Process for preparing smoke-retardant polyisocyanurate foam
    1.
    发明授权
    Process for preparing smoke-retardant polyisocyanurate foam 失效
    制备阻燃聚异氰脲酸酯泡沫的方法

    公开(公告)号:US4514525A

    公开(公告)日:1985-04-30

    申请号:US665527

    申请日:1976-03-10

    摘要: In a process for preparing a smoke-retardant polyisocyanurate foam by reacting an organic polyisocyanate in the presence of a blowing agent and an isocyanate-trimerization catalyst, the improvement comprising conducting the reaction by adding 0.5 to 6 wt. % as Si to the total components of the foam of an organosilicone surfactant having a Si content of 4-22%, and selected from an organopolysiloxane-poly-oxyalkylene copolymer, polyvinylsilane having polyoxyalkylene side chain or modified products thereof wherein the mole % of the ethylene oxide units of the polyoxyalkylene moiety of the organosilicone surfactant is greater than 40 mole % based on the total number of ethylene oxide and propylene oxide units in said polyoxyalkylene moiety.

    摘要翻译: 在有机多异氰酸酯在发泡剂和异氰酸酯 - 三聚催化剂存在下反应制备阻燃聚异氰脲酸酯泡沫的方法,其改进包括通过加入0.5至6wt。 Si为Si含量为4〜22%的有机硅氧烷表面活性剂的总成分的Si,选自有机聚硅氧烷 - 聚 - 氧化烯共聚物,具有聚氧化烯侧链的聚乙烯基硅烷或其改性产物,其中摩尔% 基于所述聚氧化烯部分中的环氧乙烷和环氧丙烷单元的总数,有机硅氧烷表面活性剂的聚氧化烯部分的环氧乙烷单元大于40摩尔%。

    Process for preparing smoke-retardant polyisocyanurate foam
    2.
    发明授权
    Process for preparing smoke-retardant polyisocyanurate foam 失效
    制备阻燃聚异氰脲酸酯泡沫的方法

    公开(公告)号:US4072636A

    公开(公告)日:1978-02-07

    申请号:US663503

    申请日:1976-03-03

    IPC分类号: C08G18/02 C08J9/00 C08G18/14

    摘要: In a process for preparing a smoke-retardant polyisocyanurate foam by reacting an organic polyisocyanate in the presence of a blowing agent and an isocyanate-trimerization catalyst, an improvement is characterized in that the reaction is conducted in the presence of an organosilicate having the formula Si(OR).sub.4 or R.sub.n Si(OR').sub.4-n wherein R and R' are the same or different and represent aliphatic, alicyclic and aromatic hydrocarbon groups having 1-12 carbon atoms or substituted derivatives thereof and n is an integer of 1 to 3.

    摘要翻译: 在有机多异氰酸酯存在下,在发泡剂和异氰酸酯 - 三聚催化剂存在下,通过使有机多异氰酸酯反应来制备阻燃性聚异氰脲酸酯泡沫体的方法,其特征在于反应在具有式Si的有机硅酸盐存在下进行 (OR)4或RnSi(OR')4-n其中R和R'相同或不同,表示具有1-12个碳原子的脂族,脂环族和芳族烃基或其取代的衍生物,n是1〜 3。

    Process for preparing an N-substituted carbamoyl-lactam compound
    6.
    发明授权
    Process for preparing an N-substituted carbamoyl-lactam compound 失效
    制备N-取代氨基甲酰基 - 内酰胺化合物的方法

    公开(公告)号:US4614615A

    公开(公告)日:1986-09-30

    申请号:US723309

    申请日:1985-04-15

    CPC分类号: C08G69/20 C08G18/10 C08G69/18

    摘要: The invention relates to a process for preparing an N-substituted carbamoyl-lactam compound having the formula: ##STR1## by admixing a polyhydroxy compound having the formula R(OH).sub.n with a polyisocyanate having the formula OCH--R'--NCO, wherein saidn has a value of at least 3,R' is a di-valent hydrocarbon group having 6-25 carbon atoms, andY is a C.sub.3 -C.sub.14 alkylene group,and reacting the product thereof with a lactam. The n value may advantageously range from 3 to 10. The invention also relates to certain novel n-substituted carbamoyl-lactam compounds which can advantageously be used in the preparation of nylon 6 block copolymers, and are particularly useful in reaction injection molding nylon 6.

    摘要翻译: 本发明涉及通过将具有式R(OH)n的多羟基化合物与具有式OCH-R'-NCO的多异氰酸酯混合制备具有下式的N-取代氨基甲酰基 - 内酰胺化合物的方法:其中 所述n的值至少为3,R'是具有6-25个碳原子的二价烃基,Y是C3-C14亚烷基,并使其产物与内酰胺反应。 n值可以有利地在3至10的范围内。本发明还涉及某些新颖的n-取代氨基甲酰基 - 内酰胺化合物,其可有利地用于制备尼龙6嵌段共聚物,并且特别适用于反应注射成型尼龙6。

    Reaction injection molding process and reaction injection molded products
    8.
    发明授权
    Reaction injection molding process and reaction injection molded products 失效
    反应注射成型工艺和反应注塑产品

    公开(公告)号:US4582879A

    公开(公告)日:1986-04-15

    申请号:US592081

    申请日:1984-03-22

    摘要: A reaction injection molding process is disclosed comprising:introducing a mixture of substantially stable reactant streams into a mold, said mixture, in the aggregate, containing polyamide polymer forming compounds and polyurethane polymer forming compounds, said polyamide polymer forming compounds including lactam, an anionic polymerization catalyst and a polymerization activator, said polyurethane polymer forming compounds including a polyol, a polyisocyanate, a chain extender if desired, and a polyurethane polymerization catalyst, said polyamide polymer forming compounds and said polyurethane forming compounds reacting to respectively form polyamide and polyurethane polymers in said mold to thereby yielding a reaction injection molded product composed of said polymers; andrecovering said product from said mold.

    摘要翻译: 公开了一种反应注射成型方法,包括:将基本上稳定的反应物流的混合物引入模具中,所述混合物在聚集体中,含有聚酰胺聚合物形成化合物和形成聚氨酯聚合物的化合物,所述聚酰胺聚合物形成化合物包括内酰胺,阴离子聚合 催化剂和聚合活化剂,所述聚氨酯聚合物形成化合物,包括多元醇,多异氰酸酯,扩链剂,如果需要,和聚氨酯聚合催化剂,所述聚酰胺聚合物形成化合物和所述聚氨酯形成化合物在所述聚合反应中分别形成聚酰胺和聚氨酯聚合物 从而产生由所述聚合物组成的反应注塑产品; 并从所述模具中回收所述产品。

    Reinforced foam composites comprising hydroxy-containing vinyl ester
resin
    10.
    发明授权
    Reinforced foam composites comprising hydroxy-containing vinyl ester resin 失效
    包含含羟基乙酸酯树脂的增强泡沫复合材料

    公开(公告)号:US5091436A

    公开(公告)日:1992-02-25

    申请号:US482298

    申请日:1990-02-20

    摘要: There is disclosed a polyurethane/unsaturated polyester hybrid foam of the rigid type prepared from novel components including not only polyol and polyisocyanate but also a unique hydroxy-containing vinyl ester and vinyl monomer, optionally together with an additional polar vinyl monomer, all together providing the necessary components for a hybrid polyurethane-polyvinyl ester matrix, which mixture of components before foaming is capable of having suspended therein fillers and reinforcing fibers to produce a foam or reinforced foam composite having a density between about 20 and 100 pounds per cubic foot. The reinforced foam can be made into baords and the like and advantageously has continuous fiberglass strands or yarn disposed longitudinally in or adjacent the surface skin of the foam. The strands or yarn are preferably parallel and close together and are preferably flattened out in the foam-forming process so that the surfaces have a continuous fiberglass implant longitudinally and substantially so transversely. One preferred structural composite is illustrated in the drawings.

    摘要翻译: 公开了一种由新型成分制成的刚性类型的聚氨酯/不饱和聚酯混合泡沫体,其不仅包括多元醇和多异氰酸酯,而且还包括独特的含羟基的乙烯基酯和乙烯基单体,任选与另外的极性乙烯基单体一起提供 用于混合聚氨酯 - 聚乙烯酯基质的必需组分,其中发泡前组分的混合物能够悬浮在填料和增强纤维中以产生密度在约20和100磅/立方英尺之间的泡沫或增强泡沫复合材料。 增强的泡沫可以制成保持器等,并且有利地具有连续的玻璃纤维束或纱线,其纵向放置在泡沫的表面皮肤中或附近。 绞线或纱线优选平行并靠近在一起,并且优选在泡沫形成过程中被平坦化,使得表面具有纵向和基本上如此横向的连续玻璃纤维植入物。 在附图中示出了一种优选的结构复合材料。