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    Method for dyeing keratin fibers with compositions which contain 6- or 7-hydroxyindole derivatives as couplers and oxidation dye precursors
    1.
    发明授权
    Method for dyeing keratin fibers with compositions which contain 6- or 7-hydroxyindole derivatives as couplers and oxidation dye precursors 失效
    用含有6-或7-羟基吲哚衍生物作为成色剂和氧化染料前体的组合物染色角蛋白纤维的方法

    公开(公告)号：US6090160A

    公开(公告)日：2000-07-18

    申请号：US402941

    申请日：1995-03-13

    申请人： Alex Junino ,  Jean Jacques Vandenbossche ,  Herve Richard ,  Jean Cotteret

    发明人： Alex Junino ,  Jean Jacques Vandenbossche ,  Herve Richard ,  Jean Cotteret

    IPC分类号： A61K8/00 ,  A61K8/41 ,  A61K8/49 ,  A61Q5/10 ,  A61K7/13

    CPC分类号： A61Q5/10 ,  A61K8/492

    摘要： Hydraulic coupler compounds corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical; R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical or an alkoxycarbonyl radical; X denotes a C.sub.1 -C.sub.4 lower alkyl radical, a C.sub.1 -C.sub.18 alkoxy radical, a halogen atom, a C.sub.1 -C.sub.20 acyloxy radical, an acetylamino group, a trimethylsilyloxy group or a dialkyl(C.sub.1 -C.sub.4)aminomethyl group, the OH group occupying the 6- or 7-positions, as well as their salts, are combined with oxidation dye precursors for dyeing keratinous fibers.

    摘要翻译： 对应于下式的液压成色剂化合物：其中R 1表示氢原子或C 1 -C 4烷基; R2和R3可以相同或不同，表示氢原子，C1-C4低级烷基，羧基或烷氧基羰基; X表示C1-C4低级烷基，C1-C18烷氧基，卤素原子，C1-C20酰氧基，乙酰氨基，三甲基甲硅烷氧基或二烷基（C1-C4）氨基甲基，OH基占据 将6-或7-位以及它们的盐与用于染色角质纤维的氧化染料前体组合。

    Tinctorial composition for keratinous fibers containing oxidation dye precursors and couplers derived from 4-hydroxyindole, and dyeing method using them
    2.
    发明授权
    Tinctorial composition for keratinous fibers containing oxidation dye precursors and couplers derived from 4-hydroxyindole, and dyeing method using them 失效
    含有氧化染料前体和衍生自4-羟基吲哚的成色剂的角质纤维的着色组合物和使用它们的染色方法

    公开(公告)号：US5609649A

    公开(公告)日：1997-03-11

    申请号：US262444

    申请日：1994-06-20

    申请人： Alex Junino ,  Jean J. Vandenbossche ,  Herve Richard ,  Jean Cotteret

    发明人： Alex Junino ,  Jean J. Vandenbossche ,  Herve Richard ,  Jean Cotteret

    IPC分类号： A61K8/00 ,  A61K8/33 ,  A61K8/35 ,  A61K8/40 ,  A61K8/41 ,  A61K8/49 ,  A61Q5/10 ,  A61K7/13

    CPC分类号： A61Q5/10 ,  A61K8/492

    摘要： Tinctorial composition for keratinous fibers, in particular for human hair, characterized in that it contains, in a medium appropriate for dyeing these fibers, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor in combination with at least one heterocyclic coupler, corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical; R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical or an alkoxycarbonyl radical; R.sub.3 denotes a hydrogen or halogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical, an alkoxycarbonyl radical or a formyl radical; X denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a halogen atom, a C.sub.1 -C.sub.4 alkoxy radical, an acetylamino group or a dialkyl(C.sub.1 -C.sub.4)aminomethyl group; at least one of the groups X, R.sub.1, R.sub.2 and R.sub.3 differing from hydrogen; as well as their salts.

    摘要翻译： 用于角质纤维，特别是人类头发的着色组合物，其特征在于，在适于对这些纤维进行染色的介质中含有至少一种对氧化染料前体或至少一种邻位氧化染料前体与至少一种杂环成色剂 对应于下式：其中R 1表示氢原子或C 1 -C 4烷基; R2表示氢原子，C1-C4低级烷基，羧基或烷氧基羰基; R3表示氢或卤素原子，C1-C4低级烷基，羧基，烷氧基羰基或甲酰基; X表示氢原子，C1-C4烷基，卤素原子，C1-C4烷氧基，乙酰氨基或二烷基（C1-C4）氨基甲基; X，R1，R2和R3中的至少一个不同于氢; 以及它们的盐。

    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds
    3.
    发明授权
    Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds 失效
    基于吲哚衍生物的角质纤维染色组合物和新化合物

    公开(公告)号：US4822375A

    公开(公告)日：1989-04-18

    申请号：US21932

    申请日：1987-03-05

    申请人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    发明人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/41 ,  A61K8/49 ,  A61K8/92 ,  A61Q5/10 ,  C07D209/08 ,  C07D209/12 ,  C07D209/42 ,  C07D491/04 ,  C07D491/056 ,  C07F7/18 ,  C07F9/572 ,  C09B53/00 ,  C09B53/02 ,  C09B57/00 ,  C09B69/00 ,  D06P3/08 ,  A61K7/13 ,  C07D209/30 ,  C07F9/12

    CPC分类号： C07D491/04 ,  A61K8/492 ,  A61Q5/10 ,  C07D209/08 ,  C07F7/1856 ,  C07F9/5728 ,  C09B69/007 ,  C09B69/008

    摘要： Dyeing compositions for keratinous fibres based on indole derivatives, and new compounds.Dyeing composition for keratinous fibres, and especially human hair, characterized in that it contains, in a cosmetically acceptable medium suitable for dyeing these fibres, at least one dye corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a lower alkyl group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group -COOSiR.sub.9 - R.sub.10 R.sub.11 ; and R.sub.5, which may be identical or different, denote at least one linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, the other group R.sub.4 or R.sub.5 being able to be a hydrogen atom, R.sub.4 and R.sub.5 are not simultaneously acetyl, or alternatively R.sub.4 and R.sub.5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a thiocarbonyl group, a group>P(O)OR.sub.6 or>CR.sub.7 R.sub.8 ;R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, and R.sub.8 denotes a lower alkoxy group or a mono- or dialkylamino group, R.sub.9, R.sub.10 and R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, and the cosmetically acceptable salts of alkali metals, alkaline earth metal metals, ammonia or amines.

    摘要翻译： 基于吲哚衍生物的角质纤维染色组合物和新化合物。 用于角质纤维，特别是人类头发的染色组合物，其特征在于，其在适合于染色这些纤维的化妆品可接受的培养基中含有至少一种对应于下式的染料：其中R 1表示氢原子 或低级烷基或-SiR 9 R 10 R 11基团; R2和R3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或基团-COOSiR9-R10R11; 和R 5可以相同或不同，表示至少一个直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， SiR 9 R 10 R 11，基团-P（O）（OR 6）2或基团R 6 OSO 2 - ，另一基团R 4或R 5可以是氢原子，R 4和R 5不同时为乙酰基，或者R4和R5连同 形成任选地含有羰基，硫代羰基，基团> P（O）OR 6或> CR 7 R 8的环的氧原子。 R6表示氢原子或低级烷基，R7表示氢原子或低级烷基，R8表示低级烷氧基或一或二烷基氨基，R9，R10和R11可相同或不同， 表示直链或支链的低级烷基，以及碱金属，碱土金属金属，氨或胺的美容上可接受的盐。

    Compositions for coloring the skin based on indole derivatives
    4.
    发明授权
    Compositions for coloring the skin based on indole derivatives 失效
    基于吲哚衍生物着色皮肤的组合物

    公开(公告)号：US4956174A

    公开(公告)日：1990-09-11

    申请号：US21931

    申请日：1987-03-05

    申请人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    发明人： Gerard Lang ,  Herve Richard ,  Madeleine Leduc ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/46 ,  A61K8/49 ,  A61K8/58 ,  A61K8/86 ,  A61K8/92 ,  A61Q1/02 ,  A61Q19/04

    CPC分类号： A61Q19/04 ,  A61K8/492

    摘要： Cosmetic composition designed to impart to the skin a coloring which is substantially similar to the pigmentation resulting from natural tanning, characterized in that it contains, in a cosmetically acceptable medium suitable for topical application, at least one compound of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom, a lower alkyl group or a residue --SiR.sub.9 R.sub.10 R.sub.11, R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ; R.sub.4 and R.sub.5 which may be identical or different, denote a hydrogen atom, a linear or branched C.sub.1 -C.sub.20 alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group R.sub.6 OSO.sub.2 --, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O)(OR.sub.6).sub.2 or an aralkyl group, or alternatively R.sub.4 and R.sub.5, with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group when at least one of the groups, R.sub.1, R.sub.2 or R.sub.3 is other than hydrogen or alternatively a thiocarbonyl group, a residue >P(O)OR.sub.6, a group >CR.sub.7 R.sub.8 or a methylene group, R.sub.6 denoting a hydrogen atom or a lower alkyl group, R.sub.7 denoting a hydrogen atom or a lower alkyl group, R.sub.8 denoting a lower alkoxy group or a mono- or dialkylamino group and R.sub.9, R.sub.10 or R.sub.11, which may be identical or different, denoting linear or branched lower alkyl groups, at least one of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 being other than hydrogen; and the corresponding salts with alkali metals, alkaline earth metals, ammonium or amines.

    摘要翻译： 化妆品组合物被设计成赋予皮肤一种基本上类似于由天然鞣制引起的色素沉着的着色，其特征在于其在适合局部应用的化妆品可接受的介质中包含至少一种下式的化合物： I），其中R 1表示氢原子，低级烷基或残基-SiR 9 R 10 R 11，R 2和R 3可以相同或不同，表示氢原子，低级烷基，羧基，低级烷氧基羰基或 一组-COOSiR9R10R11; 可以相同或不同的R 4和R 5表示氢原子，直链或支链C 1 -C 20烷基，甲酰基，直链或支链C 2 -C 20酰基，直链或支链C 3 -C 20链烯酰基， 基团R6OSO2-，基团-SiR9R10R11，基团-P（O）（OR6）2或芳烷基，或者R4和R5与它们所连接的氧原子形成任选含有羰基的环， R 1，R 2或R 3中的至少一个不是氢或硫代羰基，残基> P（O）OR 6，基团> CR 7 R 8或亚甲基，R 6表示氢原子或低级烷基 ，R7表示氢原子或低级烷基，R8表示低级烷氧基或单或二烷基氨基，R9，R10或R11可以相同或不同，表示直链或支链的低级烷基，至少一个 的取代基R 1，R 2，R 3，R 4和R 5不是氢; 和与碱金属，碱土金属，铵或胺的相应的盐。

    Method for dyeing keratinous fibres using an aminoindole in combination with a quinone derivative
    5.
    发明授权
    Method for dyeing keratinous fibres using an aminoindole in combination with a quinone derivative 失效
    使用氨基酸与喹啉衍生物组合的染色剂的染色方法

    公开(公告)号：US5180400A

    公开(公告)日：1993-01-19

    申请号：US707056

    申请日：1991-05-29

    申请人： Alain Baudry ,  Alex Junino ,  Herve Richard

    发明人： Alain Baudry ,  Alex Junino ,  Herve Richard

    IPC分类号： A61K8/00 ,  A61K8/35 ,  A61K8/41 ,  A61K8/42 ,  A61K8/44 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  D06P3/08 ,  D06P5/00

    CPC分类号： A61K8/492 ,  A61Q5/10

    摘要： Method for dyeing keratinous fibres, characterized in that at least one composition (A) containing at least one aminoindole in a medium appropriate for dyeing is applied to these fibres, the application of the composition (A) being preceded or followed by the application of a composition (B) containing, in a medium appropriate for dyeing, at least one quinone derivative chosen from ortho- or para-benzoquinones, ortho- or para-benzoquinone monoimines or diimines, 1,2- or 1,4-naphthoquinones, ortho- or para-benzoquinone sulphonimides, .alpha.,.omega.-alkylene-bis-1,4-benzoquinones, or 1,2- or 1,4-naphthoquinone monoimines or diimines, the aminoindoles and the quinone derivatives being chosen such that the difference in redox potential .DELTA.E between the redox potential E.sub.i of the aminoindoles, determined at pH 7 in a phosphate medium on a vitreous carbon electrode by voltametry, and the redox potential E.sub.q of the quinone derivative, determined at pH 7 in a phosphate medium by polarography on a mercury electrode relative to the saturated calomel electrode, in such that.DELTA.E=E.sub.i -E.sub.q .ltoreq.470 mV.

    摘要翻译： 染色角质纤维的方法，其特征在于在适于染色的培养基中至少含有至少一个氨基吲哚的组合物（A）施用于这些纤维，组合物（A）在施用之前或之后施用 在适于染色的介质中含有至少一种选自邻 - 或对 - 苯醌，邻 - 或对 - 苯醌单亚胺或二亚胺的醌衍生物，1,2-或1,4-萘醌，邻 - 或对苯醌磺酰亚胺，α，ω-亚烷基 - 双-1,4-苯醌或1,2-或1,4-萘醌单亚胺或二亚胺，选择氨基吲哚和醌衍生物，使得氧化还原电位的差异 在玻璃碳电极上的磷酸盐介质中通过伏安法在pH7下测定的氨基吲哚的氧化还原电位Ei与在磷酸盐介质中通过极谱法在pH7下测定的醌衍生物的氧化还原电位Eq 在汞电极上相对于饱和甘汞电极，使得DELTA E = Ei-Eq

    Use of indole derivative for dyeing keratin materials, tinctorial compositions, new compounds and dyeing process
    9.
    发明授权
    Use of indole derivative for dyeing keratin materials, tinctorial compositions, new compounds and dyeing process 失效
    用于染色材料，化学成分，新化合物和染色工艺的染料衍生用途

    公开(公告)号：US5131911A

    公开(公告)日：1992-07-21

    申请号：US769811

    申请日：1991-10-02

    申请人： Gerard Lang ,  Serge Forestier ,  Alex Junino ,  Herve Richard ,  Jean Jacques Van den Bossche

    发明人： Gerard Lang ,  Serge Forestier ,  Alex Junino ,  Herve Richard ,  Jean Jacques Van den Bossche

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/37 ,  A61K8/39 ,  A61K8/49 ,  A61K8/58 ,  A61Q1/00 ,  A61Q5/10 ,  C07D209/08

    CPC分类号： A61Q5/10 ,  A61K8/492 ,  C07D209/08

    摘要： Process for dyeing keratin fibers by using derivatives of formula: ##STR1## where: R.sub.1 =H, lower alkyl or SiR.sub.11 R.sub.12 R.sub.13 ;R.sub.2 and R.sub.3, which may be identical or different, =H, alkyl, carboxyl, alkoxycarbonyl or --COOSiR.sub.11 R.sub.12 R.sub.13 ;R.sub.4 to R.sub.7, which may be identical or different, =H or an O--Z group, where Z=H, C.sub.1 -C.sub.20 alkyl, aralkyl, formyl, C.sub.2 -C.sub.20 acyl, C.sub.3 -C.sub.20 alkenyl, --SiR.sub.11 R.sub.12 R.sub.13, --P(O)(OR.sub.8).sub.2, R.sub.8 OSO.sub.2 ;or a heterocycle which may contain a P(O)(OR.sub.8) or CR.sub.9 R.sub.10 group;with the reservation that at least two of R.sub.4 to R.sub.7 denotes OZ or form a ring, and that at least one of R.sub.4 or R.sub.7 represents OZ;R.sub.8 and R.sub.9 =H, lower alkyl;R.sub.10 =alkoxy, mono- or dialkylamino;R.sub.11, R.sub.12 and R.sub.13, which may be identical or different, are alkyl groups;or their alkali metal, alkaline-earth metal, ammonium and amine salts.

    摘要翻译： 通过使用下式的衍生物染色角蛋白纤维的方法：其中：R1 = H，低级烷基或SiR11R12R13; R2和R3可以相同或不同，= H，烷基，羧基，烷氧基羰基或-COOSiR11R12R13; 其中Z = H，C 1 -C 20烷基，芳烷基，甲酰基，C 2 -C 20酰基，C 3 -C 20链烯基，-SiR 11 R 12 R 13，-P（O）（OR 8），R 4至R 7可以相同或不同， 2，R8OSO2; 或可含有P（O）（OR 8）或CR 9 R 10基团的杂环; 保留R4至R7中的至少两个表示OZ或形成环，并且R4或R7中的至少一个表示OZ; R8和R9 = H，低级烷基; R10 =烷氧基，单或二烷基氨基; R 11，R 12和R 13可以相同或不同，是烷基; 或它们的碱金属，碱土金属，铵和胺盐。