monomer to copolymer is less than 15% per hour, (b) the degree of conversion of monomer to copolymer is greater than 75%, and (c) at least 0.1 weight percent of non-converted acrylonitrile and/or methacrylonitrile relative to the total weight of the reaction medium, remains in the reaction medium, and whereafter no additional monomer is added.
摘要翻译： 通过将约25至85重量份的苯乙烯和/或α-甲基苯乙烯单体与约15-75重量份的丙烯腈和/或甲基丙烯腈单体在水分散体中聚合制备共聚物的改进方法 公开了在产生自由基的化合物的存在下，聚合后残留在共聚物中的单体的量显着降低。 将含有共聚物和未转化的单体的水溶性自由基化合物加入含有共聚物和非转化单体的水性反应介质中，每100份重量的单体和存在于反应介质中的共聚物为约0.05至2.5份 在（a）单体向共聚物的转化率小于15％/小时的时间点，（b）单体向共聚物的转化率大于75％，（c）至少 0.1重量％的未转化的丙烯腈和/或甲基丙烯腈相对于反应介质的总重量保留在反应介质中，此后不加入另外的单体。
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