摘要:
Compositions of expandable vinylaromatic polymers which contain a polymer, of at least one vinylaromatic monomer, having an average molecular weight Mw ranging from 50,000 to 170,000, which comprise: a) 0-50% by weight of a copolymer obtained by polymerizing one or more vinylaromatic monomers and 0.1-15% by weight of an α-alkylstyrene; b) 0-10% by weight of a compatible polymer having a crystallinity lower than 10% and a glass transition temperature (Tg) higher than 100° C., the remaining percentage consisting of the vinylaromatic polymer; c) 2-10% by weight, calculated with respect to the total, of an expanding agent; with the proviso that at least one of (a) or (b) is present in the polymeric mixture.
摘要:
Compositions of expandable vinylaromatic polymers which contain a polymer, of at least one vinylaromatic monomer, having an average molecular weight Mw ranging from 50,000 to 170,000, which comprise: a) 0-50% by weight of a copolymer obtained by polymerizing one or more vinylaromatic monomers and 0.1-15% by weight of an α-alkylstyrene; b) 0-10% by weight of a compatible polymer having a crystallinity lower than 10% and a glass transition temperature (Tg) higher than 100° C., the remaining percentage consisting of the vinylaromatic polymer; c) 2-10% by weight, calculated with respect to the total, of an expanding agent; with the proviso that at least one of (a) or (b) is present in the polymeric mixture.
摘要:
A thermoplastic composition based on a polyolefin and a vinyl aromatic polymer, having an improved combination of physical, mechanical and thermal properties, comprising:from 40 to 80% by weight of a vinyl aromatic polymer (A) containing, as an elastomeric component, from 0.5 to 5% by weight of a vinyl aromatic monomer - conjugated diene linear block polymer and from 5 to 15% of a diene rubber, from 5 to 50% by weight of a polyolefin (B) and from 10 to 50% by weight of an olefinic elastomer (C) containing, grafted thereon, a vinyl aromatic polymer, wherein the molar ratio between the vinyl aromatic polymer and the olefinic elastomer in the grafted phrase is greater than 0.8, the sum of components (A), (B) and (C) being equal to 100%.
摘要:
A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer in a controlled way, comprising the dissolving of an elastomer, such as polybutadiene, in a mixture consisting of a monomer and of a solvent in the presence of a polymerization catalytic system, which comprises an initiator of free radicals and a stable initiator of free radicals. The mixture obtained in this way is heated to a temperature of about 100° C. to functionalize the rubber, then more monomer is added and the temperature is raised to start the polymerization reaction.
摘要:
Process for the preparation of block copolymers, based on vinylaromatic monomers and monomers deriving from (meth)acrylic acid by means of radicalic polymerization which comprises polymerizing the monomers at a temperature higher than or equal to 120° C., in the presence of a radicalic initiating system comprising a compound having general Formula (I)
摘要:
Mass-continuous process for the production of vinylaromatic polymers which comprises feeding a reaction mixture containing at least one vinylaromatic monomer to at least one tubular reactor of the PFR type and operating with a recycling ratio, referring to the recycling flow-rate/feeding flow-rate, of less than 4.
摘要:
A sand dispensing system with a compact movable sand reservoir, mounted for movement atop a metal making furnace, is refillable with a predetermined amount of sand, and tilts with the furnace. The reservoir dispenses a directed stream of the predetermined amount of sand through a nozzle in a sump panel door to fill a tap hole in the furnace. One end of the nozzle receives the directed stream of sand. The opposite end of the nozzle projects into the furnace, to direct the sand stream into the tap hole when the sand reservoir is in the dispensing position. An imaging device may be used to inspect the tap hole before and after the sand is directed into the tap hole. A remote control may be used to operate the sand dispensing system. The predetermined amount may be adjusted as the fill volume of the tap hole increases.
摘要:
A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer comprising a rigid matrix consisting of vinylaromatic polymers or copolymers and of an elastomeric phase dispersed in the matrix in form of particles with a strictly bimodal distribution which comprises the functionalization of a first elastomeric fraction by means of a catalytic system containing a stable free radical initiator and subsequently the polymerization of the thus obtained mixture also in presence of a second non functionalized elastomeric fraction.
摘要:
Process for the preparation of block copolymers, based on vinylaromatic monomers and monomers deriving from (meth)acrylic acid by means of radicalic polymerization which comprises polymerizing the monomers at a temperature higher than or equal to 120° C., in the presence of a radicalic initiating system comprising a compound having general Formula (I).
摘要:
A thermoplastic composition having a good balance of mechanical and thermal properties, an improved impact strength and a good processability includes a functionalized polyphenylene ether, a polyamide, and an olefinic elastomer containing a vinylaromatic monomer grafted thereon.