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1.发明授权Immobilized calixarenes and related compounds and process for their production 有权固定的杯芳烃和相关化合物及其生产方法公开(公告)号：US06951690B2
公开(公告)日：2005-10-04
申请号：US10394904
申请日：2003-03-21
CPC分类号： B01J31/2295 , B01J20/3204 , B01J20/3219 , B01J20/3248 , B01J20/3253 , B01J31/066 , B01J31/1633 , B01J2231/321 , B01J2231/50 , B01J2231/60 , B01J2531/16 , Y10T428/31663 , Y10T428/31942
摘要： Immobilized calixarenes and calixarene-related compounds are produced by a process comprising either: (a) contacting the calixarene or calixarene-related compound with a substrate containing one or more metallic or non-metallic oxides that has been surface modified by reaction with one or more polyhalides and/or polyalkoxides of an element capable of forming a stable aryloxide species with the substrate, or (b) reaction of such a substrate with a calixarene or calixarene-related compound that has been previously modified or derivatized by reaction with said polyhalides and/or polyalkoxides.
摘要翻译： 固定化的杯芳烃和杯芳烃相关化合物通过以下方法制备，该方法包括：（a）将杯芳烃或杯芳烃相关化合物与含有一种或多种金属或非金属氧化物的基质接触，所述金属或非金属氧化物通过与一种或多种 能够与底物形成稳定的芳氧基物质的元素的多卤化物和/或多烷氧化物，或（b）这种底物与杯芳烃或杯芳烃相关化合物的反应，其已经通过与所述多卤化物和/ 或多烷氧化物。
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公开(公告)号：US08808655B2
公开(公告)日：2014-08-19
申请号：US12030200
申请日：2008-02-12
申请人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
发明人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
CPC分类号： B01D53/565 , B01D53/8628 , B01D2253/202
摘要： Immobilized nitronyl nitroxide active sites on the surface of a porous inorganic oxide support act as efficient and rapid oxidants for NO, reacting with >99% of the NO under flow conditions through a packed bed; and, in a parallel configuration with nitroxyl radical active sites, act to remove >99% of both NO and NO2 from a gas mixture, with >95% of the active sites participating in NOx trapping.
摘要翻译： 在多孔无机氧化物载体表面上固定的硝基氮氧化物活性位置作为NO的有效和快速氧化剂，在流动条件下通过填充床与> 99％的NO反应; 并且与硝酰自由基活性位点并联配置，可以从气体混合物中除去> 99％的NO和NO2，其中95％的活性位点参与NOx捕获。
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公开(公告)号：US08703083B2
公开(公告)日：2014-04-22
申请号：US12510861
申请日：2009-07-28
CPC分类号： B01D53/565 , B01D53/8628 , B01D2253/202
摘要： Immobilized nitronyl nitroxide active sites on the surface of a porous inorganic oxide support act as efficient and rapid oxidants for NO, reacting with >99% of the NO under flow conditions through a packed bed; and, in a parallel configuration with nitroxyl radical active sites, act to remove >99 % of both NO and NO2 from a gas mixture, with >95% of the active sites participating in NOx trapping.
摘要翻译： 在多孔无机氧化物载体表面上固定的硝基氮氧化物活性位置作为NO的有效和快速氧化剂，在流动条件下通过填充床与> 99％的NO反应; 并且与硝酰自由基活性位点并联配置，可以从气体混合物中除去> 99％的NO和NO2，其中95％的活性位点参与NOx捕获。
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公开(公告)号：US20090028768A1
公开(公告)日：2009-01-29
申请号：US12030200
申请日：2008-02-12
申请人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
发明人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
IPC分类号： B01D53/56
CPC分类号： B01D53/565 , B01D53/8628 , B01D2253/202
摘要： Immobilized nitronyl nitroxide active sites on the surface of a porous inorganic oxide support act as efficient and rapid oxidants for NO, reacting with >99% of the NO under flow conditions through a packed bed; and, in a parallel configuration with nitroxyl radical active sites, act to remove >99% of both NO and NO2 from a gas mixture, with >95% of the active sites participating in NOx trapping.
摘要翻译： 在多孔无机氧化物载体表面上固定的硝基氮氧化物活性位置作为NO的有效和快速氧化剂，在流动条件下通过填充床与> 99％的NO反应; 并且与硝酰自由基活性位点并联配置，可以从气体混合物中除去> 99％的NO和NO2，其中95％的活性位点参与NOx捕获。
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5.发明申请Novel immobilized calixarenes and related compounds and process for their production 审中-公开新型固定化杯芳烃及相关化合物及其生产工艺公开(公告)号：US20050255332A1
公开(公告)日：2005-11-17
申请号：US11187195
申请日：2005-07-21
CPC分类号： B01J31/2295 , B01J20/3204 , B01J20/3219 , B01J20/3248 , B01J20/3253 , B01J31/066 , B01J31/1633 , B01J2231/321 , B01J2231/50 , B01J2231/60 , B01J2531/16 , Y10T428/31663 , Y10T428/31942
摘要： Immobilized calixarenes and calixarene-related compounds are produced by a process comprising either: (a) contacting the calixarene or calixarene-related compound with a substrate containing one or more metallic or non-metallic oxides that has been surface modified by reaction with one or more polyhalides and/or polyalkoxides of an element capable of forming a stable aryloxide species with the substrate, or (b) reaction of such a substrate with a calixarene or calixarene-related compound that has been previously modified or derivatized by reaction with said polyhalides and/or polyalkoxides.
摘要翻译： 固定化的杯芳烃和杯芳烃相关化合物通过以下方法制备，该方法包括：（a）将杯芳烃或杯芳烃相关化合物与含有一种或多种金属或非金属氧化物的基质接触，所述金属或非金属氧化物通过与一种或多种 能够与底物形成稳定的芳氧基物质的元素的多卤化物和/或多烷氧化物，或（b）这种底物与杯芳烃或杯芳烃相关化合物的反应，其已经通过与所述多卤化物和/ 或多烷氧化物。
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公开(公告)号：US09718049B2
公开(公告)日：2017-08-01
申请号：US14587608
申请日：2014-12-31
申请人： Alexander Katz , Isao Ogino , Stacey Ian Zones
发明人： Alexander Katz , Isao Ogino , Stacey Ian Zones
IPC分类号： C01B39/02 , C01B39/38 , C01B39/40 , C01B39/46 , C01B39/48 , B01J29/70 , B01J29/65 , B01J29/04 , B01J37/00 , B01J37/34 , B01J29/86 , B01J35/00 , B01J35/10
CPC分类号： B01J29/7038 , B01J29/041 , B01J29/65 , B01J29/70 , B01J29/7088 , B01J29/86 , B01J35/002 , B01J35/1057 , B01J35/1061 , B01J37/0072 , B01J37/343 , B01J2229/34 , B01J2229/37 , B01J2229/38 , C01B39/026 , C01B39/38 , C01B39/40 , C01B39/46 , C01B39/48
摘要： The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.
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公开(公告)号：US20140121427A1
公开(公告)日：2014-05-01
申请号：US14065302
申请日：2013-10-28
CPC分类号： B01J31/20 , B01J31/1625 , B01J31/2404 , B01J2231/645 , B01J2531/0211 , B01J2531/827
摘要： The present invention is directed to the activation of metal carbonyl clusters by an oxidative agent to prepare a stable metal cluster catalyst exhibiting catalytic rate enhancement. The activation comprises, for example, using oxygen for decarbonylation of carbonyl ligands and changing the oxidation state of the other ligands. In one aspect, treatment of the metal cluster catalyst under oxidative conditions in a flow reactor leads to removal of CO ligands and oxidation of bound calixarene phosphine ligands, and results in a stable activated open metal cluster that is more active for ethylene hydrogenation catalysis. The resulting metal cluster contains coordinatively unsaturated sites comprising carbonyl vacancies. In one aspect, the resulting activated open metal cluster can be used as a catalyst in a variety of chemical transformations.
摘要翻译： 本发明涉及通过氧化剂活化金属羰基簇以制备显示出催化速率增强的稳定的金属簇催化剂。 活化包括例如使用氧来羰基配体的脱羰和改变其它配体的氧化态。 在一个方面，在流动反应器中在氧化条件下处理金属簇催化剂导致CO配体的去除和结合的杯芳烃膦配体的氧化，并且导致对于乙烯氢化催化更有活性的稳定的活化的开放金属簇。 所得到的金属簇包含具有羰基空位的配位不饱和位点。 在一个方面，所得到的活化的开放金属簇可用作多种化学转化中的催化剂。
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公开(公告)号：US09718048B2
公开(公告)日：2017-08-01
申请号：US14587527
申请日：2014-12-31
申请人： Alexander Katz , Isao Ogino , Stacey Ian Zones
发明人： Alexander Katz , Isao Ogino , Stacey Ian Zones
IPC分类号： C01B39/02 , C01B39/38 , C01B39/40 , C01B39/46 , C01B39/48 , B01J29/70 , B01J29/65 , B01J29/04 , B01J37/00 , B01J37/34 , B01J29/86 , B01J35/00 , B01J35/10
CPC分类号： B01J29/7038 , B01J29/041 , B01J29/65 , B01J29/70 , B01J29/7088 , B01J29/86 , B01J35/002 , B01J35/1057 , B01J35/1061 , B01J37/0072 , B01J37/343 , B01J2229/34 , B01J2229/37 , B01J2229/38 , C01B39/026 , C01B39/38 , C01B39/40 , C01B39/46 , C01B39/48
摘要： The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in a non-aqueous solution to affect delamination of a layered zeolite precursor, generally comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.
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公开(公告)号：US09575042B2
公开(公告)日：2017-02-21
申请号：US14292252
申请日：2014-05-30
CPC分类号： G01N33/004 , B01D53/00 , B01D53/02 , B01D2253/20 , B01D2257/502 , B01J20/223 , B01J20/3483 , B01J31/2295 , C07C7/12 , Y02A50/243 , Y02P20/52 , Y10T436/205831 , C07C11/04
摘要： Provided is an organic ligand-bound metal surface that selects one gaseous species over another. The species can be closely sized molecular species having less than 1 Angstrom difference in kinetic diameter. In one embodiment, the species comprise carbon monoxide and ethylene. Such organic ligand-bound metal surfaces can be successfully used in gas phase separations or purifications, sensing, and in catalysis.
摘要翻译： 提供了一种有机配体结合的金属表面，其选择一种气态物质超过另一种。 该物种可以具有动力学直径小于1埃差的分子物种。 在一个实施方案中，物质包含一氧化碳和乙烯。 这种有机配体结合的金属表面可以成功地用于气相分离或纯化，感测和催化。
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10.发明申请Thermolytic synthesis of inorganic oxides imprinted with functional moieties 审中-公开印有功能部分的无机氧化物的热分解合成公开(公告)号：US20050003188A1
公开(公告)日：2005-01-06
申请号：US10806825
申请日：2004-03-22
申请人： John Bass , Alexander Katz
发明人： John Bass , Alexander Katz
IPC分类号： B01J21/04 , B01J23/02 , B01J31/00 , B01J31/16 , B05D7/00 , B32B15/02 , C07F15/00 , G01N20060101
CPC分类号： B01J31/1633 , B01J31/1815 , B01J2231/341 , B01J2231/4211 , B01J2531/824 , B82Y30/00 , C07B2200/11 , C07F15/0066 , Y02P20/55 , Y10T428/2982 , Y10T428/2991
摘要： Inorganic oxides, particularly silica or germania or inorganic oxides containing silica and/or germania, are imprinted with one or a plurality of functional moieties such as amine and/or thiol groups by a process featuring incorporating such groups into the oxide by use of a thermally labile material containing a protecting group for the amine or thiol, followed by removal of the thermally labile moiety by thermolysis. The resulting products are inorganic oxide substrates or bulk inorganic oxides imprinted with the functional moieties. A plurality of such moieties may be imprinted on a substrate in an order fashion using a polymeric imprinting compound, and may then be used as a templated array of functional moieties to which ordered metallic nanostructures may be constructed.
摘要翻译： 无机氧化物，特别是二氧化硅或氧化锗或含有二氧化硅和/或氧化锗的无机氧化物，通过以下方法印上一个或多个功能部分，例如胺和/或硫醇基，其特征是通过使用热 含有胺或硫醇保护基的不稳定材料，然后通过热分解除去热不稳定部分。 所得产物是无机氧化物底物或印有功能部分的本体无机氧化物。 多个这样的部分可以使用聚合物印记化合物以顺序印迹在基底上，然后可以用作可以构建有序金属纳米结构的功能部分的模板阵列。
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